Abstract
Metal nanoparticles (NPs) have recognized a growing importance in chemistry, electronics, optics, physics, and biology in the last decades. The possibility of tuning their unique properties varying dimension and morphology widely extends the range of possible applications. Several innovative chemical routes have been investigated to design shape-controlled synthesis to combine high-yield production with controllable and repeatable morphology. This chapter will focus on gold and silver NPs because of the easiness in synthesis control and of the large implementation in research and industrial applications. Synthesis methods, different morphologies and properties, and some of the possible applications will be discussed and reviewed.
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References
Meng XK, Tang SC, Vongehr S (2010) A review on diverse silver nanostructures. J Mater Sci Technol 26:487–522
Wiley B, Sun Y, Mayers B, Xia Y (2005) Shape-controlled synthesis of metal nanostructures: the case of silver. Chem A Eur J 11:454–463
Jain PK, Huang X, El-Sayed IH, El-Sayed MA (2008) Noble metals on the nanoscale: optical and photothermal properties and some applications in imaging, sensing, biology, and medicine. Acc Chem Res 41:1578–1586
Hu M, Chen J, Li ZY, Au L, Hartland GV, Li X, Marquez M, Xia Y (2006) Gold nanostructures: engineering their plasmonic properties for biomedical applications. Chem Soc Rev 35:1084–1094
Xiao J, Qi L (2011) Surfactant-assisted, shape-controlled synthesis of gold nanocrystals. Nanoscale 3:1383–1396
Shen XS, Wang GZ, Hong X, Zhu W (2009) Nanospheres of silver nanoparticles: agglomeration, surface morphology control and application as SERS substrates. Phys Chem Chem Phys 11:7450–7454
Qin Y, Song Y, Sun N, Zhao N, Li M, Qi L (2008) Ionic liquid-assisted growth of single-crystalline dendritic gold nanostructures with a three-fold symmetry. Chem Mater 20:3965–3972
Maier SA, Brongersma ML, Kik PG, Meltzer S, Requicha AAG, Atwater HA (2001) Plasmonics – a route to nanoscale optical devices. Adv Mater 13:1501–1505
Huang X, El-Sayed IH, Qian W, El-Sayed MA (2006) Cancer cell imaging and photothermal therapy in the near-infrared region by using gold nanorods. J Am Chem Soc 128:2115–2120
Sau TK, Rogach AL, Jäckel F, Klar TA, Feldmann J (2010) Properties and applications of colloidal nonspherical noble metal nanoparticles. Adv Mater 22:1805–1825
Xia Y, Xiong Y, Lim B, Skrabalak SE (2009) Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angew Chem Int Ed Engl 48:60–103
Liao H-G, Jiang Y-X, Zhou Z-Y, Chen S-P, Sun S-G (2008) Shape-controlled synthesis of gold nanoparticles in deep eutectic solvents for studies of structure-functionality relationships in electrocatalysis. Angew Chem Int Ed Engl 47:9100–9103
Barbosa S, Agrawal A, Rodríguez-Lorenzo L, Pastoriza-Santos I, Alvarez-Puebla RA, Kornowski A, Weller H, Liz-Marzán LM (2010) Tuning size and sensing properties in colloidal gold nanostars. Langmuir 26:14943–14950
Tan SJ, Campolongo MJ, Luo D, Cheng W (2011) Building plasmonic nanostructures with DNA. Nat Nanotechnol 6:268–276
Hong L, Li Q, Lin H, Li Y (2009) Synthesis of flower-like silver nanoarchitectures at room temperature. Mater Res Bull 44:1201–1204
Xionghui C, Aixia Z (2010) Preparation of microsized silver crystals with different morphologies by a wet-chemical method. Rare Metals 29:407–412
Wang H, Halas NJ (2008) Mesoscopic au “meatball” particles. Adv Mater 20:820–825
Burt J, Elechiguerra J, Reyesgasga J, Martinmontejanocarrizales J, Joseyacaman M (2005) Beyond Archimedean solids: star polyhedral gold nanocrystals. J Cryst Growth 285:681–691
Sau TK, Murphy CJ (2004) Room temperature, high-yield synthesis of multiple shapes of gold nanoparticles in aqueous solution. J Am Chem Soc 126:8648–8649
Zhao N, Wei Y, Sun N, Chen Q, Bai J, Zhou L, Qin Y, Li M, Qi L (2008) Controlled synthesis of gold nanobelts and nanocombs in aqueous mixed surfactant solutions. Langmuir 24:991–998
Xia Y, Li W, Cobley CM, Chen J, Xia X, Zhang Q, Yang M, Cho EC, Brown PK (2011) Gold nanocages: from synthesis to theranostic applications. Acc Chem Res 44:914–924
