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Magnetism of Metal Phthalocyanines

  • Juan BartoloméEmail author
  • Carlos Monton
  • Ivan K. Schuller
Part of the NanoScience and Technology book series (NANO)

Abstract

Metal-phthalocyanine (MPc) are uniquely suited for the exploration of the intrinsic mechanisms which gives rise to molecular magnetism. In this chapter, we review the structural and magnetic properties of bulk crystal, thin film and single MPcs molecules adsorbed on different substrates. Traditional magnetic measurements and new techniques like x-ray magnetic circular dichroism show that the magnetic behavior of MPc molecules is strongly related with the electronic ground state of the central metal atom hybridized with the ligand states (intra-molecular interaction). In bulk and thin films, with stacked molecules, intermolecular exchange interactions between magnetic M atoms regulates their magnetic properties. Moreover experimental results show that the magnetic properties of single molecules are strongly affected by the electronic coupling to the supporting substrate.

Keywords

High Occupied Molecular Orbital Lower Unoccupied Molecular Orbital Central Metal Atom Kondo Effect Single Molecule Magnet 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

J. Bartolomé acknowledges financial support from the projects MINECO (MAT2011/23791) and DGA IMANA E34. C. Monton and I.K. Schuller acknowledge the financial support of AFOSR FA9550-10-1-0409. The magnetism aspects of this work were supported by the Office of Basic Energy Science, US Department of Energy, under Grant No. DEFG03-87ER-45332. Illuminating discussions with F. Bartolomé and G. Filoti are acknowledged.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  • Juan Bartolomé
    • 1
    Email author
  • Carlos Monton
    • 2
  • Ivan K. Schuller
    • 2
  1. 1.Instituto de Ciencia de Materiales de Aragón and Departamento de Física de la Materia CondensadaCSIC–Universidad de ZaragozaZaragozaSpain
  2. 2.Center for Advanced Nanoscience, Department of PhysicsUniversity of California San DiegoLa JollaUSA

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