Abstract
The outstanding behaviours of inorganic polymer flocculants polyaluminum superior to the traditional coagulants aluminum salts were experimentally examined by the potentiometry, 27Al NMR, timed ferron complexation spectrophotometry, laser scattering PCS, streaming current detector, zeta potential meter and flocculation detector determination and jar test.
Al13 species can be made up only when the Al solution is undertaken a base addition with the production of Al(OH) -4 as precursors. Their superior properties in the coagulation-flocculation processes should be attributed also to the character of temporary refractory of hydrolysis. A scheme of transformation pathway for Al species in solution was suggested.
Their mechanism and quantitative model in coagulation-flocculation processes may be proposed to set up on the basis of the surface complexation-precipitation modeling.
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References
polymeric species, I, II. Water Research 21 (1987) 115, 123
Tang, H.X.: Basic studies of inorganic polymer flocculants. Environmental Chemistry (in Chinese) 9 (3) (1990) 1–12
Hem, J.D., Roberson, C.E.: Form and stability of aluminum hydroxide complexes in dilute solution. U.S. Geol. Survey Water-Supply Paper 1827-A (1967) pp.55
Stol, R.J., van Helden, A.K., de Bruyn, P.L.: Hydrolysis-precipitation studies of aluminum (III) solutions. 2. A kinetics study and model. J. Colloid Interface. Sci. 57 (1976) 115
Letterman, R.D., Asolekar, S.R.: Surface ionization of polynuclear species in the Al(III) hydrolysis. II. A conditional equilibrium model. Water Research 24 (1990) 941
Akitt, J.W., Greenwood, N.N., Khandelwal, B.L., Lester, G.D.: 27A1 nuclear magnetic resonance studies of the hydrolysis and polymerisation of the hexa-aquo-aluminum(III) cation. J. Chem. Soc. Dalton Trans. (1972) 604–610
Bottero, J.Y., Cases, J.M., Fiessinger, F., Poirier, J.E.: Studies of hydrolyzed aluminum chloride solutions. 1. Nature of aluminum species and composition of aqueous solutions. J. Physical Chemistry 84 (1980) 2933
Bottero, J.Y., Axelos, M., Tchoubar, D., et al.: Mechanism of formation of aluminum trihydroxide from KegginA1i3 Polymers. J. Colloid Interface Sci. 117 (1987) 47
Smith, R.W., Hem, J.D.: Effect of ageing on aluminum hydroxide complexes in dilute aqueous solutions. U.S. Geol. Survey Water-Supply Paper 1827D (1972) pp.51
Parthasarathy, N., Buffle, J.: Study of polymeric aluminum(III) hydroxide solutions for application in waste water treatment. Properties of the polymer and optimal conditions of preparation. Water Research 19 (1985) 25
Bertsch, P.M.: Aqueous polynuclear aluminum species. In: The Environmental Chemistry of Aluminum, G. Sposito (Ed.). CRC Press, 1989, pp. 87–115
Bertsch, P.M.: Conditions for AI13 polymer formation in partially neutralized aluminum solutions. Soil Sci. 51 (1987) 825
Bottero, J.Y., Masion, A., Lartiges, B.S., et al.: Hydrolysis and flocculation: a structural approach through small-angle X-ray scattering. Journal de Physique IV, 3 (1993) 211
Hahn, H.H., Stumm, W.: Kinetics of coagulation with hydrolysed Al(III). J. Colloid Interface Sci. 28 (1968) 134
Amirtharajah, A., O’Melia, C.R.: Coagulation Processes: destabilization, mixing, and flocculation. In: Water Quality and Treatment, 4th edition. McGraw-Hill, 1990, pp. 269–365
Van Benschoten, J.E., Edzwald, J.K.: Chemical aspects of coagulation using aluminum salts. I. Hydrolytic reactions of alum and polyaluminum chloride. Water Research 24 (1990) 1519
Tang, H.X., Luan, Z.K.: Features and mechanism for coagulation-flocculation processes of polyaluminum chloride. J. Environmental Science (China) 7 (1995) 204
Gregory, J.: Turbidity fluctuations in flowing suspensions. J. Colloid Interface Sci. 105 (1985) 357–371
Letterman, R.D., Iyer, D.R.: Modeling the effects of hydrolyzed aluminum and solution chemistry on flocculation kinetics. Environ. Sci. Technol. 19 (1985) 673
Dentel, S.K.: Application of the precipitation-charge neutralization model of coagulation. Environ. Sci. Technol. 22 (1988) 825
Farley, K.J., Dzombak, D.A., Morel, F.M.M.: A surface precipitation model for the sorption of cations on metal oxides. J. Colloid Interface Sci. 106 (1985) 226
Katz, L.E., Hayes, K.F.: Surface complexation modeling, I, II. J. Colloid Interface Sci. 170 (1995) 477,491
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Tang, H., Luan, Z. (1996). The Differences of Behaviour and Coagulating Mechanism Between Inorganic Polymer Flocculants and Traditional Coagulants. In: Hahn, H.H., Hoffmann, E., Ødegaard, H. (eds) Chemical Water and Wastewater Treatment IV. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61196-4_8
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DOI: https://doi.org/10.1007/978-3-642-61196-4_8
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