Cauda V, Schlossbauer A, Kecht J, Zuerner A, Bein T (2009) Multiple core-shell functionalized colloidal mesoporous silica nanoparticles. J Am Chem Soc 131:11361–11370
Morones JR, Elechiguerra JL, Camacho A, Holt K, Kouri JB, Ramírez JT, Yacaman MJ (2005) The bactericidal effect of silver nanoparticles. Nanotechnology 16:2346–2353
Daniel MC, Astruc D (2004) Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem Rev 104:293–346
Jeong GH, Lee YW, Kim M, Han SW (2009) High-yield synthesis of multi-branched gold nanoparticles and their surface-enhanced Raman scattering properties. J Colloid Interface Sci 329:97–102
Auer S, Frenkel D (2001) Prediction of absolute crystal-nucleation rate in hard-sphere colloids. Nature 409:1020
Matijevic E (1996) Controlled colloid formation. Curr Opin Colloid Interface Sci 1:176–183
Schon G, Simon U (1995) A fascinating new field in colloid science: small ligand stabilized metall clusters and possible applications in microelectronics. Colloid Polym Sci 273:101–117
Weller H (1993) Colloidal semiconductor Q-particles: chemistry in the transition region between solid state and molecules. Angew Chem Int Ed 32:41–53
Murray CB, Kagan CR, Bawendi MG (1995) Self-organization of CdSe nanocrystallites into three-dimensional quantum dot superlattices. Science 270:1335–1338
Kuo C-H, Huang MH (2005) Synthesis of branched gold nanocrystals by a seeding growth approach. Langmuir 21:2012–2016
Brust M, Bethell D, Schiffrin DJ, Kiely CJ (1995) Novel gold-dithiol nano-networks with non-metallic electronic properties. Adv Mater 7:795–797
Hostetler MJ, Green SJ, Stokes JJ, Murray RW (1996) Monolayers in three dimensions: synthesis and electrochemistry of ω-functionalized alkanethiolate-stabilized gold cluster compounds. J Am Chem Soc 118:4212–4213
Leff DV, Ohara PC, Heath JR, Gelbart WM (1995) Thermodynamic control of gold nanocrystal size: experiment and theory. J Phys Chem 99:7036–7041
Hostetler MJ, Wingate JE, Zhong C-J, Harris JE, Vachet RW, Clark MR, Londono JD, Green SJ, Stokes JJ, Wignall GD, Glish GL, Porter MD, Evans ND, Murray RW, Royce W (1998) Alkanethiolate gold cluster molecules with core diameters from 1.5 to 5.2 nm: core and monolayer properties as a function of core size. Langmuir 14:17–30
Tao AR, Habas S, Yang PD (2008) Shape control of colloidal metal nanocrystals. Small 4:310
Sun Y, Mayers B, Herricks T, Xia Y (2003) Polyol synthesis of uniform silver nanowires: a plausible growth mechanism and the supporting evidence. Nano Lett 3:955
Xiong Y, Xia Y (2007) Shape-controlled synthesis of metal nanostructures: the case of palladium. Adv Mater 19:3385
Wiley BJ, Chen Y, McLellan J, Xiong Y, Li Z-Y, Ginger D, Xia Y (2007) Synthesis and optical properties of silver nanobars and nanorice. Nano Lett 7:1032
Washio I, Xiong Y, Yin Y, Xia Y (2006) Reduction by the end groups of Poly(vinyl pyrrolidone): a new and versatile route to the kinetically controlled synthesis of Ag triangular nanoplates. Adv Mater 18:1745
Xiong Y, Washio I, Chen J, Cai H, Li Z-Y, Xia Y (2006) Poly(vinyl pyrrolidone): a dual functional reductant and stabilizer for the facile synthesis of noble metal nanoplates in aqueous solutions. Langmuir 22:8563
Morrison HG (2009) Characterization of thermal behavior of deep eutectic solvents and their potential as drug solubilization vehicles. Int J Pharm 378:1–2
Parnham ER, Drylie EA, Wheatley PS, Slawin AMZ, Morris RE (2006) Ionothermal materials synthesis using unstable deep-eutectic solvents as template-delivery agents. Angew Chem Int Ed Engl 45:4962–4966
Chambers SA (1991) Epitaxial film crystallography by high-energy Auger and X-ray photoelectron diffraction. Adv Phys 40:357
Ledentsov NN, Ustinov VM, Shchulan VA, Koper PS, Alferov ZI, Bimbers D (1998) Quantum dot heterostructures: growth, properties, lasing. Semiconductors 32:343
Jana NR, Gearheart L, Murphy CJ (2001) Wet chemical synthesis of high aspect ratio cylindrical gold nanorods. J Phys Chem B 105:4065
Nikoobakht B, El-Sayed MA (2003) Preparation and growth mechanism of gold Nanorods (NRs) using seed-mediated growth method. Chem Mater 15:1957
Barbieri A, Accorsi G, Armaroli N (2008) Luminescent complexes beyond the platinum group: the d10 avenue. Chem Commun 19:2185–2193
