Skip to main content
SpringerLink
Log in

Sorption Processes

  • Conference paper
Batch Processing Systems Engineering

Part of the book series: NATO ASI Series ((NATO ASI F,volume 143))

  • 528 Accesses

Abstract

The scientific basis for the design and operation of sorption processes is reviewed. Examples of adsorptive processes, such as liquid phase adsorption, parametric pumping and chromatography, are discussed. A new concept arising from the use of large-pore materials is presented and applied to the modeling of HPLC and pressure swing adsorption processes. Numerical tools to solve the model equations are addressed.

Lecturer

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Rodrigues, A.: Modeling of percolation process. In Percolation Processes: Theory and Applications, ed. A. Rodrigues and D. Tondeur, pp 31–81, Nijtholf and Noordhoff, 1981

    Google Scholar 

  2. Rodrigues, A.: Mass transfer and reaction in fixed-bed heterogeneous systems: application to sorption operations and catalytic reactors. In Disorder and Mixing, ed. E. Guyon, et al, pp 215–236, Kluwer Acad. Pubs., 1988

    Google Scholar 

  3. De Vault, D.: The theory of chromatography. J. Am. Chem. Soc., 65, 532 (1943)

    Article  Google Scholar 

  4. Thomas, H. C.: Heterogeneous ion exchange in a flow system. J. Am. Chem. Soc., 66, 1664 (1944)

    Article  Google Scholar 

  5. Bohart, G. and Adams, E.: Some aspects of the behavior of charcoal with respect to diclorine. J. Am. Chem. Soc., 42, 523(1920)

    Google Scholar 

  6. Walter, J.: Rate dependent chromatography adsorption. J. Chem. Phy., 13, 332(1945)

    Google Scholar 

  7. Rodrigues, A.: Theory of linear and nonlinear chromatography. In Chromatographic and Membrane Processes in Biotechnology, ed. C. Costa and J. Cabral, Kluwer Academic. Pubs., 1991

    Google Scholar 

  8. Arnold, F., Schofield, S. and Blanch, H.: Analytical affinity chromatography. J. Chromat. 355, 1–12 (1986)

    Article  Google Scholar 

  9. Chase, F.: Prediction of performance of preparative affinity chromatography. J. Chromat. 297, 179–202 (1984)

    Article  Google Scholar 

  10. Rosen, J.: Kinetics of fixed-bed system for solute diffusion into spherical particles. Ind. Eng. Chem. 20(3). 387 (1952)

    Google Scholar 

  11. Rodrigues, A.: Percolation theory I - Basic principles. In Stagewise and Mass Transfer Operations, ed. J. Calo and E. Henley, AIChEMl., 1984

    Google Scholar 

  12. Rodrigues, A. and Costa, C.: Fixed-bed processes: a strategy for modeling. In: Ion Exchange: Science and Technology, pp 272–287, M.Nijthoff, 1986

    Google Scholar 

  13. Costa, C. and Rodrigues, A.: Design of cyclic fixed-bed adsorption processes I. AIChE J. 31, 1645–1654 (1985)

    Article  Google Scholar 

  14. Costa, C. and Rodrigues, A.: Intraparticle diffusion of phenol in macroreticular adsorbents. Chem. Eng. Sci., 40, 983–993 (1985)

    Article  Google Scholar 

  15. Wilhelm, R. Rice, A. and Bendelius, A.: Parametric pumping: A dynamic principle for separating fluid mixtures. Ind. Eng. Chem. Fund.,5, 141–144 (1966)

    Article  Google Scholar 

  16. Ramalho, E., Costa, C., Grevillot, G. and Rodrigues, A.: Adsorptive parametric pumping for the purification of phenolic effluents. Separations Technology, 1, 99–107 (1991)

    Article  Google Scholar 

  17. Costa, C., Grevillot, G., Rodrigues, A. and Tondeur, D.: Purification of phenolic waste water by parametric pumping. AIChE J., 28, 73 (1982)

