Abstract
Group 4 metallocenes with bridged and substituted Ind and Cp/Flu ligands have produced high-molecular-weight isotactic (I-PP), syndiotactic (S-PP), atactic (A-PP) and hemi-isotactic (HIT-PP) (Scheme 1) polypropylenes.i
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Review: Brintzinger, H. H., Fischer, D.; Mulhaupt, R, Rieger, B., Waymouth, R. M... (1995) Angew. Chem. Int. Ed. Engl. 34: 1143
Ewen, J. A., Jones, R. L., Elder, M. J., Rheingold, A. L, and Liable-Sands, L.M. (1998) J. Amer. Chem. Soc. 120: 10786
Ewen, J. A. (1997) Scientific American, 276, (5): 6355
Ewen, J. A., Haspeslagh, L., Elder, M. J., Atwood, J. L., Zhang, H., and Cheng, H. N. (1988) in Transition Metals and Organometallics as Catalysts for Olefin Polymerization, W. Kaminsky and H. Sinn, Eds.; Springer-Verlag: New York, pp. 281–289
Miya, S., Yoshimura, T., Mise, T., Yamazaki, H. (1988). Polym. Prepr. Jpn. 37: 285
Miya, S., Mise, T, Yamazaki, H. (1989) Chem. Lett., 1953
Miya, S., Mise T., Yamazaki H., (1990) Stud. Surf. Sci. Catal. 56: 531.
Spaleck, W., Küber, F., Winter, A., Rohrmann, J., Bachmann, B., Antberg, M., Dolle, V., Paulus, E. F. (1994) Organometallics, 13: 954
Ewen, J. A., Jones, R. L., Razavi, A., Ferrara, J. D. (1988) J. Amer. Chem. Soc. 110: 6255
Ewen, J. A, Elder, M. J., Jones, R. L, Curtis, S., and Cheng, H. P. (1990 Stud. Surf. Sci. 56: 271
Ewen, J. A, Elder, M. J, (1995) in Ziegler Catalysts, (G. Fink, R. Mulhaupt, H. H. Brintzinger, Eds.) Springer-Verlag, Berlin, Heidelberg, New York, London, Paris, Tokyo, Hong Kong, Barcelona, Budapest, p. 99
Spaleck, W., Antberg, M., Rohrman, J., Winter, A., Bachmann, B., Kiprof, P., Behm, J., Herrmann, W. A. (1992) Angew. Chem. Int. Ed. Engl. 31: 1347
Ewen, J. A., Elder, M. J., Jones, R. L., Haspeslagh, L. Atwood, J. L., Bott, S. G., Robinson, K. (1991) Makromol. Chem., Macromol. Symp. 48/49: 253.
O. Meth-Cohn, S. Gronowitz, (1966) Acta Chemica Scandinavica, 20: 1577
Volz, H. and Kowarsch, H. (1976) Tet. Lett. 48: 4375.
Volz, H., Zimgib, U, Meßner, B. (1970) Tetrahedron Lett. 4: 3593.
Voltz, H., Meßner, B. (1969) Tetrahedron Lett. 47: 4111.
Hidetsra, C., Shinsuke, M. (1996) Heterocycles, 43:127.
Shapiro, R. H.; Heath, M. J. (1967) J. Am. Chem. Soc. 89: 5374.
Kraak, A., Wiersema, A. K, Jordans, P, Wynberg, H. (1968) Tetrahedron, 24: 3381.
van der Leek, Y., Angermund, K., Reffke, M., Kleinschmidt, R., Goretzki, R., Fink, G. (1997) Chem. Eur. J. 3: 585.
Cavallo, L., Guerra, G., Vacatello, M., Corradini, P. (1991) Macromolecules, 24: 1784.
Corradini, P., Busico, V., Cipullo, R. (1992) Makromol. Chem. Rapid Commun. 13: 21.
Guerra, G., Corradini, P., Cavallo, L., Vacatello, M.(1995) Makromol. Symp., 307.
Cavallo, L., Guerra, G. (1996). Macromolecules, 29: 2729.
Spaleck W., Antberg M., Rohrmann, J., Winter, A., Bachmann, B., Kiprof, P., Behim, J., Herrmann, A. (1995) in: Fink, G.; Mulhaupt, R., Brintzinger, H. H. Ziegler Catalysts; Springer-Verlag, Berlin: p. 84.
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Ewen, J.A., Jones, R.L., Elder, M.J. (1999). Expanding the Scope of Metallocene Catalysis: Beyond Indenyl and Fluorenyl Derivatives. In: Kaminsky, W. (eds) Metalorganic Catalysts for Synthesis and Polymerization. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60178-1_15
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