Abstract
This paper is a summary of research on the role of mixing in the coagulation process. In particular, the optimal rapid mix G value and detention time were determined for coagulation using an organic, cationic polyelectrolyte. The optimal G value was in agreement with previous studies, but the optimal detention time was in seconds instead of several minutes. Studies on the use of static mixers are also summarized. Comparing the static mixer to a jar test for enhanced coagulation studies showed that the type of mixer is important in determining optimal coagulant doses for TOC removal. This conclusion has important implications for water treatment plants practicing enhanced coagulation. A computational fluid dynamics model of static mixers is also introduced that can provide detailed, quantitative information on the fluid flow and chemical dispersion in static mixers.
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References
Kawamura, S.: Integrated Design of Water Treatment Facilities. John Wiley, New York 1991, pp. 63, 75
Amirtharajah, A., Mills, K.M.: Rapid-mix Design for Mechanisms of Alum Coagulation. Journal AWWA 74 (4) (1982) 210
Amirtharajah, A., O’Melia, C.R.: Coagulation Processes: Destabilization, Mixing, and Flocculation. In: Water Quality and Treatment, 4th edition, F. W. Pontius, (Ed.). McGraw-Hill, New York 1990, pp. 269–365
Horn, A. F., Merrill, E.W.: Midpoint Scission of Macromolecules in Dilute Solution in Turbulent Flow. Nature 312 (1984) 140, 141
Nouvel, M., Amirtharajah, A.: Rapid Mix of Organic Polymers in Direct Filtration. In: Proceedings AWWA Annual Conference, AWWA, Dallas, Texas 1993
Stump, V.L., Novak, J.T.: Polyelectrolyte Selection for Direct Filtration. Journal AWWA 71 (1) (1979) 338
Leu, R.J., Ghosh, M.M.: Polyelectrolyte Characteristics and Flocculation. Journal AWWA 80 (1) (1988) 159
Keys, R.O., Hogg, R.: Mixing Problems in Polymer Flocculation. Water-1979 American Institute of Chemical Engineers Symposium Series 190 (75) (1978) 63
Yeh, H.H., Ghosh, M.M.: Selecting Polymers for Direct Filtration. Journal AWWA 73 (1) (1981) 211
Brink, D.R., Choi, S.I., Al-Ani, M., Hendricks, D.W.: Bench Scale Evaluation of Coagulants for Low Turbidity Water. Journal AWWA 80 (4) (1988) 199
Amirtharajah, A., Tambo, N.: Mixing in Water Treatment. In: Mixing in Coagulation and Flocculation, A. Amirtharajah, M. M. Clark, and R. R. Trussell (Eds.). AWWA Research Foundation, Denver, Colorado 1991, pp. 3–34
Miller, D.C.: Comparison of Impellers for Rapid Mixing of Organic Polymer Coagulants. Unpublished Masters Special Research Problem, Georgia Institute of Technology, Atlanta, Georgia 1992
Oldshue, J.Y., Trussell, R.R.: Design of Impellers for Mixing. In: Mixing in Coagulation and Flocculation, A. Amirtharajah, M. M. Clark, and R. R. Trussell (Eds.). AWWA Research Foundation, Denver, Colorado 1991, pp. 309–342
Pani, M.E., Muschelknautz, E.: Static Mixers and Their Applications. International Chemical Engineering 22 (2) (1982) 197
Mutsakis, M., Rader, R.: Static Mixers Bring Benefits to Water/Wastewater Operations. Water/Engineering and Management 133 (11) (1986) 30
Clark, M.M.: Scale-Up of Laboratory Flocculation Results. In: Proceedings AWWA Annual Conference, AWWA, Denver, Colorado 1986, pp. 1239–1256
Bourne, J.R., Lenzner, J., Petrozzi, S.: Micromixing in Static Mixers: An Experimental Study. Industrial Engineering Chemistry Research 31 (4) (1992) 1216
Bourne, J.R., Maire, H.: Influence of the Kinetic Model on Simulating the Micromixing of 1-Naphthol and Diazotized Sulfanilic Acid. Industrial Engineering Chemistry Research 30 (6) (1991) 1385
Schulgen, B.F.: Effectiveness of Static Mixers for Coagulation in Water Treatment. Unpublished Masters Thesis, Georgia Institute of Technology, Atlanta, Georgia 1995
Burke, J.C.: Effectiveness of Static Mixers for Enhanced Coagulation. Unpublished Masters Special Research Problem, Georgia Institute of Technology, Atlanta, Georgia 1996
USEPA.: National Primary Drinking Water Regulations; Disinfectants and Disinfection Byproducts; Proposed Rule. Federal Register 59:145 (June 29, 1994 ) 38668
Clark, M.M., Srivastava, R.M., Lang, J.S., Trussell, R.R., McCollum, L.J., Bailey, D., Christie, J.D., Stolarik, G.: Selection and Design of Mixing Processes. AWWA Research Foundation, Denver, Colorado 1994
Engleman, M.S.: CFD–An Industrial Perspective. In: Incompressible Computational Fluid Dynamics: Trends and Advances, M. D. Gunzburger and R. A. Nicolaides (Eds.). Cambridge University Press, London 1993, pp. 67–86
Jones, W.P., Launder, B.E.: The Prediction of Laminarization with a Two-Equation Model of Turbulence. International Journal of Heat and Mass Transfer 15 (1972) 301
Baldyga, J., Henczka, M.: Closure Problem for Parallel Chemical Reactions. The Chemical Engineering Journal 58 (1995) 161
Park, W.G., Sankar, L.N.: Dynamic Stall Simulation of a NACA 0012 Airfoil Using the Primitive Variable Formulation. In: Advances in Computational Methods in Fluid Dynamics FED-196, K. N. Ghia, U. Ghia, and D. Goldstein (Eds.). American Society of Mechanical Engineers, New York 1994, pp. 59–65
Yoon, S., Kwak, D.: Three-Dimensional Incompressible Navier-Stokes Solver Using Lower-Upper Symmetric-Gauss-Seidel Algorithm. AIAA Journal 29 (6) (1990) 874
Jones, S.C., Amirtharajah, A., Sankar, L.N.: Static Mixers for Coagulation in Water Treatment: A Computational Fluid Dynamics Model. In: Proceedings AWWA Annual Conference, AWWA, Toronto 1996
White, F.M.: Viscous Fluid How. McGraw Hill, New York 1991, p. 120.
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Amirtharajah, A., Jones, S.C. (1996). Mixing for Coagulation: Organic Polymers, Static Mixers, and Modeling. In: Hahn, H.H., Hoffmann, E., Ødegaard, H. (eds) Chemical Water and Wastewater Treatment IV. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61196-4_1
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DOI: https://doi.org/10.1007/978-3-642-61196-4_1
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