    Article  Google Scholar 

  18. Almeida, F. Costa, C., Grevillot, G. and Rodrigues, A.: Removal of phenol from waste water by recuperative mode parametric pumping. In: Physicochemical Methods for Water and Wastewater Treatment. ed. L. Pawlowski, pp.169–178, Elsevier, 1982

    Google Scholar 

  19. Ferreira, L. Costa, C. and Rodrigues, A.: Scale up of adsorptive parametric pumping. Annual AIChE mt., LA, 1991

    Google Scholar 

  20. Tsewtt, M.: On a novel class of adsorption phenomena and their use in biochemical analysis. Trudi Varshayskogo obstchestva estestvoispitatelei, 40, 20–39 (1903)

    Google Scholar 

  21. Nicoud, R and Bailly, M: Choice and optimization of operating mode in industrial chromatography. In: PREP-92, ed. M. Perrut, 1992

    Google Scholar 

  22. Bailly, M. and Tondeur, D Reversibility and performance in productivity chromatography. Chem. Eng. Process., 18, 293–302 (1984)

    Article  Google Scholar 

  23. Bailly, M. and Tondeur, D.: Two way chromatography. Chem. Eng. Sci., 36, 455–469 (1981)

    Article  Google Scholar 

  24. Broughton, D.: Adsorptive separations-liquids. In: Kirk-Othmer Enc. of Chem. Techn., Vol.1, J. Wiley, 1978

    Google Scholar 

  25. De Rosset, A.: Neuzil, R and Broughton, D.: Industrial application of preparative chromatography. In: Percolation Processes: Theory and Applications, ed. A. Rodrigues and D. Tondeur, pp 249, Nijtholf and Noordhoff, 1981

    Google Scholar 

  26. Johnson, J.: Sorbex: continuing innovation in liquid phase adsorption. In: Adsorption: Science and Technology, pp383–395, M. Nijthoff, 1989

    Google Scholar 

  27. Stord, G., Masi, M and Morbidelli, M.: On counter current adsorption separation processes. In Adsorption: Science and Technology, pp 357–382, M. Nijhoff, 1989

    Google Scholar 

  28. Nielsen, A., Bergd, S. and Troberg, B.: Catalyst for the synthesis of ammonia and method of producing it. US Patent 3,243,386, (1966)

    Google Scholar 

  29. Wheeler, A.: Reaction rates and selectivity in catalyst pores. Adv. in Catalysis, 3, 250–337 (1951)

    Google Scholar 

  30. Nir, A. and Pismen, L.: Simultaneous intraparticle convection, diffusion and reaction in a porous catalyst. Chem. Eng. Sci., 32, 35–41 (1977)

    Article  Google Scholar 

  31. Rodrigues, A, Aim, B. and Zoulalian, A.: Intraparticle forced convection effect in catalyst diffusivity measurement and reactor design. AIChE J., 28, 541–546 (1982)

    Article  Google Scholar 

  32. Afeyan, A. Regnier, F. and Dean, R.: Perfusive chromatograph. US Pat. 5,019,270, (1990)

    Google Scholar 

  33. Afeyan, A. Gordon, N., Mazsareff, I., Varady, L.,Fulton, S., Yang, Y. and Regnier, F.: Flow through particles for the HPLC separation of biomolecules: Perfusion chromatography. J. Chromat., 519, 1–29 (1990)

    Article  Google Scholar 

  34. Rodrigues, A.E., Lu, Z.P. and Loureiro, J.M.: Residence Time Distribution of Inert and Linearly Adsorbed Species in Fixed-Bed Containing `Large-Pore’ Supports: App. in Sep. Eng. Chem. Eng. Sci., 46, 2765–2773 (1991)

