Skip to main content

\(\mathrm {AB}_{2}\text {S}_{4}\) Ordered-Vacancy Compounds at High Pressures

  • Chapter
  • First Online:

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 189))

Abstract

In this chapter, an overview of the effects of pressure on the crystalline structure and physical properties of sulphur-based ordered-vacancy compounds of the \(\mathrm {A}^{\mathrm{{II}}} \mathrm {B}_{2}^{\mathrm{{III}}} \mathrm {X}_{4}^{\mathrm{{VI}}}\) family is presented. Recent X-ray diffraction and Raman spectroscopy studies are presented with a main focus on the discussion of pressure-induced phase transitions and their inherent cation and cation-vacancy disordering processes.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. MacKinnon A (1985) Tables of numerical data and functional relationships in science and technology, vol. 17. Springer-Verlag, Berlin, p. 124

    Google Scholar 

  2. Georgobiani AN, Radautsan SI, Tiginyanu IM (1985) Wide-gap A(II)B(III)\(_{2}\)C(VI)\(_{4}\) semiconductors—optical and photoelectric properties, and potential applications (review). Sov Phys Sem USSR 19:121–132

    Google Scholar 

  3. Bernard JE, Zunger A (1988) Ordered-vacancy compound semiconductors: pseudocubic CdIn\(_{2}\)Se\(_{4}\). Phys Rev B 37:6835–6856

    Article  Google Scholar 

  4. Jiang X, Lambrecht WRL (2004) Electronic band structure of ordered vacancy defect chalcopyrite compounds with formula II-III\(_{2}\)-VI\(_{4}\). Phys Rev B 69:035201(8)

    Google Scholar 

  5. Binsma JJM, Galing LJ, Bloem J (1981) Order-disorder behaviour and tetragonal distortion of chalcopyrite compounds. Phys Stat Sol A 63:595–603

    Article  Google Scholar 

  6. Zunger A (1987) Order-disorder transformation in ternary tetrahedral semiconductors. Appl Phys Lett 50:164–166

    Article  Google Scholar 

  7. Rincón C (1992) Order–disorder transition in ternary chalcopyrite compounds and pseudobinary alloys. Phys Rev B 45:12716–12719

    Google Scholar 

  8. Garbato L, Ledda F, Rucci A (1987) Structural distortions and polymorphic behavior in ABC\(_{2}\) and AB\(_{2}\)C\(_{4}\) tetrahedral compounds. Prog Cryst Growth Charact 15:1–41 and references therein

    Google Scholar 

  9. Tiginyanu IM, Ursaki VV, Fulga VN (1989) Order-disorder phase transition in the cation sublattice of ZnGa\(_{2}\)Se\(_{4}\). Sov Phys Semicond 23:1069–1070

    Google Scholar 

  10. Dietrich M, Unterricker S, Deicher M, Burchard A, Magerle R, Pfeiffer W, Forkel-Wirth D, Tiginyanu IM, Moldovyan NA (1996) Quadrupole interaction in defect chalcopyrite semiconductors studied by PAC. Cryst Res Technol 31(S2):853–856

    Google Scholar 

  11. Dietrich M, Unterricker S, Deicher M, Burchard A, Magerle R, Pfeiffer W, Forkel-Wirth D, Tiginyanu IM, Moldovyan NA (1996) PAC Investigation of ordered vacancy semiconductors of type \(\rm {A^{II}{B}_{2}^{III}{C}_{4}^{VI}}\). Hyperfine Interact C 1:242–245

    Google Scholar 

  12. Alonso-Gutiérrez P, Sanjuán ML, Morón MC (2009) Thermally activated catión ordering in Zn\(_{0.5}\)Mn\(_{0.5}\)Ga\(_{2}\)Se\(_{4}\) single crystals studied by Raman scattering. Phys Status Solidi C 6:1182–1186

    Article  Google Scholar 

  13. Caldera D, Morocoima M, Quintero M, Rincon C, Casanova R, Grima P (2011) On the crystal structure of the defective ternary compound ZnGa\(_{2}\)Se\(_{4}\). Solid State Commun 151:212–215

    Article  Google Scholar 

  14. Hahn H, Frank G, Klingler W, Stoerger AD, Stoerger G (1955) Über ternare chalcogenide des aluminiums, galliums und indiums mit zink, cadmium und quecksilber. Z Anorg Allgem Chemie 279:241–270

    Article  Google Scholar 

  15. Guseinov GG, Kerimova TG, Nani RK (1980) The refinement of crystal-structure of CdGa\(_{2}\)S\(_{4}\). Izvestiya Akademii Nauk Azerbaidzhanskoi SSR seriya Fisiko-Teknischeskikh i Matemticcheskikh Nauk 4:59–61

