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Chemical Properties and Processes

  • Hans-Peter Blume
  • Gerhard W. Brümmer
  • Heiner Fleige
  • Rainer Horn
  • Ellen Kandeler
  • Ingrid Kögel-Knabner
  • Ruben Kretzschmar
  • Karl Stahr
  • Berndt-Michael Wilke
Chapter

Abstract

Many regulating functions of soils (Sect.  1.2) are based on biogeochemical processes, and are therefore affected by soil chemical properties. Examples are the storage and supply of nutrients, the sorption and degradation of contaminants, as well as the buffering of acid deposition. The chemical processes taking place at biogeochemical interfaces are of outstanding importance. About 40–60 % of the soil volume consists of pores, which can be filled with water (soil solution) or gases (soil air), depending on the actual soil moisture. The soil solids mainly consist of minerals and smaller fractions of organic matter. This porous system of mineral and organic soil particles, gases, aqueous solutions and organisms leads to the formation of very large and chemically reactive interfaces. These interfaces can adsorb, complex, precipitate or chemically transform various ions and molecules. This chapter provides an introduction to the chemical properties and processes regulating the behavior of nutrients and contaminants in soils.

Keywords

Humic Substance Clay Mineral Soil Solution Dissolve Organic Matter Layer Silicate 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

Supplementary Reading

  1. Arai Y, Sparks DL (2007) Phosphate reaction dynamics in soils and soil components: a multiscale approach. Adv Agron 94:135–179CrossRefGoogle Scholar
  2. Bartlett RJ, James BR (1993) Redox chemistry of soils. Adv Agron 50:151–208CrossRefGoogle Scholar
  3. Bolan NS, Naidu R, Syers JK, Tillman RW (1999) Surface charge and solute interactions in soils. Adv Agron 67:87–140CrossRefGoogle Scholar
  4. Bolan NS, Adriano DC, Curtin D (2003) Soil acidification and liming interactions with nutrient and heavy metal transformation and bioavailability. Adv Agron 78:215–272CrossRefGoogle Scholar
  5. Brown GE Jr, Parks GA, O’day PA (1995) Sorption at mineral-water interfaces: macroscopic and microscopic perspectives. In: Vaughan DJ, Pattrick RAD (eds) Mineral surfaces. Chapman and Hall, LondonGoogle Scholar
  6. Carrillo-Gonzalez R, Simunek J, Sauve S, Adriano D (2006) Mechanisms and pathways of trace element mobility in soils. Adv Agron 91:111–178CrossRefGoogle Scholar
  7. Chorover J, Kretzschmar R, Garcia-Pichel F, Sparks DL (2007) Soil biogeochemical processes within the critical zone. Elements 3:321–326CrossRefGoogle Scholar
  8. Davis JA, Kent DB (1990) Surface complexation modeling in aqueous geochemistry. In: Hochella MFJ, White AF (eds) Mineral-water interface geochemistry. Mineralogical Society of America, Washington, DCGoogle Scholar
  9. Evangelou VP (1998) Environmental soil and water chemistry: principles and applications. Wiley, New YorkGoogle Scholar
  10. Fageria NK, Baligar VC (2008) Ameliorating soil acidity of tropical Oxisols by liming for sustainable crop production. Adv Agron 99:345–399CrossRefGoogle Scholar
  11. Fendorf SE, Sparks DL, Lamble GM, Kelley MJ (1994) Applications of X-ray-absorption fine structure spectroscopy to soils. Soil Sci Soc Am J 58:1583–1595CrossRefGoogle Scholar
  12. Fiedler S, Vepraskas MJ, Richardson JL (2007) Soil redox potential: Importance, field measurements, and observations. Adv Agron 94:1–54CrossRefGoogle Scholar
  13. Ford RG, Scheinost AC, Sparks DL (2001) Frontiers in metal sorption/precipitation mechanisms on soil mineral surfaces. Adv Agron 74:41–62CrossRefGoogle Scholar
  14. Goldberg S (1992) Use of surface complexation models in soil chemical systems. Adv Agron 47:233–329CrossRefGoogle Scholar
  15. Hiemstra T, Van Riemsdijk WH (1996) A surface structural approach to ion adsorption: the charge distribution (CD) model. J Colloid Interf Sci 179:488–508CrossRefGoogle Scholar
  16. Hochella MFJ, White AF (eds) (1990) Mineral-water interface geochemistry. Mineralogical Society of America, Washington, DCGoogle Scholar
  17. Hochella MF, Lower SK, Maurice PA, Penn RL, Sahai N, Sparks DL, Twining BS (2008) Nanominerals, mineral nanoparticles, and earth systems. Science 319:1631–1635CrossRefGoogle Scholar
  18. Huang PM (2004) Soil mineral-organic matter-microorganism interactions: fundamentals and impacts. Adv Agron 82:391–472CrossRefGoogle Scholar
  19. Johnston CT, Tombacz E (2002) Surface chemistry of soil minerals. In: Dixon JB, Schulze DG (eds) Soil minerals with environmental applications. Soil Science Society of America, MadisonGoogle Scholar
  20. Karathanasis AD (2002) Mineral equilibria in environmental soil systems. In: Dixon JB, Schulze DG (eds) Soil mineralogy with environmental applications. Soil Sience Society of America, MadisonGoogle Scholar
  21. Kraemer SM, Crowley DE, Kretzschmar R (2006) Geochemical aspects of phytosiderophore-promoted iron acquisition by plants. Adv Agron 91:1–46CrossRefGoogle Scholar
  22. Kretzschmar R, Borkovec M, Grolimund D, Elimelech M (1999) Mobile subsurface colloids and their role in contaminant transport. Adv Agron 66:121–193CrossRefGoogle Scholar
  23. Limousin G, Gaudet JP, Charlet L, Szenknect S, Barthes V, Krimissa M (2007) Sorption isotherms: a review on physical bases, modeling and measurement. Appl Geochem 22:249–275CrossRefGoogle Scholar
  24. Lindsay WL (1979) Chemical equilibria in soils. Wiley, New YorkGoogle Scholar
  25. Manthey JA, Crowley DE, Luster DG (eds) (1994) Biochemistry of metal micronutrients in the rhizosphere. Lewis Publishers, Boca RatonGoogle Scholar
  26. Marschner H (1995) Mineral nutrition of higher plants, 2nd edn. Academic Press, LondonGoogle Scholar
  27. Maurice PA, Hochella MF (2008) