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Expanding the Scope of Metallocene Catalysis: Beyond Indenyl and Fluorenyl Derivatives

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Metalorganic Catalysts for Synthesis and Polymerization

Abstract

Group 4 metallocenes with bridged and substituted Ind and Cp/Flu ligands have produced high-molecular-weight isotactic (I-PP), syndiotactic (S-PP), atactic (A-PP) and hemi-isotactic (HIT-PP) (Scheme 1) polypropylenes.i

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Ewen, J.A., Jones, R.L., Elder, M.J. (1999). Expanding the Scope of Metallocene Catalysis: Beyond Indenyl and Fluorenyl Derivatives. In: Kaminsky, W. (eds) Metalorganic Catalysts for Synthesis and Polymerization. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-60178-1_15

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  • DOI: https://doi.org/10.1007/978-3-642-60178-1_15

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-64292-0

  • Online ISBN: 978-3-642-60178-1

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