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Radical Isomerization Polymerization

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Macromolecular Science and Engineering

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 35))

Abstract

Generally, the monomers for radical polymerization are vinyl or vinylidene compounds. They afford the polymers which consist of a carbon-carbon single bond main chain through the normal addition polymerization mechanism. However, some monomer groups can rearrange during the propagation step, such as ring-opening reaction, ring-closing reaction, and atom or group transfer reaction [1]. Consequently, from these interesting monomers, unsaturated multiple bonds, ethers, ketones, esters, or miscellaneous functional groups can be produced on the main chain of the polymers.

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Authors
  1. Jun-ichi Sugiyama
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Editors and Affiliations

  1. Dept. of Polymer Physics, NIMC, Higashi 1-1, 305-8565, Tsukuba, Japan

    Yoshikazu Tanabe

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© 1999 Springer-Verlag Berlin Heidelberg

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Sugiyama, Ji. (1999). Radical Isomerization Polymerization. In: Tanabe, Y. (eds) Macromolecular Science and Engineering. Springer Series in Materials Science, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-58559-3_3

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  • DOI: https://doi.org/10.1007/978-3-642-58559-3_3

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-63645-5

  • Online ISBN: 978-3-642-58559-3

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