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Porphyrins pp 692-692 | Cite as

Spectral data of osmium complex of porphyrin derivative C56H34Cl4N8O4Os

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data, infrared data and UV-visible spectral data of osmium complex of porphyrin derivative C56H34Cl4N8O4Os.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CD2Cl2

1 H NMR

2.31 (d, 4H, 9.3),

6.64 (d, 4H, 9.3),

7.78 (d, 8H, 6.3),

8.05 (d, 8H, 6.3),

8.91 (s, 8H)

1296,

1014,

924

C6H6

406 (4.7),

426sh (4.6),

500 (3.8),

576 (3.8),

622 (3.7)

red needles

[02Smi]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [02Smi]
    Smieja, J.A., Shirzad, K., Roy, M., Kittilstved, K., Twamley, B.: Inorg. Chim. Acta 335, 141–146 (2002)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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