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A Fourier Transform Ion Cyclotron Resonance Study of Negative Ion-Molecule Reactions of Phenyl Acetate, Phenyl Trifluoroacetate and Acetanilide

  • J. C. Kleingeld
  • N. M. M. Nibbering
Part of the Lecture Notes in Chemistry book series (LNC, volume 31)

Abstract

Recently we have shown by 18O-labelling [1] that in the gas-phase reaction of OH - with methyl phenyl ether (C6H5OCH3) 15% of the phenoxide anions (C6H5O-) are formed via an ipso substitution reaction (1a), whereas the remaining 85% are formed via an SN2 displacement [2] reaction 1b.

Keywords

Electron Beam Pulse Phenyl Acetate Phenyl Acetone Phenoxide Anion Methyl Phenyl Ether 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1982

Authors and Affiliations

  • J. C. Kleingeld
    • 1
  • N. M. M. Nibbering
    • 1
  1. 1.Laboratory of Organic ChemistryUniversity of Amsterdam1018 AmsterdamThe Netherlands

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