Ultrafast thermalization dynamics of hot photoelectrons injected into water
We present results on the mechanism of solvated electron production by photoionization of water and photodetachment of iodide with 50fs deep-UV pulses. The relaxation of photoejected electrons from the two systems differs markedly, consistent with the suggestion that iodide detachment leads to an electron:iodine caged pair.
KeywordsHydrated Petroleum Cage Recombination Iodine
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- 5.Kloepfer, J. A; Vilchiz, V.H., Lenchenkov, V.A.; Bradforth, S.E. J. Chem. Phys. submitted; Kloepfer, J.A; Vilchiz, V.H.; Lenchenkov, V.A; Bradforth, S.E. Chem. Phys. Lett. 1998, 298, 120Google Scholar