Hada H, Yonezawa Y, Yoshida A, Kurakake A (1976) Photoreduction of silver ion in aqueous and alcoholic solutions. J Phys Chem 80:2728–2731
Sato T, Onaka H, Yonezawa Y (1999) Sensitized photoreduction of silver ions in the presence of acetophenone. J Photochem Photobiol A Chem 127:83–87
Itakura T, Torigoe K, Esumi K (1995) Preparation and characterization of ultrafine metal particles in ethanol by UV irradiation using a photoinitiator. Langmuir 11:4129–4134
Esumi K, Matsumoto T, Seto Y, Yoshimura T (2005) Preparation of gold-, gold/silver-dendrimer nanocomposites in the presence of benzoin in ethanol by UV irradiation. J Colloid Interface Sci 284:199–203
Scaiano JC, Aliaga C, Maguire S, Wang D (2006) Magnetic field control of photoinduced silver nanoparticle formation. J Phys Chem B 110:12856–12859
Scaiano JC, Billone P, Gonzalez CM, Maretti L, Marin ML, McGilvray KL, Yuan N (2009) Photochemical routes to silver and gold nanoparticles. Pure Appl Chem 81:635–647
Courrol LC, de Oliveira Silva FR, Gomes L (2007) A simple method to synthesize silver nanoparticles by photo-reduction. Colloids Surf A Physicochem Eng Asp 305:54–57
Yang S, Wang Y, Wang Q, Zhang R, Ding B (2007) UV irradiation induced formation of Au nanoparticles at room temperature: the case of pH values. Colloids Surf A Physicochem Eng Asp 301:174–183
Han MY, Quek CH (2000) Photochemical synthesis in formamide and room-temperature Coulomb staircase behavior of size-controlled gold nanoparticles. Langmuir 16:362–367
Esumi K, Wakabayashi M, Torigoe K (1996) Preparation of colloidal silver-palladium alloys by UV-irradiation in mixtures of acetone and 2-propanol. Colloids Surf A Physicochem Eng Asp 109:55–62
Hada H, Yonezawa Y, Saikawa M (1982) Photoreduction of silver in a titanium dioxide suspension. Bull Chem Soc Jpn 55:2010–2014
Yonezawa Y, Kometani N, Sakaue T, Yano A (2005) Photoreduction of silver ions in a colloidal titanium dioxide suspension. J Photochem Photobiol A Chem 171:1–8
Zhang H, Wang G, Chen D, Lv X, Li J (2008) Tuning photoelectrochemical performances of Ag-TiO2 nanocomposites via reduction/oxidation of Ag. Chem Mater 20:6543–6549
Hada H, Tanemura H, Yonezawa Y (1978) Photoreduction of the silver ion in a zinc oxide suspension. Bull Chem Soc Jpn 51:3154–3160
Carbone L, Jakab A, Khalavka Y, Sönnichsen C (2009) Light-controlled one-sided growth of large plasmonic gold domains on quantum rods observed on the single particle level. Nano Lett 9:3710–3714
Dong SA, Zhou SP (2007) Photochemical synthesis of colloidal gold nanoparticles. Mater Sci Eng B Solid-State Mater Adv Technol 140:153–159
Jia H, Xu W, An J, Li D, Zhao B (2006) A simple method to synthesize triangular silver nanoparticles by light irradiation. Spectrochim Acta A Mol Biomol Spectrosc 64:956–960
Maillard M, Huang P, Brus L (2003) Silver nanodisk growth by surface plasmon enhanced photoreduction of adsorbed [Ag +]. Nano Lett 3:1611–1615
Taubert A, Arbell I, Mecke A, Graf P (2006) Photoreduction of a crystalline Au(III) complex: a solid-state approach to metallic nanostructures. Gold Bull 39:205–211
Tung HT, Song JM, Nien YT, Chen IG (2008) A novel method for preparing vertically grown single-crystalline gold nanowires. Nanotechnology 19:455603
Glover RD, Miller JM, Hutchison JE (2011) Generation of metal nanoparticles from silver and copper objects: nanoparticle dynamics on surfaces and potential sources of nanoparticles in the environment. ACS Nano 5:8950–8957
Goldstein J, Newbury D, Joy D, Lyman C, Echlin P, Lifshin E, Sawyer LC, Michael JR (2002) Scanning electron microscopy and X-ray microanalysis. Springer, New York
Williams DB, Carter CB (2009) Transmission electron microscopy: a textbook for materials science. Springer, New York
Stassi S, Cauda V, Canavese G, Manfredi D, Pirri CF (2012) Synthesis and characterization of gold nanostars as filler of tunneling conductive polymer composites. Eur J Inorg Chem 16:2669–2673
Mulvihill MJ, Ling XY, Henzie J, Yang P (2010) Anisotropic etching of silver nanoparticles for plasmonic structures capable of single-particle SERS. J Am Chem Soc 132:268–274
Lim B, Xia Y (2011) Metal nanocrystals with highly branched morphologies. Angew Chem Int Ed Engl 50:76–85
