Abstract
In recent years, carbon nanotubes(CNTs) have attracted more and more attention due to their special electric structure, large specific surface area, hollow and layered structures, extraordinary mechanical and chemical stability properties and their widely potential applications. Especially, CNTs not only have a large electrons-storage capacity, but also show electronic conductivity similar to that of metals. Taking account of their 1D nano-structures and good electrical conductivity, it is reasonable to conclude that CNTs are beneficial to transport the electrons and enhance photoelectric conversion efficiencies of dye-sensitized solar cells (DSSCs). This review surveys the literature and highlights recent progress in the three possible applications (as counter electrode, anode, and electrolyte) of CNTs in DSSCs, and the mechanism of increasing electron transport and conversion efficiency is analyzed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Similar content being viewed by others
References
Saito Y, Kubo W, Kitamura T, Wada Y, Yanagida S (2004) I-/I3 - redox reaction behavior on poly (3,4-ethylenedioxythiophene) counter electrode in dye-sensitized solar cells. J Photochem Photobiol A Chem 164:153
Lee KM, Chiu WH, Wei HY, Hu CW, Suryanarayanan V, Hsieh WF, Ho KC (2010) Effects of mesoscopic poly(3,4-ethylenedioxythiophene) films as counter electrodes for dye-sensitized solar cells. Thin Solid Films 518:1716
Luo J, Niu HJ, Wu WJ, Wang C, Bai XD, Wang W (2012) Enhancement of the efficiency of dye-sensitized solar cell with multi-wall carbon nanotubes/polythiophene composite counter electrodes prepared by electrodeposition. Solid State Sci 14:145
Yu JG, Ma TT, Liu SW (2011) Enhanced photocatalytic activity of mesoporous TiO2 aggregates by embedding carbon nanotubes as electron-transfer channel. Phys Chem Chem Phys 13:3491
Zhang J, Li XX, Guo W, Hreid T, Hou JF, Su HQ, Yuan ZB (2011) Electropolymerization of a poly(3,4-ethylenedioxythiophene) and functionalized, multi-walled, carbon nanotubes counter electrode for dye-sensitized solar cells and characterization of its performance. Electrochim Acta 56:3147
Lee SU, Choi WS, Hong BY (2010) A comparative study of dye-sensitized solar cells added carbon nanotubes to electrolyte and counter electrodes. Energy Mater Sol Cells 94:680
Bhandari S, Deepa M, Srivastava AK, Lal C, Kant R (2008) Poly(3,4-ethylenedioxythiophene) (PEDOT)-Coated MWCNTs Tethered to Conducting Substrates: Facile Electrochemistry and Enhanced Coloring Efficiency Macromol Rapid Commun 29:1959
Byrne M, Gun’ko Y (2010) Recent Advances in Research on Carbon Nanotube–Polymer Composites. Adv Mater 22:1672
Bhandari S, Deepa M, Srivastava AK, Joshi AG, Kant R (2009) Poly(3,4-ethylenedioxythiophene)-Multiwalled Carbon Nanotube Composite Films: Structure-Directed Amplified Electrochromic Response and Improved Redox Activity. J Phys Chem B 113:9416
Abidian MR, Corey JM, Kipke DR, Martin DC (2010) Conducting polymer nanotubes improve electrical properties, mechanical adhesion, neural attachment, and neurite outgrowth of neural electrodes. Small 6:421
Shin HJ, Jeon SS, Im SS (2011) CNT/PEDOT core/shell nanostructures as a counter electrode for dye-sensitized solar cells. Synth Met 161:1284
Kay A, Gratzel M (1996) Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder. Sol Energy Mater Sol Cells 44:99
Suzuki K, Yamaguchi M, Kumagai M, Yanagiday S (2003) Application of carbon nanotubes to counter electrodes of dye-sensitized solar cells. Chem Lett 32:28
Lee WJ, Ramasamy E, Lee DY, Song JS (2008) Spray coated multi-wall carbon nanotube counter electrode for tri-iodide (I3 -) reduction in dye-sensitized solar cells. Sol Energy Mater Sol Cells 92:814
Ramasamy E, Lee WJ, Lee DY, Song JS (2008) Performance variation of carbon counter electrode based dye-sensitized solar cells. Electrochem Commun 10:1087
Zhu HW, Zeng HF, Subramanian V, Masarapu C, Hung KH, Wei BQ (2008) Anthocyanin-sensitized solar cell using carbon nanotube films as counter electrodes. Nanotechnology 19:465204-1
Cherepy NJ, Smestad GP, Gratzel M, Zhang JZ (1997) Ultrafast electron injection: Implications for a photoelectrochemical cell utilizing an anthocyanin dye-sensitized TiO2 nanocrystalline electrode. J Phys Chem B 101:9342