    Google Scholar 

  16. Schwer H, Kraemer V (1990) The crystal structure of CdAl\(_{2}\)S\(_{4}\), HgAl\(_{2}\)S\(_{4}\), and HgGa\(_{2}\)S\(_{4}\). Z Kristall 190:103–110

    Article  Google Scholar 

  17. Carpenter GB, Wu P, Gao YM, Wold A (1989) Redetermination of crystal structure of zinc thiogallate. Mater Res Bull 24:1077–1082

    Google Scholar 

  18. Lowe-Ma CK, Vanderah TA (1991) Structure of ZnGa\(_{2}\)S\(_{4}\), a defect sphalerite derivative. Acta Cryst C 47:919–924

    Article  Google Scholar 

  19. Gastaldi L, Simeone MG, Viticoli S (1985) Cation ordering and crystal structures in AGa\(_{2}\)X\(_{4}\) compounds (CoGa\(_{2}\)S\(_{4}\), CdGa\(_{2}\)S\(_{4}\), CdGa\(_{2}\)Se\(_{4}\), HgGa\(_{2}\)Se\(_{4}\), HgGa\(_{2}\)Te\(_{4})\). Solid State Commun. 55: 605–607 and referencies therein; Agostinelli E, Gastaldi L, Viticoli S (1985) Crystallographic and magnetic investigations on cobalt gallium sulfides: \(\alpha \)-CoGa\(_{2}\)S\(_{4}\) and \(\gamma \)-CoGa\(_{2}\)S\(_{4}\). J Phys Chem Solids 46:1345–1349

    Article  Google Scholar 

  20. Burlakov II, Raptis YS, Ursaki VV, Anastassakis E (1997) Order-disorder phase transition in CdAl\(_{2}\)S\(_{4}\) under hydrostatic pressure. Solid State Commun 101:377–381

    Article  Google Scholar 

  21. Ursaki VV, Burkalov II, Tiginyanu IM, Raptis YS, Anastassakis E, Aneda A (1999) Phase transitions in defect chalcopyrite compounds under hydrostatic pressure. Phys Rev B 59:257–268

    Article  Google Scholar 

  22. Meenakshi S, Vijyakumar V, Godwal BK, Eifler A, Orgzall I, Tkachev S, Hochheimer HD (2006) High pressure X-ray diffraction study of CdAl\(_{2}\)Se\(_{4}\) and Raman study of AAl\(_{2}\)Se\(_{4}\) (A = Hg, Zn) and CdAl\(_{2}\)X\(_{4}\) (X = Se, S). J Phys Chem Solids 67:1660–1667

    Google Scholar 

  23. Eifler A, Hecht JD, Lippold G, Riede V, Grill W, Krauss G, Krämer V (1999) Combined infrared and Raman study of the optical phonons of defect chalcopyrite single crystals. Physica B 263–264:806–808

    Article  Google Scholar 

  24. Eifler A, Krauss G, Riede V, Krämer V, Grill W (2005) Optical phonon modes and structure of ZnGa\(_{2}\)Se\(_{4}\) and ZnGa\(_{2}\)S\(_{4}\). J Phys Chem Solids 66:2052–2057

    Article  Google Scholar 

  25. Gomis O, Vilaplana R, Manjón FJ, Pérez-González E, López-Solano J, Rodríguez-Hernández P, Muñoz A, Errandonea D, Ruiz-Fuertes J, Segura A, Santamaría-Pérez D, Tiginyanu IM, Ursaki VV (2012) High-pressure optical and vibrational properties of CdGa\(_{2}\)Se\(_{4}\): order–disorder processes in adamantine compounds. J Appl Phys 111:013518 (15)

    Google Scholar 

  26. Manjón FJ, Gomis O, Vilaplana R, Sans JA, Ortiz HM (2013) Order–disorder processes in adamantine ternary ordered-vacancy compounds. Phys Stat Sol B 250: 1496-1504

    Google Scholar 

  27. Mitani T, Onari S, Allakhverdiev K, Gashimzade F, Kerimova T (2001) Raman scattering in CdGa\(_{2}\)S\(_{4}\) under pressure. Phys Stat Sol B 223:287–291

    Article  Google Scholar 

  28. Errandonea D, Kumar RS, Manjón FJ, Ursaki VV, Tiginyanu IM (2008) High-pressure x-ray diffraction study on the structure and phase transitions of defect-stannite ZnGa\(_{2}\)Se\(_{4}\) and defect-chalcopyrite CdGa\(_{2}\)S\(_{4}\). J Appl Phys 104:063524(9)

