Abstract
The study of molecular dissociation processes is one of the most interesting areas of modern spectroscopy owing to the challenges presented by even the simplest of diatomic molecules. This paper reviews the commonly used descriptions of molecular dissociation processes for diatomic molecules, the selection rules for predissociation, and a few of the principles to be remembered when one is forced to speculate about dissociation mechanisms in a new molecule. Some of these points will be illustrated by the example of dissociative ionization in O2.
Work performed under the auspices of the U.S. Department of Energy and the Office of Naval Research.
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References
G. Herzberg: Spectra of Diatomic Molecules (Van Nostrand, Princeton 1950)
W. M. Gelbart: Ann. Rev. Phys. Chem. 28, 323 (1977)
H. Okabe: Photochemistry of Small Molecules (Wiley, New York 1978)
P.M. Dehmer, Y. A. Chupka: J. Chem. Phys. 62, 4525 (1975)
F. R. Gilmore: J. Quant. Spectrosc. Radiat. Transfer 5, 369 (1965)
R. W. Nicholls: J. Phys. B 1, 1192 (1968)
O. Edqvist, E. Lindholm, L.E. Sellin, L. Asbrink: Phys. Scr. 1, 25 (1970)
R.S. Freund: J. Chem. Phys. 54, 3125 (1971) and references therein
P. H. Krupenie: J. Phys. Chem. Ref. Data 1, 423 (1972)
See C.E. Brion, K.H. Tan, M.J. van der Wiel, Ph. E. van der Leeuw: J. Electron Spectrosc. Relat. Phenom. 17, 101 (1975) and references therein
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© 1983 Springer-Verlag Berlin Heidelberg
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Dehmer, P.M. (1983). Dissociation in Small Molecules. In: Tolk, N.H., Traum, M.M., Tully, J.C., Madey, T.E. (eds) Desorption Induced by Electronic Transitions DIET I. Springer Series in Chemical Physics, vol 24. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-45550-6_15
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DOI: https://doi.org/10.1007/978-3-642-45550-6_15
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