Porphyrins pp 228-228 | Cite as

Spectral data of porphyrin derivative C46H33N3S

  • R. Gupta
Part of the Molecules and Radicals book series (volume 32C1)

Abstract

This chapter contains a tabular compilation of nuclear magnetic resonance data, infrared data and UV-visible spectral data of porphyrin derivative C46H33N3S.

Spectral Studies

2.1. Spectral Data of Porphyrins: Tetraphenyl and Analogous Porphyrins

Structure formula

NMR

IR

UV-visible

Remarks

Ref.

Solvent

Peaks δ [ppm]/nJ [Hz]

Peaks

Wave number

\( \tilde{v} \) [cm−1]

Solvent

Peaks

λ [nm]/(ε [M−1 cm−1]/log ε)

  

CDCl3

1 H NMR

−2.37 (s, 1H, −NH),

2.80 (s, 6H, −CH3),

7.72–7.77 (m, 12H, m, p-phenyl),

8.08–8.21 (m, 8H, o-phenyl),

8.45 (d, J = 4.39, 2H, β-pyrrole),

8.52 (d, J = 4.39, 2H, β-pyrrole),

8.87 (m, 2H, β-pyrrole)

3322,

3059,

2929,

710

toluene

430 (15.9),

516 (1.43),

550 (sh),

618 (0.21),

678 (0.41)

purple solid

[04Aga]

CDCl3

13 C NMR

18.36, 29.79, 32.02, 53.49, 123.72, 126.66, 127.16, 128.38, 129.99, 133.17, 133.87, 134.46, 138.78, 142.51, 144.94, 154.48, 158.80

Symbols and abbreviations

Short Form

Full Form

NMR

nuclear magnetic resonance

IR

infrared

UV-Visible

ultraviolet–visible

δ

chemical shift

γ

absorption band

λ

wavelength

ε

molar absorptivity

References

  1. [04Aga]
    Agarwal, N., Ravikanth, M.: Tetrahedron 60, 4739–4747 (2004)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • R. Gupta
    • 1
  1. 1.JaipurIndia

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