    Article  Google Scholar 

  35. Rodrigues, A.E., Lopes, J.C., Lu, Z.P., Loureiro J. M. and Dias, M.M.: Importance of Intraparticle Convection on the Performance of Chromatographic Processes. 8th. Intern. Symp. Prep. Chromat. ‘PREP-91“, Arlington, VA; J. Chromatography, 590. 93–100 (1992)

    Google Scholar 

  36. Rodrigues, A.: An extended Van Deemter equation (Rodrigues equation) for the performance of chromatographic processes using large-pore, permeable packings. submitted to LC-GC, 1992

    Google Scholar 

  37. Van Deemter, J. Zuiderwveg, F. and Klinkenberg, A.: Longitudinal diffusion and resistance to mass transfer as causes of nonideality in chromatography. Chem. Eng. Sci., 5, 271–289 (1956)

    Article  Google Scholar 

  38. Lu, Z.P., Loureiro, J.M., LeVan, M.D. and Rodngues, A.E.: Effect of Intraparticle Forced Convection on Gas Desorption from Fixed-Bed Containing ‘Large-Pore’ Adsorbents. Ind. Eng. Chem. Res., 35, 1530 (1992)

    Article  Google Scholar 

  39. Lu, Z.P., Loureiro, J.M., LeVan, M.D. and Rodrigues, A.E.: Intraparticle Convection Effect on Pressurization and Slowdown of Absorbers. AIChE J.,38, 857–867 (1992)

    Article  Google Scholar 

  40. Rodrigues, A.E., Loureiro, J.M. and LeVan, M.D.: Simulated Pressurization of Adsorption Beds. Gas Separation and Purification, 5, 115 (1991)

    Article  Google Scholar 

  41. Lu, Z.P., Loureiro, J.M., LeVan, M.D. and Rodrigues, A.E.:Intraparticle Diffusion/ Convection Models in Pressurization and Blowdown: Nonlinear Equilibrium“, Sep. Sci. Technol., 271(4), 1857–1874 (1992)

    Article  Google Scholar 

  42. Lu, Z.P., Loureiro, J.M., LeVan, M.D. and Rodrigues, A.E.: Pressurization and Blowdown of an Adiabadc Adsorption Bed: IV Diffusion/Convection Model. Gas Sep & Purif. 6 (2), 89–100, (1992)

    Article  Google Scholar 

  43. Sereno, C. Rodrigues, A. and Villadsen, J.: Solution of partial differential equations systems by the moving finite element method. Computers Chem Engng., 16, 583–592 (1992)

    Article  Google Scholar 

  44. Loureiro, J. and Rodrigues, A.: Two solution methods for hyperbolic systems of partial differential equations in chemical engineering. Chem Eng. Sci.,46, 3259–3267 (1991)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratory of Separation and Reaction Engineering, School of Engineering, University of Porto, 4099, Porto Codex, Portugal

    Alirio E. Rodrigues & Lu Zuping

Authors
  1. Alirio E. Rodrigues
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lu Zuping
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. School of Chemical Engineering, Purdue University, West Lafayette, IN, 47907, USA

    Ginraras V. Reklaitis

  2. Department of Chemical Engineering, College of Engineering University of South Florida, 4202 East Fowler Avenue, ENG 118, Tampa, FL, 33620-5350, USA

    Aydin K. Sunol

  3. Laboratory for Technical Chemistry, Eidgenössische Technische Hochschule (ETH) Zürich, Switzerland

    David W. T. Rippin

  4. Department of Chemical Engineering, Boğaziçi University, TR-80815, Bebek-Istanbul, Turkey

    Öner Hortaçsu

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Rodrigues, A.E., Zuping, L. (1996). Sorption Processes. In: Reklaitis, G.V., Sunol, A.K., Rippin, D.W.T., Hortaçsu, Ö. (eds) Batch Processing Systems Engineering. NATO ASI Series, vol 143. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60972-5_10

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-60972-5_10

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64635-5

  • Online ISBN: 978-3-642-60972-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation