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Porphyrins pp 585-585 | Cite as

Spectral data of cobalt complex of porphyrin derivative C53H47BrCoN6Pd

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data and UV-visible spectral data of cobalt complex of porphyrin derivative C53H47BrCoN6Pd.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

4.07 (s, 12H, N(CH3)2),

4.13 (s, 3H, ArCH3),

4.16 (s, 6H, ArCH3),

5.47 (s, 4H, CH2N),

9.74 (br s, 6H, ArHp-tol),

12.57 (br s, 2H, ArHpincer),

13.06 (br s, 6H, ArHp-tol),

15.91 (br s, 8H, β-H)

 

CH2Cl2

413 (1.000),

530 (0.060)

red solid

[10Sui]

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [10Sui]
    Suijkerbuijk, B.M.J.M., Schamhart, D.J., Kooijman, H., Spek, A.L., van Koten, G., Klein Gebbink, R.J.M.: Dalton Trans. 39, 6198–6216 (2010)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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