    Google Scholar 

  29. Meenakshi S, Vijyakumar V, Eifler A, Hochheimer HD (2010) Pressure-induced phase transition in defect chalcopyrites HgAl\(_{2}\)Se\(_{4}\) and CdAl\(_{2}\)S\(_{4}\). J Phys Chem Solids 71:832–835

    Article  Google Scholar 

  30. Sans JA (2013), to be published

    Google Scholar 

  31. Santamaría-Pérez D (2013), to be published

    Google Scholar 

  32. Gomis O, Santamaría-Pérez D, Vilaplana R, Luna R, Sans JA, Manjón FJ, Errandonea D, Pérez-González E, Rodríguez-Hernández P, Muñoz A, Tiginyanu IM, Ursaki VV (2013) Structural and elastic properties of defect chalcopyrite HgGa2S4 under high pressure. J Alloys and Comp doi:10.1016/j.jallcom.2013.08.123

  33. Grzechnik A, Ursaki VV, Syassen K, Loa I, Tiginyanu IM, Handfland M (2001) Pressure-induced phase transitions in cadmium thiogallate CdGa\(_{2}\)Se\(_{4}\). J Solid State Chem 160:205–211

    Article  Google Scholar 

  34. Marquina J, Power Ch, Grima P, Morocoima M, Quintero M, Couzinet B, Chervin JC, Munsch P, González J (2006) Crystallographic properties of the MnGa\(_{2}\)Se\(_{4}\) compound under high pressure. J Appl Phys 100:093513(6)

    Google Scholar 

  35. Hanada T (1998) Neutron and electron diffraction studies of ZnGa\(_{2}\)Se\(_{4}\). Physica B 241–243:373–375

    Google Scholar 

  36. Ackland GJ (2001) High-pressure phases of group IV and III-V semiconductors. Rep Prog Phys 64:483–516

    Article  Google Scholar 

  37. Mujica A, Rubio A, Muñoz A, Needs RJ (2003) High-pressure phases in group-IV, III-V, and II-VI compounds. Rev Mod Phys 75:863–912

    Article  Google Scholar 

  38. Bovornratanaraks T, Saengsuwan V, Yoodee K, McMahon MI, Hejni C, Ruffolo D (2010) High pressure orthorhombic structure of CuInSe\(_{2}\). J Phys Condens Matter 22:355801(4)

    Google Scholar 

  39. Xue HT, Tang FL, Lu WJ, Feng YD, Wang ZM, Wang Y (2013) First-principles investigatioin of structural phase transitions and electronic properties of CuGaSe\(_{2}\) up to 100 GPa. Comp Mat Sci 67:21–26

    Article  Google Scholar 

  40. Chelikovsky JR, Burdett JK (1986) Ionicity and the structural stability of solids. Phys Rev Lett 56:961–964

    Article  Google Scholar 

  41. Chelikowsky JR (1987) High-pressure phase transitions in diamond and zinc-blende semiconductors. Phys Rev B 35:1174–1180

    Article  Google Scholar 

  42. Ozolins V, Zunger A (1999) Theory of systematic absence of NaCl-Type ( \(\beta \)-Sn-Type) high pressure phases in covalent (Ionic) semiconductors. Phys Rev Lett 82:767–770

    Article  Google Scholar 

  43. Christensen NE, Satrathy S, Pawlowska Z (1987) Bonding and ionicity in semiconductors. Phys Rev B 36:1032–1050

    Article  Google Scholar 

  44. Jayaraman A, Dernier PD, Kasper HM, Maines RG (1977) Pressure induced phase transformations in some I-III-IV2 semiconductors. High Temp High Press 9:97–102

    Google Scholar 

  45. Serghiou G, Reichmann HJ, Boehler R (1997) Size criterion for amorphization of molecular ionic solids. Phys Rev B 55:14765–14769

    Article  Google Scholar 

  46. Errandonea D, Manjón FJ, Somayazulu M, Hausermann D (2004) Effects of pressure on the local atomic structure of CaWO\(_{4}\) and YLiF\(_{4}\): mechanism of the scheelite-to-wolframite and scheelite-to-fergusonite transitions. J Solid State Chem 177:1087–1097

    Article  Google Scholar 

  47. Beister HJ, Ves S, Honle W, Syassen K, Kuhn G (1991) Structural phase transitions and optical absorption of LiInSe\(_{2}\) under pressure. Phys Rev B 43:9635–9642

