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Porphyrins pp 86-86 | Cite as

Spectral data of palladium complex of porphyrin derivative C44H27N5O2Pd

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of palladium complex of porphyrin derivative C44H27N5O2Pd.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

7.70-7.82 [m, 9H, Ho, Hp (M)],

8.16 [d, 6H, Hm (M)],

8.33 [d, 2H, Hm (Z)],

8.59 [d, 2H, Ho (Z), JHo,Hm = 8.3],

8.68 [d, 2H, Hβ (Z)],

8.82 [s, 4H, Hβ (M)],

8.85 [d, 2H, Hβ (Z), JHβ,Ho = 5.0]

 

CH2Cl2

416 (5.47),

485 (3.52),

524 (4.48),

555 (3.52)

 

[02Piz]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [02Piz]
    Pizzotti, M., Ugo, R.A., Elisabetta, S.Q., Ledoux-Rak, I., Zerbi, G., Zoppo, M.D., Fantucci, P., Invernizzi, I.: Inorg. Chim. Acta 340, 70–80 (2002)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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