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Porphyrins pp 108-108 | Cite as

Nuclear magnetic resonance data of ruthenium complex of porphyrin derivative C44H28N4Ru

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data of ruthenium complex of porphyrin derivative C44H28N4Ru.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

4.57 (m, P-Ar-Ho),

6.50 (t, 8H, J = 7.5, P-Ar-Hm),

6.77 (t, 8H, J = 7.3, P-Ar-Hp),

6.99 (d, 4H, J = 8.3, C ≡ ≡CAr-Ho),

7.16 (t, 4H, J = 7.5, C ≡ ≡CAr-Hm),

7.27 (t, 2H, J = 7.3, C ≡ ≡CAr-Hp),

7.46 (t, 8H, J = 7.8, meso-Arm),

7.54 (t, 4H, J = 7.3, meso-Arp),

7.60 (d, 8H, J = 6.8, meso-Aro),

8.13 (s, 8H, β-H)

   

orange/bronze crystals

[11Bon]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [11Bon]
    Bond, A.D., Sandersb, J.K.M., Stulz, E.: New J. Chem. 35, 2691–2696 (2011)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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