Abstract
If a polymer is dissolved in a volatile liquid and this liquid is removed by spraying, the polymer forms fine fibers which may be deposited on a releasing surface as a fine, microporous fiber fleece (see Sect. 9.1). In this case the molecular weight of the polymer should be rather low so that the polymer is able to dissolve in the volatile liquid. Another possibility of creating micropores is to mix a nonsolvent into the polymer solution in the volatile liquid. If this nonsolvent is also able to evaporate and has a lower volatility than the solvent, micropores are produced in a similar way to the coagulation process.
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References
9.1 Spraying of Plymer solutions
US 2 999 788 (DuPont; PW Morgan; 22.1.59/12.9.61)
US 3 364 063 (Kendall Co.; D Satas; 20.7.64/16.1.68)
DAS 1 225 380 (Bayer AG; A Reischl, B Zorn; 4.6.64/22.9.66)=BE 664 870=NE 6 507 007
DDR 34 258 (VEB Kunstblume Sebnitz; E Pilz, E Augst; 27.12.63/28.12.64)
FR 1 501187 (Bayer AG; D Prior. 5.11.65; 4.11.66/10.11.67)=NE 6 615 459=DAS 1 267 841
FR 1 530 717 (Uniroyal Inc.; RN Steel, PV Butsatz, RT Nojiri; UR Prior. 31–5–66; 3i.5.67/28.6.68)=NE 6 707 452
US 3 496 056 (Uniroyal Inc.; RN Steel et al.; 6.2.69/17.2.70 div. from Appi, of Prior. 31.5.66, see also FR 1 530 717
US 2 950 752, (Am. Viscose Corp. 24.12.53); US 2 988 469, (Am. Viscose Corp. 22.12.59)
GB 1196 090 (Uniroyal Inc.; US Prior. 18.5.67; 194.68/24.6.7o)=FR 1 580 935=NE 6 806 362 =US 3 537 947
DBP 830 585 (Alkor; K Lissmann, L Wolf; 9.12.44/16.10.52)
FR1 298 959 (Kendall Co.; D Satas; US Prior. 23.5.60; 23.5.61/12.6.62)
JA 27 273/67 (Toyo Rubber Ind. Co. Ltd.; 13.7.64/23.12.67)
GB 1 081 406 (C Freudenberg; H Fabricius et al.; D Prior. 25.10.63; 28.10.64/31.8.67)
JA 13 156/66 (Teijin Co.Ltd.; 27.11.63/25.7.66)
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JA 2 233/68 (Teijin Co. Ltd.; 24.2.65/26.1.68)
JA 74–004 069 (Yuasa Battery Co. Ltd.; 30.6.66/30.1.74)
SZ 417 085 (C Freudenberg; E Demme et al.; 30.10.63/31.1.67)
DOS 4 425 793 (M Keppeler; 21.7.94/1.2.96); DOS 4 425 792 (M Keppeler; 21.7.94/1.2.96)
DOS 2 621141 (C Freudenberg; K Schmidt, H Hoffmann; 6.4.78)
JA 53 075 304 (Honey Chem. Ind.; 6.2.74/4.7.78)=JA 74–156 444+JA 74–14 246
9.2 Selective Evaporation Process
BE 652 899 (Feldmühle; OE Prior. 13.9.63; 10.9.64/4.1.65)=OE 246–093
One drop of a solvent is dropped on a paper at 20 °C and 66% air humidity. The paper becomes transparent. The time required to evaporate the drop is measured. (The paper becomes intransparent again.) The same is done with diethyl ether as a comparison. Then the time required to evaporate the solvent to be tested is divided by the time the diethyl ether needs to evaporate. The evaporation number is the quotient of this division. The evaporation number is a figure without a dimension (as e.g. second etc.) with diethyl ether as evaporation number as 1. It is measured according to DIN 53 170
