Porphyrins pp 59-59 | Cite as

Spectral data of nickel complex of porphyrin derivative C44H24N8NiO8

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of nickel complex of porphyrin derivative C44H24N8NiO8.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

7.92 (apparent t, 4H, J = 7.9, H5-C6H4-NO2),

8.36 (apparent dt, 4H, J = 7.6, 1.4, H6-C6H4NO2),

8.64 (ddd, 4H, J = 8.3, 2.3, 1.1, H4-C6H4NO2),

8.71 (s, 8H, pyrrole-H),

8.91 (apparent t, 4H, J = 1.8, H2-C6H4-NO2)

 

CHCl3

327 (4.36),

417

(5.60, Soret),

529 (4.52),

557 (4.04)

 

[07Wyr]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

Reference

  1. [07Wyr]
    Wyrebek, P., Ostrowki, S.: J. Porphyrins Phthalocyanines 11, 822–828 (2007)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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