Wongcharee K, Meeyoo V, Chavadej S (2007) Dye-sensitized solar cell using natural dyes extracted from rosella and blue pea flowers. Sol Energy Mater Sol Cells 91:566
Hao SC, Wu JH, Huang YF, Lin JM (2006) Natural dyes as photosensitizers for dye-sensitized solar cell. Sol Energy 80:209
Huang Z, Liu XH, Li KX, Li DM, Luo YH, Li H, Song WB, Chen LQ, Meng QB (2007) Application of carbon materials as counter electrodes of dye- sensitized solar cells. Electrochem Commun 9:596
Lai WH, Su YH, Teoh LG, Hon MH (2008) Commercial and natural dyes as photosensitizers for a water-based dye-sensitized solar cell loaded with gold nanoparticles. J Photochem Photobiol 195:307
Robertson N (2006) Optimizing dyes for dye-sensitized solar cells. Angew Chem Int Ed 45:2338
Zhu HW, Wei JQ, Wang KL, Wu DH (2009) Applications of carbon materials in photovoltaic solar cells. Sol Energy Mater Sol Cells 93:1461
Xiao YM, Wu JH, Yue GT, Lin JM, Huang ML, Lan Z (2011) Low temperature preparation of a high performance Pt/SWCNT counter electrode for flexible dye-sensitized solar cells. Electrochim Acta 56:8545
Lee SU, Choi WS, Hong BY (2010) A comparative study of dye-sensitized solar cells added carbon nanotubes to electrolyte and counter electrodes. Sol Energy Mater Sol Cells 94:680
Im JS, Lee SK, Yun J, Lee YS (2012) CNT–Pt counter electrode prepared using a polyol process to achieve high performance in dye-sensitised solar cells. J Ind Eng Chem 25:581
Mathew A, Rao GM, Munichandraiah N (2011) Dye sensitized solar cell based on platinum decorated multiwall carbon nanotubes as catalytic layer on the counter electrode. Mater Res Bull 46:2045
Huang KC, Wang YC, Chen PY, Lai YH, Huang JH, Chen YH, Dong RX, Chuc CW, Lin JJ, Ho KC (2012) High performance dye-sensitized solar cells based on platinum nanoparticle/multi-wall carbon nanotube counter electrodes: The role of annealing. J Power Sources 203:274
Roh JY, Kim YH (2011) Synthesis of MWNTs using thermal chemical vapor deposition for the application of a counter electrode for DSSCs. Curr Appl Phys 11(S70):S69
Lin JY, Liao JH, Hung TY (2011) A composite counter electrode of CoS/MWCNT with highly electrocatalytic activity for dye-sensitized solar cells. Electrochem Commun 13:977
Peng SJ, Wu YZ, Zhu PN, Thavasi V, Mhaisalkar SG, Ramakrishna S (2011) Facile fabrication of polypyrrole/functionalized multiwalled carbon nanotubes composite as counter electrodes in low-cost dye-sensitized solar cells. J Photochem Photobiol A Chem 223:97
Li QH, Wu JH, Tang QW, Lan Z, Li PJ, Lin JM, Fan LQ (2008) Application of microporous polyaniline counter electrode for dye-sensitized solar cells. Electrochem Commun 10:101299
Sun HC, Luo YH, Zhang YD, Li DM, Yu ZX, Li KX, Meng QB (2010) In Situ Preparation of a Flexible Polyaniline/Carbon Composite Counter Electrode and Its Application in Dye-Sensitized Solar Cells. J Phys Chem C 114:11673
Kuan HC, Ma CCM, Chen KH, Chen SM (2004) Preparation, electrical, mechanical and thermal properties of composite bipolar plate for a fuel cell. J Power Sources 134:7
Liao SH, Hung CH, Ma CCM, Yen CY, Lin YF, Weng CC (2008) Preparation and properties of carbon nanotube-reinforced vinyl ester/nanocomposite bipolar plates for polymer electrolyte membrane fuel cells. J Power Sources 176:175
Yen MY, Yen CY, Liao SH, Hsiao MC, Weng CC, Lin YF, Ma CCM, Tsai MC, Sud A, Ho KK, Liu PL (2009) A novel carbon-based nanocomposite plate as a counter electrode for dye-sensitized solar cells. Compos Sci Technol 69:2193
Choi H, Kim H, Hwang S, Choi W, Jeon M (2011) Dye-sensitized solar cells using graphene-based carbon nano composite as counter electrode. Sol Energy Mater Sol Cells 95:323
Battumur T, Mujawar SH, Truong QT, Ambade SB, Lee DS, Lee WJ, Han SH, Lee SH (2012) Graphene/carbon nanotubes composites as a counter electrode for dye-sensitized solar cells. Curr Appl Phy. 12:49
Leary R, Westwood A (2011) Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis. Carbon 49:741
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56
Kongkanand A, Kamat PV (2007) Electron Storage in Single Wall Carbon Nanotubes. Fermi Level Equilibration in Semiconductor–SWCNT Suspensions. ACS Nano 1:13