DBP 1694 059 (Bayer AG; A Reischl, H Träubel, B Zorn; 3.1.66/3.6.7i)=BE 692 n6=FR 1510 261
A survey of solvent parameters of polymers and solvents can be found in: Bandrup J, Immergut EE (1966) Polymer handbook, vol I. New York, p 341 etc.; solvents and nonsolvents for different polymers are named in Bandrup J, Immergut EH (1966) Polymer handbook, 3rd ed. pp VII/391
OS 1 694179 (Bayer AG; A Reischl et al.; 9.8.67/26.8.71)=FR 1 578 378=NE 6 811 i67=BE 719 174
IUP 15=DIN 53 333, see Das Leder (1961) 86
OS 1 694 205 (Bayer AG; H Träubel, B Zorn; 12.10 67/4.11.71)=BE 706 920=NE 6 715 596, addition to OS 1 694 085
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JA 6 149/68 (Yuasa Battery Co.; 22.7.63/6.3.68)
JA 24 548/71 (Yuasa Battery Co.; 29.3.66/14.7.71)
BE 600 256 (DuPont; DT Bottorf, JL Hecht, VE James; US Prior. 7.2.60; 15.2.61/16.8.61)
GB 1 051 834 (Polymer Corp; GB Prior. 22.8.62; 16.8.63/21.12.66)
RA 226 835 (NA Abaturova, IN Vlodavets; 6.12.66/March 69)
NE 6 715 596 (Bayer AG; D Prior. 22.11.66; 16.11.67/24.5.68)
OS 1 619 213 (Ceskoslov. Zavody Gumarenski & Plastikavske; K Hlustik; CZ Prior. 18.7.66; 27.6.67/10.9.70)=DDR 63 36o=FR 1 531 873
JA 24 547/71 (Yuasa Battery Co. Ltd.; 25.3.66/14.7.71)
US 3 546 001 (Immont Corp.; Ch Giannone et al.; 11.2.69/8.12.70; cip. 16.5.66)
US 3 403 046 (Interchemical Corp.; FH Schwacke, Ch Giannone; 8.10.65/24.9.68)
OS 2 136 558 (Goodrich; WTh Murphy; 22.7.71/3.2.72; US Prior. 24.7.70)
OS 2 523 740 (Stamicarbon B. V.; AJ Pennings et al.; NE Prior. 30.5.74; 28.5.75/11.12.75)
JA 73–36 940 (Yuasa Battery Co. Ltd.; 29.12.70/8.11.71)
Träubel H (1991) Homogene und heterogene Raumkörper-Leder und seine mikroporösen Substitute; ein Vergleich. Das Leder 42:109
DE 3 507 467 (Bayer; K Nachtkamp et al.; 2.3.85/4.9.86); DE 3 521762 (Bayer; 19.6.85/2.1.87)
JA 59 179 636 [Tejin KK; 31.3.83/12.10.84 (53 741)]
GB 1135 463 (Interchemical Corp.; 9.5.66/4.12.68; US Prior. 16.6.65)=FR 1 514 955=SZ 479 655 =DE 1 619 255
WO 94 20 665 (Tejin Ltd.; K Okawa, K Sasaki, Y Suzuki; 10.3.93/15.9.94)=EP 640 715=JA 065 17 893; JA 062 64 369 (Teijin Cordley Ltd.; 10.3.93/20.9.94); JA 062 64 370 (Teijin Cordley Ltd.; 10.3.93/20.9.94); JA 062 64 371 (Teijin Cordley Ltd.; 10.3.93/20.9.94)
JA 79–157 803 (Fujikura Rubber Works; 1.6.78/13.12.79)=JA 78–66 140
JA 53 023 101 (Teijin KK; 7.9.76/27.3.78)=JA 76–106 228
9.3 Selective Evaporation Process of Dispersed Polymers
SZ 1 546/66 (Chemgene Corp.; R Smith-Johannsen; US Prior. 3.2.65; 3.2.66/15.10.69)=NE 6 601383
FR1547182 (Gurit AG; CH Prior. 28.12.66; 14.12.67/22.11.68)=NE 6 716 617
JA 49 111970 (Nikko Physiochem.Shik; 26.2.73/24.10.74)
OS 1 809 610 (BASF; CH Krauch, A Sanner; 19.11.68/11.6.70)
JA 49 111970 (Nikko Physiochem. Shik; 26.2.73/24.10.74)
JA 5117586 (Mitsubishi Kasei Corp.; 24.10.91/14.5.93)
DAS 1 045 359 (Göppinger Kaliko; W Gräbner; 22.6.56/4.1248)
FR 1554 754 (Teijin Ltd.; JA Prior. 7.11.66; 7.11.67/24.1.69)
