Abstract
This chapter deals with the study of nonequilibrium vibrational distributions created by the so-called vibration-vibration (V-V) up-pumping mechanism [2.1] (or Treanor’s mechanism) and with the effects of such a mechanism on chemical reactions of diatomic molecules. Treanor’s mechanism is responsible for the overpopulation of the vibrational distribution of a diatomic molecule under physical conditions characterized by large vibrational temperatures [θ1 = E10/k ln(N0/N1)] and small transiational ones (Tg). (E10 is the energy difference between level 1 and level 0, N1 and N2 being the corresponding population densities; k is Boltzmann’s constant.) Indeed, in this case V-V energy exchanges are more effective than vibration-translation (V-T) ones thus creating a quasi-stationary vibrational distribution made up of a Treanor’s distribution for the low-lying vibrational levels, a plateau, and a tail. The extension of this plateau depends on the effectiveness of V-V rates in overcoming the V-T ones [2.2–5].
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Cacciatore, M., Capitelli, M., De Benedictis, S., Dilonardo, M., Gorse, C. (1986). Vibrational Kinetics, Dissociation, and Ionization of Diatomic Molecules Under Nonequilibrium Conditions. In: Capitelli, M. (eds) Nonequilibrium Vibrational Kinetics. Topics in Current Physics, vol 39. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-48615-9_2
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