Abstract
Aqueous solutions of electrolytes have been, among liquid systems, those most widely studied from a structural point of view, mainly because of the interest in the ionic hydration which is a central problem in chemical physics. The most widely used structural technique has been up to now X-ray diffraction which, in spite of its limitations when applied to non-crystalline materials, has provided, in recent years, important information about the structure of solutions [1–3]. The recent development of the EXAFS spectroscopy opens now new perspectives, so that it can be of interest to compare the two techniques in order to understand their capabilities in obtaining a reliable picture of the structural behaviour of aqueous solutions.
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Licheri, G., Pinna, G. (1983). EXAFS and X-Ray Diffraction in Solutions. In: Bianconi, A., Incoccia, L., Stipcich, S. (eds) EXAFS and Near Edge Structure. Springer Series in Chemical Physics, vol 27. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-50098-5_53
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DOI: https://doi.org/10.1007/978-3-642-50098-5_53
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