Senthil Kumar P, Pastoriza-Santos I, Rodríguez-González B, Javier García de Abajo F, Liz-Marzán LM (2008) High-yield synthesis and optical response of gold nanostars. Nanotechnology 19:015606
Khoury CG, Vo-Dinh T (2008) Gold nanostars for surface-enhanced Raman scattering: synthesis, characterization and optimization. J Phys Chem C 112:18849–18859
Nalbant Esenturk E, Hight Walker AR (2009) Surface-enhanced Raman scattering spectroscopy via gold nanostars. J Raman Spectrosc 40:86–91
Stassi S, Canavese G, Cauda V, Marasso SL, Pirri CF (2012) Evaluation of different conductive nanostructured particles as filler in smart piezoresistive composites. Nanoscale Res Lett 7:327
Xu X, Jia J, Yang X, Dong S (2010) A templateless, surfactantless, simple electrochemical route to a dendritic gold nanostructure and its application to oxygen reduction. Langmuir 26:7627–7631
Feng QL, Wu J, Chen GQ, Cui FZ, Kim TN, Kim JO (2000) A mechanistic study of the antibacterial effect of silver ions on Escherichia coli and Staphylococcus aureus. J Biomed Mater Res 52:662–668
Xia Y, Halas NJ (2005) Shape-controlled synthesis and surface plasmonic properties of metallic nanostructures. MRS Bull 30:338–348
Haynes CL, McFarland AD, Van Duyne RP (2005) Surface-enhanced: Raman spectroscopy. Anal Chem 77:338 A–346 A
Jeanmaire DL, Van Duyne RP (1977) Surface Raman spectroelectrochemistry Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode. J Electroanal Chem 84:1–20
Fleischmann M, Hendra PJ, McQuillan AJ (1974) Raman spectra of pyridine adsorbed at a silver electrode. Chem Phys Lett 26:163–166
Virga A, Rivolo P, Descrovi E, Chiolerio A, Digregorio G, Frascella F, Soster M, Bussolino F, Marchiò S, Geobaldo F, Giorgis F (2012) SERS active Ag nanoparticles in mesoporous silicon: detection of organic molecules and peptide-antibody assays. J Raman Spectrosc 43:730–736
Chiolerio A, Virga A, Pandolfi P, Martino P, Rivolo P, Geobaldo F, Giorgis F (2012) Direct patterning of silver particles on porous silicon by inkjet printing of a silver salt via in-situ reduction. Nanoscale Res Lett 7:502
Huang T, Meng F, Qi L (2010) Controlled synthesis of dendritic gold nanostructures assisted by supramolecular complexes of surfactant with cyclodextrin. Langmuir 26:7582–7589
Sureshkumar M, Siswanto DY, Lee CK (2010) Magnetic antimicrobial nanocomposite based on bacterial cellulose and silver nanoparticles. J Mater Chem 20:6948–6955
Shah MSAS, Nag M, Kalagara T, Singh S, Manorama SV (2008) Silver on PEG-PU-TiO2 polymer nanocomposite films: an excellent system for antibacterial applications. Chem Mater 20:2455–2460
Hsu SH, Tseng HJ, Lin YC (2010) The biocompatibility and antibacterial properties of waterborne polyurethane-silver nanocomposites. Biomaterials 31:6796–6808
Varaprasad K, Murali Mohan Y, Ravindra S, Narayana Reddy N, Vimala K, Monika K, Sreedhar B, Mohana Raju K (2010) Hydrogel-silver nanoparticle composites: a new generation of antimicrobials. J Appl Polym Sci 115:1199–1207
Bryaskova R, Pencheva D, Kale GM, Lad U, Kantardjiev T (2010) Synthesis, characterisation and antibacterial activity of PVA/TEOS/Ag-Np hybrid thin films. J Colloid Interface Sci 349:77–85
Dastjerdi R, Montazer M, Shahsavan S (2010) A novel technique for producing durable multifunctional textiles using nanocomposite coating. Colloids Surf B Biointerfaces 81:32–41
Dallas P, Sharma VK, Zboril R (2011) Silver polymeric nanocomposites as advanced antimicrobial agents: classification, synthetic paths, applications, and perspectives. Adv Colloid Interface Sci 166:119–135
Dastjerdi R, Montazer M (2010) A review on the application of inorganic nano-structured materials in the modification of textiles: focus on anti-microbial properties. Colloids Surf B Biointerfaces 79:5–18
Goyal AK, Johal ES, Rath G (2011) Nanotechnology for water treatment. Curr Nanosci 7:640–654
Gasparyan VK (2009) Gold and silver nanoparticles in bioassay, cell visualization and therapy. Curr Clin Pharmacol 4:159–163
Leung KCF, Xuan S, Zhu X, Wang D, Chak CP, Lee SF, Ho WKW, Chung BCT (2012) Gold and iron oxide hybrid nanocomposite materials. Chem Soc Rev 41:1911–1928
