Abstract
There has been renewed interest in the spectroscopic and quantum-chemical investigation of linear polyenes, concerning the low-lying singlet excited state of forbidden symmetry(Ag in C2h). The last state is now approved to be lower than the first allowed level(1Bu) in most polyenes[1], as illustrated in Fig.l for the systems investigated in the present paper. It is also well known that this state has large contribution from a doubly excited electron configuration.
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© 1985 Springer-Verlag Berlin Heidelberg
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Kasama, A., Taya, M., Kamisuki, T., Adachi, Y., Maeda, S. (1985). Resonance CARS Study of α. ω-Diphenylpolyenes in the Electronic Excited States. In: Laubereau, A., Stockburger, M. (eds) Time-Resolved Vibrational Spectroscopy. Springer Proceedings in Physics, vol 4. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-47541-2_33
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DOI: https://doi.org/10.1007/978-3-642-47541-2_33
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