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Synthesis of Ti-MWW Zeolite

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Book cover MWW-Type Titanosilicate

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Abstract

Titanosilicate with MWW topology can be prepared by hydrothermal method, dry-gel method, and post-synthesis method. At first, the addition of B atoms in the synthesis gels was identified as the key factor for the successful synthesis of Ti-MWW under hydrothermal condition. Then, several alternative methods, for example, hydrothermal method with dual SDAs and post-synthesis method, were developed to provide B-less or B-free condition, which avoided a waste of B atoms as well as the framework acidity introduced by B atoms. Ti-MWW zeolites prepared by different methods varied in particle size and activity in liquid oxidation reactions, for example, the epoxidation of 1-hexene.

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Authors and Affiliations

  1. Department of Chemistry, East China Normal University, Shanghai, People’s Republic of China

    Peng Wu, Hao Xu, Le Xu, Yueming Liu & Mingyuan He

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  1. Peng Wu
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  2. Hao Xu
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  3. Le Xu
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  4. Yueming Liu
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  5. Mingyuan He
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Correspondence to Peng Wu .

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Wu, P., Xu, H., Xu, L., Liu, Y., He, M. (2013). Synthesis of Ti-MWW Zeolite. In: MWW-Type Titanosilicate. SpringerBriefs in Molecular Science(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-39115-6_2

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