Rahman M, Ahmad MZ, Kazmi I, Akhter S, Afzal M, Gupta G, Jalees Ahmed F, Anwar F (2012) Advancement in multifunctional nanoparticles for the effective treatment of cancer. Expert Opin Drug Deliv 9:367–381
Wang LS, Chuang MC, Ho JA (2012) Nanotheranostics – a review of recent publications. Int J Nanomedicine 7:4679–4695
Li D, He Q, Li J (2009) Smart core/shell nanocomposites: intelligent polymers modified gold nanoparticles. Adv Colloid Interface Sci 149:28–38
Tang YH, Huang AYT, Chen PY, Chen HT, Kao CL (2011) Metallodendrimers and dendrimer nanocomposites. Curr Pharm Des 17:2308–2330
Ravichandran R, Sundarrajan S, Venugopal JR, Mukherjee S, Ramakrishna S (2012) Advances in polymeric systems for tissue engineering and biomedical applications. Macromol Biosci 12:286–311
Huang H, Yuan Q, Yang X (2005) Morphology study of gold-chitosan nanocomposites. J Colloid Interface Sci 282:26–31
Madhumathi K, Sudheesh Kumar PT, Abhilash S, Sreeja V, Tamura H, Manzoor K, Nair SV, Jayakumar R (2010) Development of novel chitin/nanosilver composite scaffolds for wound dressing applications. J Mater Sci Mater Med 21:807–813
Tang F, He F, Cheng H, Li L (2010) Self-assembly of conjugated polymer-Ag@SiO2 hybrid fluorescent nanoparticles for application to cellular imaging. Langmuir 26:11774–11778
Zhao J, Castranova V (2011) Toxicology of nanomaterials used in nanomedicine. J Toxicol Environ Health B Crit Rev 14:593–632
Tolaymat TM, El Badawy AM, Genaidy A, Scheckel KG, Luxton TP, Suidan M (2010) An evidence-based environmental perspective of manufactured silver nanoparticle in syntheses and applications: a systematic review and critical appraisal of peer-reviewed scientific papers. Sci Total Environ 408:999–1006
Rybak A, Boiteux G, Melis F, Seytre G (2010) Conductive polymer composites based on metallic nanofiller as smart materials for current limiting devices. Compos Sci Technol 70:410–416
Kim WT, Jung JH, Kim TW, Son DI (2010) Current bistability and carrier transport mechanisms of organic bistable devices based on hybrid Ag nanoparticle-polymethyl methacrylate polymer nanocomposites. Appl Phys Lett 96:253301
Mahendia S, Tomar AK, Kumar S (2010) Electrical conductivity and dielectric spectroscopic studies of PVA-Ag nanocomposite films. J Alloys Compd 508:406–411
Gautam A, Ram S (2010) Preparation and thermomechanical properties of Ag-PVA nanocomposite films. Mater Chem Phys 119:266–271
Zhang R, Moon KS, Lin W, Wong CP (2010) Preparation of highly conductive polymer nanocomposites by low temperature sintering of silver nanoparticles. J Mater Chem 20:2018–2023
Chun KY, Oh Y, Rho J, Ahn JH, Kim YJ, Choi HR, Baik S (2010) Highly conductive, printable and stretchable composite films of carbon nanotubes and silver. Nat Nanotechnol 5:853–857
Pudas M, Hagberg J, Leppävuori S (2004) Gravure offset printing of polymer inks for conductors. Prog Org Coat 49:324–335
Zhu R, Chung CH, Cha KC, Yang W, Zheng YB, Zhou H, Song TB, Chen CC, Weiss PS, Li G, Yang Y (2011) Fused silver nanowires with metal oxide nanoparticles and organic polymers for highly transparent conductors. ACS Nano 5:9877–9882
Gaynor W, Burkhard GF, McGehee MD, Peumans P (2011) Smooth nanowire/polymer composite transparent electrodes. Adv Mater 23:2905–2910
Kim BY, Shim IB, Araci ZO, Scott Saavedra S, Monti OLA, Armstrong NR, Sahoo R, Srivastava DN, Pyun J (2010) Synthesis and colloidal polymerization of ferromagnetic Au-Co nanoparticles into Au-Co3O4 nanowires. J Am Chem Soc 132:3234–3235
Englebienne P, Van Hoonacker A (2005) Gold-conductive polymer nanoparticles: a hybrid material with enhanced photonic reactivity to environmental stimuli. J Colloid Interface Sci 292:445–454
Joshi L, Prakash R (2011) One-pot synthesis of polyindole-Au nanocomposite and its nanoscale electrical properties. Mater Lett 65:3016–3019
Nambiar S, Yeow JTW (2011) Conductive polymer-based sensors for biomedical applications. Biosens Bioelectron 26:1825–1832
Kotov N (2004) Membrane sensors: nanocomposites are streteched thin. Nat Mater 3:669–671
Hanisch C, Ni N, Kulkarni A, Zaporojtchenko V, Strunskus T, Faupel F (2011) Fast electrical response to volatile organic compounds of 2D Au nanoparticle layers embedded into polymers. J Mater Sci 46:438–445