    Article  Google Scholar 

  48. Shannon RD (1976) Revised effective ionic-radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr Sect A Cryst Phys Diffr Theor Gen Crystallogr 32:751–767

    Article  Google Scholar 

  49. Kroumova E, Aroyo MI, Perez-Mato JM, Kirov A, Capillas C, Ivantchev S, Wondratschek H (2003) Bilbao crystallographic server : useful databases and tools for phase-transition studies. Phase Transitions 76:155–170

    Article  Google Scholar 

  50. Vilaplana R, Robledillo M, Gomis O, Sans JA, Manjón FJ, Pérez-González E, Rodríguez-Hernández P, Muñoz A, Tiginyanu IM, Ursaki VV (2013) Vibrational study of HgGa\(_{2}\)S\(_{4}\) under high pressure. J Appl Phys 113:093512(10)

    Google Scholar 

  51. Loudon R (1964) Raman effect in crystals. Adv Phys 13:423

    Google Scholar 

  52. Alonso-Gutiérrez P, Sanjuán ML (2008) Ordinary and extraordinary phonons and photons: Raman study of anisotropy effects in the polar modes of MnGa\(_{2}\)Se\(_{4}\). Phys Rev B 78:045212(9)

    Google Scholar 

  53. Luna R (2013), to be published

    Google Scholar 

  54. Allakverdiev KR (2001) Pressure induced phase transitions in GaSe-, TlGaSe\(_{2}\)-, and CdGa\(_{2}\)S\(_{4}\)-type crystals. Frontiers of high pressure research II: application of high pressure to low-dimensional novel electronic materials. Kluwer, Amsterdam, pp. 99–118

    Google Scholar 

  55. Klotz S, Besson JM, Braden M, Karch K, Pavone P, Strauch D, Marshall WG (1997) Pressure induced frequency shifts of transverse acoustic phonons in germanium to 9.7 GPa. Phys Rev Lett 79:1313–1316

    Article  Google Scholar 

  56. González J, Fernandez BJ, Besson JM, Gauthier M, Polian A (1992) High-pressure behavior of Raman modes in CuGaS\(_{2}\). Phys Rev B 46:15092–15101

    Article  Google Scholar 

  57. Anastasakis E, Cardona M (1998) High pressure in semiconductor physics, vol 2. Academic, New York, p. 152 and references therein

    Google Scholar 

  58. Sanjurjo JA, López-Cruz E, Vogl P, Cardona M (1983) Dependence on volume of the phonon frequencies and the ir effective charges of several III-V semiconductors. Phys Rev B 28:4579–4584 and references therein

    Google Scholar 

  59. Range KJ, Becker W, Weiss A (1968) Uber Hochdruckphasen des CdAl\(_{2}\)S\(_{4}\), HgAl\(_{2}\)S\(_{4}\), ZnAl\(_{2}\)Se\(_{4}\), CdAl\(_{2}\)Se\(_{4}\), und HgAl\(_{2}\)Se\(_{4}\) mit Spinell-struktur. Z Naturforschg 23b:1009–1009

    Google Scholar 

  60. Range KJ (1971) Hochdruckuntersuchungen and ternarën Chalkogeniden mit tetraedrisch koordinierten Kationen. Chem Zeitung 95:3–11

    Google Scholar 

  61. Kaempfer M, Neuhaus A (1972) Drucktransformationen von ZnGa \(_{2}\)S\(_{4}\), CdGa\(_{2}\)S\(_{4}\) un HgGa\(_{2}\)S\(_{4}\). Chemie-Ing Techn 44:946–946

    Google Scholar 

Download references

Acknowledgments

This study was supported by the Spanish government MEC under project MAT2010-21270-C04-04, by MALTA Consolider Ingenio 2010 project (CSD2007-00045), by Generalitat Valenciana under project GVA-ACOMP-2013-012 and by the Vicerrectorado de Investigación y Desarrollo of the Universidad Politécnica de Valencia (UPV2011-0914 PAID-05-11 and UPV2011-0966 PAID-06-11).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Francisco Javier Manjón .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Manjón, F.J., Vilaplana, R.I. (2014). \(\mathrm {AB}_{2}\text {S}_{4}\) Ordered-Vacancy Compounds at High Pressures. In: Manjon, F., Tiginyanu, I., Ursaki, V. (eds) Pressure-Induced Phase Transitions in AB2X4 Chalcogenide Compounds. Springer Series in Materials Science, vol 189. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-40367-5_5

Download citation

Publish with us

Policies and ethics