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Stabilization and Regeneration of Spent Sorbents

  • Conference paper
Desulfurization of Hot Coal Gas

Part of the book series: NATO ASI Series ((ASIG,volume 42))

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Abstract

The sulfur compounds present in coal are converted to hydrogen sulfide when coal is gasified. To comply with environmental regulations, a high fraction of the sulfur must be removed from the product gas stream. Calcium-based sorbents are the prime candidates for in-bed capture of sulfur.

The removal of sulfur takes place through the reaction of hydrogen sulfide with calcium-based sorbent and produces calcium sulfide, which is not stable and therefore not suitable for disposal. Calcium sulfide, however, can be either reacted with oxygen to produce stable and environmentally acceptable compounds for disposal, or regenerated with water and carbon dioxide.

This paper addresses the effects of operating variables on the successful stabilization and regeneration of sulfide-containing solid wastes from coal gasifiers.

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References Cited

  1. Abbasian, J., Rehmat, A. and Banerjee, D. D., “Sulfation of Partially Sulfided Calcium-Based Sorbents,” Ind. Eng. Chem. Res. 30. No. 8, 1991.

    Google Scholar 

  2. Abbasian, J., Rehmat, A., Leppin, D. and Banerjee, D. D., “An Advanced Coal Gasification Desulfurization Process.” Paper presented at the 25th IECEC Conference, Reno, Nevada, August 1990.

    Google Scholar 

  3. Torres-Ordonez, R. J., Longwell, J. P. and Saroffin, A. F., “Physical Transformations During CaS(s) Oxidation,” Energy & Fuel 3,1989.

    Google Scholar 

  4. Torres-Ordonez, R. J., Longwell, J. P., and Saroffin, A. F., “Intrinsic Kinetics of CaS(s) Oxidation,” Energy & Fuel 3,1989.

    Google Scholar 

  5. Torres-Odronez, R., “The Oxidation of CaS(s) Crystals During Simulated Coal Combustion,” Ph.D. Thesis, Massachusets Institute of Technology, June 1986.

    Google Scholar 

  6. Kamphius, B., Potma, A. W. and Spitsbergen, U., “Regenerative Sorbents for High Temperature Desulfurization of Coal Combustion Gases.” Proceedings of the Sixth Annual International Pittsburgh Coal Conference 2,994, September 10-14,1990.

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  7. Yang, R. T. and Shen, M.-S., “Direct Evidence of the Existence of Gaseous Intermediates in the Calcium Sulfide-Calcium Sulfate Reaction,” AICHE J. 25, No. 3, 548 (1979).

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  8. Yang, R. T. and Shen, M.-S., “Calcium Silicate: A New Class of Highly Regenerative Sorbents for Hot Gas Desulfurization,” AICHE J. 25, No. 5, 812 (1979).

    Google Scholar 

  9. Pham, H. N., “An Oxidation Study of Fluidized-Bed Ashes Containing Calcium Sulfide.” Paper presented at AICHE Annual Meeting — Clean Coal Technology II Session, Chicago, November 11,1990.

    Google Scholar 

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© 1998 Springer-Verlag Berlin Heidelberg

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Abbasian, J. (1998). Stabilization and Regeneration of Spent Sorbents. In: Atimtay, A.T., Harrison, D.P. (eds) Desulfurization of Hot Coal Gas. NATO ASI Series, vol 42. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-58977-5_14

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  • DOI: https://doi.org/10.1007/978-3-642-58977-5_14

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-63810-7

  • Online ISBN: 978-3-642-58977-5

  • eBook Packages: Springer Book Archive

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