Shan C, Yang H, Han D, Zhang Q, Ivaska A, Niu L (2010) Graphene/AuNPs/chitosan nanocomposites film for glucose biosensing. Biosens Bioelectron 25:1070–1074
Devadoss A, Spehar-Délèze AM, Tanner DA, Bertoncello P, Marthi R, Keyes TE, Forster RJ (2010) Enhanced electrochemiluminescence and charge transport through films of metallopolymer-gold nanoparticle composites. Langmuir 26:2130–2135
Jiang G, Hore MJA, Gam S, Composto RJ (2012) Gold nanorods dispersed in homopolymer films: optical properties controlled by self-assembly and percolation of nanorods. ACS Nano 6:1578–1588
Beyene HT, Chakravadhanula VSK, Hanisch C, Elbahri M, Strunskus T, Zaporojtchenko V, Kienle L, Faupel F (2010) Preparation and plasmonic properties of polymer-based composites containing Ag-Au alloy nanoparticles produced by vapor phase co-deposition. J Mater Sci 45:5865–5871
Hu X, Li Z, Zhang J, Yang H, Gong Q, Zhang X (2011) Low-power and high-contrast nanoscale all-optical diodes via nanocomposite photonic crystal microcavities. Adv Funct Mater 21:1803–1809
Nguyen TP (2011) Polymer-based nanocomposites for organic optoelectronic devices. A review. Surf Coat Technol 206:742–752
Duncan TV (2011) Applications of nanotechnology in food packaging and food safety: barrier materials, antimicrobials and sensors. J Colloid Interface Sci 363:1–24
Orozco VH, Kozlovskaya V, Kharlampieva E, López BL, Tsukruk VV (2010) Biodegradable self-reporting nanocomposite films of poly(lactic acid) nanoparticles engineered by layer-by-layer assembly. Polymer 51:4127–4139
Zhu Z, Senses E, Akcora P, Sukhishvili SA (2012) Programmable light-controlled shape changes in layered polymer nanocomposites. ACS Nano 6:3152–3162
Andres CM, Kotov NA (2010) Inkjet deposition of layer-by-layer assembled films. J Am Chem Soc 132:14496–14502
Chrissafis K, Bikiaris D (2011) Can nanoparticles really enhance thermal stability of polymers? Part I: an overview on thermal decomposition of addition polymers. Thermochim Acta 523:1–24
Yuan C, Luo W, Zhong L, Deng H, Liu J, Xu Y, Dai L (2011) Gold@Polymer nanostructures with tunable permeability shells for selective catalysis. Angew Chem Int Ed 50:3515–3519
Sangermano M, Perruchas S, Gacoin T, Rizza G (2008) Synthesis of Au@SiO2 core/shell nanoparticles and their dispersion into an acrylic photocurable formulation: film preparation and characterization. Macromol Chem Phys 209:2343–2348
Sangermano M, Marchino A, Perruchas S, Gacoin T, Rizza G (2008) UV-cured nanostructured gold/acrylic coating. Macromol Mater Eng 293:964–968
Maity S, Bochinski JR, Clarke LI (2012) Metal nanoparticles acting as light-activated heating elements within composite materials. Adv Funct Mater 22:5259–5270
Chiolerio A, Sangermano M (2012) In situ synthesis of Ag-acrylic nanocomposites: tomography-based percolation model, irreversible photoinduced electromigration and reversible electromigration. Mater Sci Eng B Solid-State Mater Adv Technol 177:373–380
Sangermano M, Roppolo I, Camara VHA, Dizman C, Ates S, Torun L, Yagci Y (2011) Polysulfone/metal nanocomposites by simultaneous photoinduced crosslinking and redox reaction. Macromol Mater Eng 296:820–825
Chiolerio A, Vescovo L, Sangermano M (2010) Conductive UV-cured acrylic inks for resistor fabrication: models for their electrical properties. Macromol Chem Phys 211:2008–2016
Sangermano M, Yagci Y, Rizza G (2007) In situ synthesis of silver-epoxy nanocomposites by photoinduced electron transfer and cationic polymerization processes. Macromolecules 40:8827–8829
Vescovo L, Sangermano M, Scarazzini R, Kortaberria G, Mondragon I (2010) In-situ-synthetized silver/epoxy nanocomposites: electrical characterization by means of dielectric spectroscopy. Macromol Chem Phys 211:1933–1939
Colucci G, Celasco E, Mollea C, Bosco F, Conzatti L, Sangermano M (2011) Hybrid coatings containing silver nanoparticles generated in situ in a thiol-ene photocurable system. Macromol Mater Eng 296:921–928
Cook WD, Nghiem QD, Chen Q, Chen F, Sangermano M (2011) Simultaneous photoinduced silver nanoparticles formation and cationic polymerization of divinyl ethers. Macromolecules 44:4065–4071
