A Fourier Transform Ion Cyclotron Resonance Study of Negative Ion-Molecule Reactions of Phenyl Acetate, Phenyl Trifluoroacetate and Acetanilide

  • J. C. Kleingeld
  • N. M. M. Nibbering
Part of the Lecture Notes in Chemistry book series (LNC, volume 31)


Recently we have shown by 18O-labelling [1] that in the gas-phase reaction of OH - with methyl phenyl ether (C6H5OCH3) 15% of the phenoxide anions (C6H5O-) are formed via an ipso substitution reaction (1a), whereas the remaining 85% are formed via an SN2 displacement [2] reaction 1b.


Electron Beam Pulse Phenyl Acetate Phenyl Acetone Phenoxide Anion Methyl Phenyl Ether 
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Copyright information

© Springer-Verlag Berlin Heidelberg 1982

Authors and Affiliations

  • J. C. Kleingeld
    • 1
  • N. M. M. Nibbering
    • 1
  1. 1.Laboratory of Organic ChemistryUniversity of Amsterdam1018 AmsterdamThe Netherlands

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