Yu HT, Quan X, Chen S, Zhao HM (2007) TiO2–Multiwalled Carbon Nanotube Heterojunction Arrays and Their Charge Separation Capability. J Phys Chem C 111:12987
Yu Y, Yu CJ, Yu JG, Kwok YC, Che YK, Zhao JC, Ding L, Ge WK, Wong PK (2005) Enhancement of photocatalytic activity of mesoporous TiO2 by using carbon nanotubes. Appl Catal A 289:186
Muduli S, Lee W, Dhas V, Mujawar S, Dubey M, Vijayamohanan K, Han SH, Ogale S (2009) Enhanced Conversion Efficiency in Dye-Sensitized Solar Cells Based on Hydrothermally Synthesized TiO2–MWCNT Nanocomposites. ACS Appl Mater Interface 1:2030
Lee TY, Alegaonkar PS, Yoo JB (2007) Fabrication of dye sensitized solar cell using TiO2 coated carbon nanotubes. Thin Solid Films 515:5131
Yen CY, Lin YF, Liao SH, Weng CC, Huang CC, Hsiao YH, Ma CCM, Chang MC, Shao H, Tsai MC, Hsieh CK, Tsai CH, Weng FB (2008) Preparation and properties of a carbon nanotube-based nanocomposite photoanode for dye-sensitized solar cells. Nanotechnology 19:375305/1
Kim SL, Jang SR, Vittal R, Lee J, Kim KJ (2006) Rutile TiO2-modified multi-wall carbon nanotubes in TiO2 film electrodes for dye-sensitized solar cells. J Appl Electrochem 36:1433
Sawatsuk T, Chindaduang A, Sae-kung C, Pratontep S, Tumcharern G (2009) Dye-sensitized solar cells based on TiO2–MWCNTs composite electrodes: Performance improvement and their mechanisms. Diamond Relat Mater 18:524
Yu JG, Fan JJ, Cheng B (2011) Dye-sensitized solar cells based on anatase TiO2 hollow spheres/carbon nanotube composite films. J Power Sources 196:7891
Liu JW, Kuo YT, Klabunde KJ, Rochford C, Wu J, Li J (2009) Novel Dye-Sensitized Solar Cell Architecture Using TiO2-Coated Vertically Aligned Carbon Nanofiber Arrays. ACS Appl Mater Interface 1:1645
Yen MY, Hsiao MC, Liao SH, Liu PI, Tsai HM, Ma CCM, Pu NW, Ger MD (2011) Preparation of graphene/multi-walled carbon nanotube hybrid and its use as photoanodes of dye-sensitized solar cells. Carbon 49:3597
Sun SG, Gao L, Liu YQ (2011) Optimization of the cutting process of multi-wall carbon nanotubes for enhanced dye-sensitized solar cells. Thin Solid Films 519:2273
Lin WJ, Hsu CT, Tsai YC (2011) Dye-sensitized solar cells based on multiwalled carbon nanotube–titania/titania bilayer structure photoelectrode. J Colloid Interface Sci 358:562
Usui H, Matsui H, Tanabe N, Yanagida S (2004) Improved dye-sensitized solar cells using ionic nanocomposite gel electrolytes. J Photochem Photobiol A 164:97
Zhang YG, Zhao J, Sun BQ, Chen XJ, Li Q, Qiu LH, Feng YN (2012) Performance enhancement for quasi-solid-state dye-sensitized solar cells by using acid-oxidized carbon nanotube-based gel electrolytes. Electrochim Acta 61:185
Emery KA, Osterwald CR, Aharoni H (1987) Spectral mismatch correction for GaAs solar cells with varying junction depths. Solid State Electron 30:213
Akhtar MS, Park JG, Lee HC, Lee SK, Yang OB (2010) Carbon nanotubes–polyethylene oxide composite electrolyte for solid-state dye-sensitized solar cells Electrochim Acta 55:2418
Novák P, Müller K, Santhanam KSV, Haas O (1997) Electrochemically Active Polymers for Rechargeable Batteries. Chem Rev 97:207
Akhtar MS, Li ZY, Park DM, Oh DW, Kwak DH, Yang OB (2011) A new carbon nanotubes (CNTs)–poly acrylonitrile (PAN) composite electrolyte for solid state dye sensitized solar cells. Electrochim Acta 56:9973
Zhang XH, Wang SM, Xu ZX, Wu J, Xin L (2008) Poly(o-phenylenediamine)/MWNTs composite film as a hole conductor in solid-state dye-sensitized solar cells. J Photochem Photobiol A Chem 198:288
Acknowledgment
The authors are grateful for the support of the National Science Foundation of China (Grant No.21074031), Foundation of Heilongjiang Education Bureau.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Ma, L., Niu, H. (2015). Application of Carbon Nanotubes in Dye-Sensitized Solar Cells. In: Kar, K., Pandey, J., Rana, S. (eds) Handbook of Polymer Nanocomposites. Processing, Performance and Application. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-45229-1_35
Download citation
DOI: https://doi.org/10.1007/978-3-642-45229-1_35
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-45228-4
Online ISBN: 978-3-642-45229-1
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)