Chiolerio A, Roppolo I, Sangermano M (2013) Radical diffusion engineering: tailored nanocomposite materials for piezoresistive inkjet printed strain measurement. RSC Adv 3:3446–3452
Nair JR, Ijeri VS, Gerbaldi C, Bodoardo S, Bongiovanni R, Penazzi N (2010) Novel self-directed dual surface metallisation via UV-curing technique for flexible polymeric capacitors. Org Electron Phys Mater Appl 11:1802–1808
Yagci Y, Sangermano M, Rizza G (2008) Synthesis and characterization of gold – epoxy nanocomposites by visible light photoinduced electron transfer and cationic polymerization processes. Macromolecules 41:7268–7270
Smirnova TN, Kokhtych LM, Kutsenko AS, Sakhno OV, Stumpe J (2009) The fabrication of periodic polymer/silver nanoparticle structures: In situ reduction of silver nanoparticles from precursor spatially distributed in polymer using holographic exposure. Nanotechnology 20:405301
Trandafilović LV, Luyt AS, Bibić N, Dimitrijević-Branković S, Georges MK, Radhakrishnan T, Djoković V (2012) Formation of nano-plate silver particles in the presence of polyampholyte copolymer. Colloids Surf A Physicochem Eng Asp 414:17–25
Jeon SH, Xu P, Zhang B, MacK NH, Tsai H, Chiang LY, Wang HL (2011) Polymer-assisted preparation of metal nanoparticles with controlled size and morphology. J Mater Chem 21:2550–2554
Kim JU, Cha SH, Shin K, Jho JY, Lee JC (2004) Preparation of gold nanowires and nanosheets in bulk block copolymer phases under mild conditions. Adv Mater 16:459–464
Hu S, Brittain WJ, Jacobson S, Balazs AC (2006) Selective ordering of surfactant modified gold nanoparticles in a diblock copolymer. Eur Polym J 42:2045–2052
Mallick K, Witcomb M, Scurrell M (2007) A novel synthesis route for a gold-polymer soft composite material. Phys Status Solid Rapid Res Lett 1:R1–R3
Scott A, Gupta R, Kulkarni GU (2010) A simple water-based synthesis of Au Nanoparticle/PDMS composites for water purification and targeted drug release. Macromol Chem Phys 211:1640–1647
Goyal A, Kumar A, Patra PK, Mahendra S, Tabatabaei S, Alvarez PJJ, John G, Ajayan PM (2009) In situ synthesis of metal nanoparticle embedded free standing multifunctional PDMS films. Macromol Rapid Commun 30:1116–1122
Kalyva M, Kumar S, Brescia R, Petroni S, La Tegola C, Bertoni G, De Vittorio M, Cingolani R, Athanassiou A (2013) Electrical response from nanocomposite PDMS-Ag NPs generated by in situ laser ablation in solution. Nanotechnology 24:035707
Anyaogu KC, Cai X, Neckers DC (2008) Gold nanoparticle photopolymerization of acrylates. Macromolecules 41:9000–9003
Spano F, Massaro A, Blasi L, Malerba M, Cingolani R, Athanassiou A (2012) In situ formation and size control of gold nanoparticles into chitosan for nanocomposite surfaces with tailored wettability. Langmuir 28:3911–3917
Govindaraju A et al (2005) Reinforcement of PDMS masters using SU-8 truss structures. J Micromech Microeng 15:1303
Mannsfeld SCB, Tee BCK, Stoltenberg RM, Chen CVHH, Barman S, Muir BVO, Sokolov AN, Reese C, Bao Z (2010) Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers. Nat Mater 9:859–864
Harsaanyi G (2000) Polymer films in sensor applications: a review of present uses and future possibilities. Sens Rev 20:98–105
Shimojo M, Namiki A, Ishikawa M, Makino R, Mabuchi K (2004) A tactile sensor sheet using pressure conductive rubber with electrical-wires stitched method. IEEE Sens J 4:589–596
Strumpler R, Glatz-Reichenbach J (1999) Conducting polymer composites. J Electroceramics 3:329–346
Fu S-Y, Feng X-Q, Lauke B, Mai Y-W (2008) Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate-polymer composites. Compos B Eng 39:933–961
Toker D, Azulay D, Shimoni N, Balberg I, Millo O (2003) Tunneling and percolation in metal-insulator composite materials. Phys Rev B 68:041403
Lundberg B, Sundqvist B (1986) Resistivity of a composite conducting polymer as a function of temperature, pressure, and environment: applications as a pressure and gas concentration transducer. J Appl Phys 60:1074–1079
Lantada AD, Lafont P, Sanz JLM, Munoz-Guijosa JM, Otero JE (2010) Quantum tunnelling composites: characterisation and modelling to promote their applications as sensors. Sens Actuators A Phys 164:46–57
