Porphyrins pp 109-109 | Cite as

Spectral data of zinc complex of porphyrin derivative C44H28N4Zn

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of zinc complex of porphyrin derivative C44H28N4Zn.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

7.79–7.71 (m, 12H, m-Ph, p-Ph),

8.22 (dd, 8H, o-Ph),

8.94 (s, 8H, βpyrr)

13 C NMR

121.1 (C5, 10, 15, 20),

126.5, 127.4 (Cβpyrr),

132.0, 134.4, 142.8

 

CHCl3

C6H6

422

(265 × 10−2),

552

(14 × 10−2),

594

(3.9 × 10−2),

422

(253 × 10−2)

548

(14 × 10−2),

588

(2.2 × 10−2)

 

[08Bos]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [08Bos]
    Boscencui, R., Socoteanu, R., Oliveira, A.S., Ferreira, L.F.V.: J. Serb. Chem. Soc. 73(7), 713–726 (2008)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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