NE 6 815 306 (Bayer; K König, H Träubel, A Reischl, B Zorn; D Prior. 25.10.67; 25.10.68/ 29.4.69)=OS 1 694 213
DAS 1 020 300 (HC Bick, RS Horn, RF Patt; US Prior. 21.11.51; 18.11.52/5.12.57)=FR 1 070 592 =GB 734 791=US 2 746 941
OS 2 004 276 (Teijin Ltd.; K Kigane et al.; JA Prior 31.1.69 (=JA 7 088–69); 30.1.70/24.9.70)= FR 2 033 850
JA 49 682/72 (Teijin Ltd.; 25.12.69/13.12.72)
OS 2 063 949 (PPG Industries Inc.; JA Steiner; US Prior. 22.6.70; 28.12.70/30.12.71)
NE 6 516 286 (USM Corp., US Prior. 18.12.64; 14–12.65/20.6.66)=FR 1 462 597
OE 213 367 (Göppinger Kaliko; 22.2.60/15.7.60)
JA 19 623/72 (Teijin Ltd.; 14.10.68/5.6.72)
JA 43 047/72 (Teijin Ltd.; 31.1.69/31.10.72)
OS 2 020 153 (Teijin Ltd.; K Kigane et al.; JA Prior. 2.4.69; 24.4.70/17.12.70)
JA 16 764/63 (Nippon Mikusani Kogyo KK; 21.8.61/3.9.63)
JA 6 196/66 (Nankai Gum Co.Ltd.; 12.2.62/1.4.66)
RA 164 579 (IV Plotnikov et al.; 15–1.62/Jan.65)
FR 1418 697 (IBM; P Chebiniak, RT Wiley; US Prior 30.12.63; 24.12.64/11.10.65)
OS 1469 597 (USM; CG. Newton; US Prior. 18.12.64; 18.12.65/2.1.69)
JA 49 067 952 (Nikko Shikiryo Kogyo KK; 4.11.72/2.7.74)
JA 49 130 476 (Teijin; 17.4.73/13.12.74)
JA 06 294 077 (94,394,077) (Achilles Corp.; K Oosawa, K Mitsumura, K Sugaya; 10.2.93/21.10.94)
JA 07145570 (Unitika Ltd.; T Furuta, K Kamemaru; 22.11.93/6.6.95)
JA 4202859 (Achilles Corp.; 29.11.90/23.7.93)
DOS 3 836 030 (Bayer AG; W Thoma, R Langel, W Schröer; 22.10.88/3.5.90); EP 238 991 (Bayer AG; W Thoma, R Langel et al.; 26.3.86/30.9.87); DOS 3 507 467 (Bayer AG; K Nachtkamp, W Thoma et al.; 2.3.85/4.9.86)
FR 2 384 058 (Adidas; H Dassler; 17.3.77/13.10.78)=DOS 2 711 579
JA 51 024 666 (Bando Chem. Ind. Ltd.; 23.8.74/28.2.76)
FR 1 488 995 (Soc. Anon. Peltex; 13.9.65/12.6.67)=NE 6 612 797=BE 686 221
JA 74 039 172 (Toyo Rubber Ind. Co.; 22.5.70/23.10.74)=JA 70–44137
FR 1337 536 (R. T. Vanderbilt Co. Inc.; RR Waterman et al.; 11.2.63/20.4.64; US Prior. 6.12.62)= US 62–242 653
JA 60 017 181 (Teijin KK; 4.7.83/29.1.85)=JA 83–120 316); JA 60 021 982 (Teijin KK; 4.2.83/ 8.7.83)=JA 83–129 557
DOS 3 327 862 (Dainichiseika Color & Chem. Mfg. Co. Ltd., Ukima Colour & Chem.; K Kuri-yama et al.; 2.8.83/14.2.85)
JA 63 286 466 (Dainichiseika Color Chem.; 20.5.87/24.11.88)=JA 87–121 089
JA 01138 263 (Dainichiseika Color Chem.; 26.11.87/31.5.89)=JA 87–295 963
JA 5117586 (Mitsubishi Kasei Corp.; 24.10.91/14.5.93)
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© 1999 Springer-Verlag Berlin Heidelberg
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Träubel, H. (1999). Microporosity by Evaporation of Volatile Products. In: New Materials Permeable to Water Vapor. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-59978-1_9
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DOI: https://doi.org/10.1007/978-3-642-59978-1_9
Publisher Name: Springer, Berlin, Heidelberg
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