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Part of the book series: Reactivity and Structure Concepts in Organic Chemistry ((REACTIVITY,volume 2))

Abstract

The expression of the third-order term of Eq. (3.9), i.e. Eq. (9.1), finds an interesting application. This term can be negative and therefore contribute to stabilizing the system only if

$$ {{\text{S}}_{{\text{k 0}}}}{{\text{S}}_{0{\text{L}}}}{S_{LK{\text{ }}}} > {\text{ 0}} $$
(10.1)

since for a sufficiently small interaction

$$ {S_{pq}}{\text{ (}}{H_{qp}}{\text{ - }}{S_{qp}}{H_{00}}) < 0 $$

in the argument using real functions. This stability condition (10.1), applied to a system composed of three species interacting with one another, serves frequently as the selection rule of chemical interactions.

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© 1975 Springer-Verlag Berlin · Heidelberg

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Fukui, K. (1975). Three-species Interaction. In: Theory of Orientation and Stereoselection. Reactivity and Structure Concepts in Organic Chemistry, vol 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61917-5_10

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  • DOI: https://doi.org/10.1007/978-3-642-61917-5_10

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-61919-9

  • Online ISBN: 978-3-642-61917-5

  • eBook Packages: Springer Book Archive

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