Abstract
We present an overview of our theoretical studies of the Eley-Rideal dynamics of the reaction of gas-phase H(D) with D(H) adsorbed on Cu(111). The studies are based on a three-dimensional flat-surface model and an empirical potential energy surface. Results for reactive cross sections and rovibrational HD product state distributions are presented. The pronounced isotope effects on the vibrational state distribution are shown to have a simple dynamical origin. Our predictions for these product distributions are in semi-quantative agreement with experiments, whereas the calculated and measured reactive cross section disagree.
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References
K. R. Lykke and B. D. Kay, in: Laser Photoionization and Desorption Surface Analysis Techniques, vol. 1208, ed. N. S. Nogar, (SPIE, Belling-ham, WA, 1990) p. 18.
E. W. Kuipers, A. Vardi, A. Danon, and A. Amirav, Phys. Rev. Lett. 66, 116 (1991).
C. T. Rettner, Phys. Rev. Lett. 69, 383 (1992).
C. T. Rettner and D. J. Auerbach, Science 263,365 (1994).
C. T. Rettner, J. Chem. Phys. 101, 1529 (1994).
C. T. Rettner and D. J. Auerbach, Phys. Rev. Lett. 74, 4551 (1995).
C. T. Rettner and D. J. Auerbach, J. Chem. Phys. (in press)
J. Harris and B. Kasemo, Surf. Sci. 105, L281 (1981).
P. Kratzer and W. Brenig, Surf. Sci. 254, 275 (1991).
B. Jackson and M. Persson, J. Chem. Phys. 96, 2378 (1992);
B. Jackson and M. Persson, Surf. Sci. 269/270, 195 (1992).
B. Jackson, M. Persson, and B. D. Kay, J. Chem. Phys. 100, 7687 (1994).
D. D. Koleske, S. M. Gates, and B. Jackson, J. Chem. Phys. 101, 3301 (1994).
M. Persson and B. Jackson, J. Chem. Phys. 102, 1078 (1995).
M. Persson and B. Jackson, Chem. Phys. Lett. 237, 468 (1995).
B. Jackson and M. Persson, J. Chem. Phys. 103, 6257 (1995).
See the separate contributions by Michelsen et al., B. Hay den, and S. Holloway in Surface Reactions ed. R.J. Madix (Springer, Berlin, 1993).
C. T. Rettner, H. A. Michelsen, and D. J. Auerbach, J. Chem. Phys., 102, 4265 (1995).
B. Hammer, M. Schefler, K. W. Jacobsen, and J. K. Nørskov, Phys. Rev. Lett. 73 (1994) 1400.
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© 1996 Springer-Verlag Berlin Heidelberg
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Jackson, B., Persson, M. (1996). Eley-Rideal Dynamics of the Reaction of Gas-Phase H(D) with D(H) on Cu(111). In: Okiji, A., Kasai, H., Makoshi, K. (eds) Elementary Processes in Excitations and Reactions on Solid Surfaces. Springer Series in Solid-State Sciences, vol 121. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-61185-8_2
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DOI: https://doi.org/10.1007/978-3-642-61185-8_2
Publisher Name: Springer, Berlin, Heidelberg
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