Ultrafast thermalization dynamics of hot photoelectrons injected into water

  • V. H. Vilchiz
  • J. A. Kloepfer
  • A. C. Germaine
  • V. A. Lenchenkov
  • S. E. Bradforth
Conference paper
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 66)

Abstract

We present results on the mechanism of solvated electron production by photoionization of water and photodetachment of iodide with 50fs deep-UV pulses. The relaxation of photoejected electrons from the two systems differs markedly, consistent with the suggestion that iodide detachment leads to an electron:iodine caged pair.

Keywords

Hydrated Petroleum Cage Recombination Iodine 

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Copyright information

© Springer-Verlag Berlin Heidelberg 2001

Authors and Affiliations

  • V. H. Vilchiz
    • 1
  • J. A. Kloepfer
    • 1
  • A. C. Germaine
    • 1
  • V. A. Lenchenkov
    • 1
  • S. E. Bradforth
    • 1
  1. 1.Department of ChemistryUniversity of Southern CaliforniaLos AngelesCA

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