Abstract
The use of molecular devices in post-CMOS devices and structures is described. Particularly we demonstrate the fabrication and characterization of two-novel devices: a two-terminal device which exhibits a two-negative differential resistance peaks and a sub-10-nm-channel vertical molecular transistor which contains a molecular quantum-dot compound. We show that the latter device can be operated in two distinct modes: gate-controlled switch and gate-controlled hysteresis.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Schaller, R.R.: Moore’s law: past, present, and future. IEEE Spectrum 34, 52–& (1997)
International Roadmap for Semiconductors (Semiconductor Industry Association (SIA), SEMATECH, 2010)
Colinge, J.P., Colinge, C.A.: Physics of Semiconductor Devices. Kluwer Academic, Norwell (2002)
Campbell, S.A.: Fabrication Engineering at the Micro and Nanoscale. Oxford University Press, Oxford (2004)
Rupp, K., Selberherr, S.: The economic limit to Moore’s law. IEEE T Semiconduct. M 24, 1–4 (2011)
Frank, D.J. et al.: Device scaling limits of Si MOSFETs and their application dependencies. P IEEE 89, 259–288 (2001)
Lemme, M.C. et al.: Subthreshold behavior of triple-gate MOSFETs on SOI material. Solid State Electron. 48, 529–534 (2004)
Kim, N.S. et al.: Leakage current: Moore’s law meets static power. Computer 36, 68– + (2003)
Lu, W., Lieber, C.M.: Nanoelectronics from the bottom up. Nat. Mater. 6, 841–850 (2007)
Stan, M.R., Franzon, P.D., Goldstein, S.C., Lach, J.C., Ziegler, M.M.: Molecular electronics: From devices and interconnect to circuits and architecture. P IEEE 91, 1940–1957 (2003)
Heath, J.R., Kuekes, P.J., Snider, G.S., Williams, R.S.: A defect-tolerant computer architecture: Opportunities for nanotechnology. Science 280, 1716–1721 (1998)
Strukov, D.B., Snider, G.S., Stewart, D.R., Williams, R.S.: The missing memristor found. Nature 453, 80–83 (2008)
Mentovich, E.D., Belgorodsky, B., Kalifa, I., Cohen, H., Richter, S.: Large-scale fabrication of 4-nm-channel vertical protein-based ambipolar transistors. Nano Lett. 9, 1296–1300 (2009)
Strukova, D.B., Kohlstedta, H.: Resistive switching phenomena in thin films: Materials, devices, and applications. MRS Bull. 37, 108–114 (2012)
Raoux, S., Ielmini, D., M., W., Karpov, I.: Phase change materials. MRS Bull. 37, 118–123 (2012)
Zimbovskaya, N.A., Pederson, M.R.: Electron transport through molecular junctions. Phys. Rep. 509, 1–87 (2011)
Mentovich, E.D. et al.: Multipeak negative-differential-resistance molecular device. Small 4, 55–58 (2008)
Metzger, R.M.: Unimolecular electronics. J. Mater. Chem. 18, 4364–4396 (2008)
Orihashi, N., Hattori, S., Asada, M.: Millimeter and submillimeter oscillators using resonant tunneling diodes with stacked-layer slot antennas. Jpn. J. Appl. Phys. 2(43), L1309–L1311 (2004)
Maezawa, K. et al.: High-power oscillations in resonant tunneling diode pair oscillator ICs fabricated with metamorphic devices. Jpn. J. Appl. Phys. 1(46), 2306–2308 (2007)
Metzger, R.M.: Unimolecular electrical rectifiers. Chem. Rev. 103, 3803–3834 (2003)
Joachim, C., Gimzewski, J.K., Aviram, A.: Electronics using hybrid-molecular and mono-molecular devices. Nature 408, 541–548 (2000)
Rose, G.S., Stan, M.R.: A programmable majority logic array using molecular scale electronics. IEEE T Circ. I 54, 2380–2390 (2007)
Mathews, R.H. et al.: A new RTD-FET logic family. P IEEE 87, 596–605 (1999)
Collier, C.P. et al.: Electronically configurable molecular-based logic gates. Science 285, 391–394 (1999)
Heath, J.R.: Molecular electronics. Annu. Rev. Mater. Res. 39, 1–23 (2009)
Chen, J.S. et al.: Negative differential resistance effect in organic devices based on an anthracene derivative. Appl. Phys. Lett. 89 (2006)
Galperin, M., Ratner, M.A., Nitzan, A.: Hysteresis, switching, and negative differential resistance in molecular junctions: A polaron model. Nano Lett. 5, 125–130 (2005)
Goto, E. et al.: Esaki diode high-speed logical circuits. IRE. T. Electron. Comp 25–29 (1960)
Kuroyana, N., Inoue, N.: High speed logical circuits combining esaki-diode bistable circuits with emitter follower. Rev. Elec. Commun. Lab 13, 701-& (1965)
Axelrod, M.S., Farber, A.S., Rosenheim, D.E.: Some new high-speed tunnel-diode logic circuits. IBM J. (1962)
Maezawa, K., Mizutani, T.: A new resonant tunneling logic gate employing monostable-bistable transition. Jpn. J. Appl. Phys. 2 Lett. 32, L42–L44 (1993)
Chen, K.J., Maezawa, K., Yamamoto, M.: InP-based high-performance monostable bistable transition logic elements (MOBILE’s) using integrated multiple-input resonant-tunneling devices. IEEE Electr. Dev. L 17, 127–129 (1996)
Mentovich, E.D., Richter, S.: Post-complementary metal-oxide-semiconductor vertical and molecular transistors: A platform for molecular electronics. Appl. Phys. Lett. 99 (2011)
Mentovich, E.D., Belgorodsky, B., Richter, S.: Resolving the mystery of the elusive peak: negative differential resistance in redox proteins. J. Phys. Chem. Lett. 2, 1125–1128 (2011)
Mentovich, E.D., Belgorodsky, B., Kalifa, I., Richter, S.: 1-nanometer-sized active-channel molecular quantum-dot transistor. Adv. Mater. 22, 2182–2186 (2010)
Mentovich, E.D., Richter, S.: The role of leakage currents and the gate oxide width in molecular transistors. Jpn. J. Appl. Phys. 49 (2010)
D’Amico, P., Ryndyk, D.A., Cuniberti, G., Richter, K.: Charge-memory effect in a polaron model: equation-of-motion method for Green functions. New J. Phys. 10 (2008)
Acknowledgements
This work was supported by the agency for Tashtiot program and the USAFÂ fund.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Hakim, R., Mentovich, E.D., Richter, S. (2013). Towards Post-CMOS Molecular Logic Devices. In: Lorente, N., Joachim, C. (eds) Architecture and Design of Molecule Logic Gates and Atom Circuits. Advances in Atom and Single Molecule Machines. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-33137-4_2
Download citation
DOI: https://doi.org/10.1007/978-3-642-33137-4_2
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-33136-7
Online ISBN: 978-3-642-33137-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)