Zhang XW, Zheng PY, Yi XQ (2000) Time dependence of piezoresistance for the conductor-filled polymer composites. J Polym Sci B Polym Phys 38:2739–2749
Bloor D, Donnelly K, Hands PJ, Laughlin P, Lussey D (2005) A metal–polymer composite with unusual properties. J Phys D: Appl Phys 38:2851–2860
Canavese G, Lombardi M, Stassi S, Pirri CF (2012) Comprehensive characterization of large piezoresistive variation of Ni-PDMS composites. Appl Mech Mater 110–116:1336–1344
Edgcombe CJ, Valdrè U (2001) Microscopy and computational modelling to elucidate the enhancement factor for field electron emitters. J Microsc 203:188–194
Ausanio G, Barone A, Campana C, Iannotti V, Luponio C, Pepe G, Lanotte L (2006) Giant resistivity change induced by strain in a composite of conducting particles in an elastomer matrix. Sens Actuators A Physl 127:56–62
Canavese G, Stassi S, Stralla M, Bignardi C, Pirri CF (2012) Stretchable and conformable metal–polymer piezoresistive hybrid system. Sens Actuators A Phys 186:191–197
Bloor D, Graham A, Williams EJ, Laughlin PJ, Lussey D (2006) Metal–polymer composite with nanostructured filler particles and amplified physical properties. Appl Phys Lett 88:102103
Sun Y, Mayers B, Xia Y (2003) Transformation of silver nanospheres into nanobelts and triangular nanoplates through a thermal process. Nano Lett 3:675–679
Chen S, Carroll DL (2002) Synthesis and characterization of truncated triangular silver nanoplates. Nano Lett 2:1003–1007
Lu HW, Liu SH, Wang XL, Qian XF, Yin J, Zhu ZK (2003) Silver nanocrystals by hyperbranched polyurethane-assisted photochemical reduction of Ag+. Mater Chem Phys 81:104–107
Chiolerio A, Cotto M, Pandolfi P, Martino P, Camarchia V, Pirola M, Ghione G (2012) Ag nanoparticle-based inkjet printed planar transmission lines for RF and microwave applications: considerations on ink composition, nanoparticle size distribution and sintering time. Microelectron Eng 97:8–15
Molesa S, Redinger DR, Huang DC, Subramanian V (2003) High-quality inkjet-printed multilevel interconnects and inductive components on plastic for ultra-low-cost RFID applications. Mater Res Soc Sympos Proc 769:253–258
Magdassi S, Bassa A, Vinetsky Y, Kamyshny A (2003) Silver nanoparticles as pigments for water-based ink-jet inks. Chem Mater 15:2208–2217
Bidoki SM, Lewis DM, Clark M, Vakorov A, Millner PA, McGorman D (2007) Ink-jet fabrication of electronic components. J Micromech Microeng 17:967–974
Tiberto P, Barrera G, Celegato F, Coisson M, Chiolerio A, Martino P, Pandolfi P, Allia P (2013) Magnetic properties of jet-printer inks containing dispersed magnetite nanoparticles. Eur Phys J B 86:173
Soltman D, Subramanian V (2008) Inkjet-printed line morphologies and temperature control of the coffee ring effect. Langmuir 24:2224–2231
Lichtenberger M (2004) Inks Water-based. www.eng.buffalo.edu/COurses/spring04/ce457_527/Matt.pdf
Lee HH, Chou KS, Huang KC (2005) Inkjet printing of nanosized silver colloids. Nanotechnology 16:2436–2441
Chiolerio A, MacCioni G, Martino P, Cotto M, Pandolfi P, Rivolo P, Ferrero S, Scaltrito L (2011) Inkjet printing and low power laser annealing of silver nanoparticle traces for the realization of low resistivity lines for flexible electronics. Microelectron Eng 88:2481–2483
Bai JG, Creehan KD, Kuhn HA (2007) Inkjet printable nanosilver suspensions for enhanced sintering quality in rapid manufacturing. Nanotechnology 18:185701
Perelaer J, De Gans BJ, Schubert US (2006) Ink-jet printing and microwave sintering of conductive silver tracks. Adv Mater 18:2101–2104
Reinhold I, Hendriks CE, Eckardt R, Kranenburg JM, Perelaer J, Baumann RR, Schubert US (2009) Argon plasma sintering of inkjet printed silver tracks on polymer substrates. J Mater Chem 19:3384–3388
Kamyshny S, Steinke J, Magdassi S (2011) Metal-based inkjet inks for printed electronics. Open Appl Phys J 4:19–36
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Stassi, S. et al. (2014). Nanosized Gold and Silver Spherical, Spiky, and Multi-branched Particles. In: Bhushan, B., Luo, D., Schricker, S., Sigmund, W., Zauscher, S. (eds) Handbook of Nanomaterials Properties. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-31107-9_33
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