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Multidimensional HPLC of Polymers pp 17–26Cite as

Theory of Polymer Chromatography

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Abstract

The retention of a species in liquid chromatography can be expressed in terms of the distribution coefficient relevant to the partition function of a polymer between the flowing and the stagnant liquid phase in the column, which correspond to the interstitial volume V i (i.e. the volume of the solvent outside the particles of the packing) and the pore volume V p.

$$ K=\frac{{{V_e}-{V_i}}}{{{V_p}}} $$

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Authors and Affiliations

  1. Department of Chemistry and Polymer Science, University of Stellenbosch, Stellenbosch, South Africa

    Harald Pasch

  2. Institute of Chemistry, Karl-Franzens-University Graz, Graz, Austria

    Bernd Trathnigg

Authors
  1. Harald Pasch
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  2. Bernd Trathnigg
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Pasch, H., Trathnigg, B. (2013). Theory of Polymer Chromatography. In: Multidimensional HPLC of Polymers. Springer Laboratory. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36080-0_2

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