Abstract
As is well known, the eigen-vibrations of a cubical cavity, with edge l and volume V=l3 whose walls are perfect reflectors, have the following properties: The components k i of the wave vector whose magnitudes amount to 2π divided by the wave-length, have the eigenvalues
where the integers s i are to be restricted to positive numbers, since we are dealing with standing waves. The number dN of eigen-vibrations with wave vector components k i lying between k i and k i + dk i is then given by
where the factor 2 takes care of the two polarisation directions of the wave, while the factor 8 arises because for standing waves we have to restrict ourselves to the positive octant of the k-space.
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Notes
Cf. C.G. Darwin, Proc. Roy. Soc. London (A), 136, 36 (1932).
These relations can be found in a somewhat different form (four-dimension) in P. Jordan and W. Pauli, Z. Phys. 47, 151 (1927) and in the form given here in W. Heisenberg and W. Pauli, ibid., 56, 1 (1927).
Cf. L. Landau and R. Peierls, Z. Phys. 62, 188 (1930).
A discussion on the introduction of the quantities F and F * for avoiding the zero-point energy can be found in L. Rosenfeld and J. Solomon, Journ. de Phys. Series 7, 2, 139 (1931) and also in J. Solomon, Doctoral Thesis, Paris (1931). The C.R. between i F and F* given in these references arc, incorrect, since they are not compatible with the conditions, div \(\vec F = 0\) and div \(\vec F* = 0\).
Cf. L. Landau and R. Peierls, Z. Phys. 69, 56 (1931) in particular, Secs. 3 and 4; W. Heisenberg, The Physical Principles of Quantum Theory, loc. cit., Chapter 3, Sec. 2.
L. Landau and R. Peierls, Z. Phys., 62, 188 (1930)
cf. also J.R. Oppenheimer, Phys. Rev., 38, 725 (1931).
Reviews: L. Rosenfeld, Mém. de l’Inst. Henri Poincaré, 2, 24 (1932)
E. Fermi, Rev. Mod. Phys. 1, 87 (1932).
Original Papers; G. Mie, Ann. d. Phys. (4) 85, 711 (1928)
W. Heisenberg and W. Pauli, I, Z. Phys. 56, 1 (1929); II, ibid, 59, 168 (1929). (Remarks on these: L. Rosenfeld, ibid., 58, 540 (1929) and 63, 574 (1930)
E. Fermi, Lincei Rend. (6), 9, 881 (1929), 12, 431 (1930)
L. Rosenfeld, Ann. d. Phys., 5, 113 (1930).)
P.A.M. Dirac, Proc. Roy. Soc. London, 114, 243, 710 (1927). Dirac employed standing waves and not progressive waves for quantising the radiation. Secondly, at that time his theory of the electron had not appeared and, therefore, he used in the Hamiltonian for each particle the non-relativistic operator \(\left( {1/2m} \right)\sum {\pi _j^2 }\) instead of \(c\left( {\sum {\alpha _j \pi _j + mc\beta } } \right)\). This is approximately correct for small velocities of particles. The fact that the equations (26.23) and (26.24) follow from quantum electrodynamics was shown by
J.R. Oppenheimer, Phys. Rev., 35, 461 (1930) and
E. Fermi, Lincei Rend., 12, 431 (1930).
L. Landau and R. Peierls, Z. Phys. 62, 188 (1930).
W. Heisenberg, Ann. d. Phys. (5), 9, 338 (1931). In contrast to Heisenberg’s approach, we do not use here the method of quantisation of matter waves. The interaction between the electrons of the atom can then be arbitrary.
I thank Prof. R. Peierls for these remarks. For the case of the self-energy of an oscillator, cf., also L. Rosenfeld, Z. Phys., 70, 454 (1931).
I. Waller, Z. Phys., 62, 673 (1930).
J.R. Oppenheimer, Phys. Rev., 35, 461 (1930).
Cf. M. Born and G. Rumer, Z. Phys., 69, 141 (1931).
Approximate ansatz for these have been presented in G. Breit, Phys. Rev., 34, 553 (1929); 36, 383 (1930) (magnetic interaction, but without retardation). See H. Bethe and E. Salpeter, Quantum Mechanics of One-and Two-electron problem, loc. cit. and
C. Moller, Z. Phys., 70. 786 (1931) (Collisions with weak interaction, treated as retarded), also Ann. d. Phys., 14, 531 (1932). See further G. Wentzel, Wave Mechanics of Collision and Radiation Processes, loc. cit.
Cf. also A.D. Fokker, Physica, 12, 145 (1932) and Z. Phys., 58, 386 (1929), where a two-body problem with partly retarded and partly advanced potentials is treated. For this problem, no radiation is emitted classically.
L. Rosenfeld, Z. Phys., 65, 589 (1930).
J. Solomon, Z. Phys., 71, 162 (1931).
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Pauli, W. (1980). Quantum Electrodynamics. In: General Principles of Quantum Mechanics. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61840-6_10
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