Abstract
The importance of cycloaddition pathways in ion-molecule reactions has been the subject of recent investigations [1]. This is in some measure because of the importance of cycloaddition reactions in the synthesis of organic neutrals [2]. Indeed, the selection rules which govern the reactivity as well as regio- and stereo-selectivity of organic neutrals in solution are well established [31. There are now enough data available to test applicability of some of these selection rules to the cycloaddition reactions of radical cations and neutrals. Some of these concepts have been incorporated into a simple theory, a Frontier Molecular Orbital approach modified to take into account the unique features of radical cations [4].
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References
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Unpublished results, University of Nebraska
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Lay, J.O., Gross, M.L. (1982). Gas-Phase Radical-Ion Cycloadditions : Experiment and Theory. In: Ion Cyclotron Resonance Spectrometry II. Lecture Notes in Chemistry, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50207-1_13
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DOI: https://doi.org/10.1007/978-3-642-50207-1_13
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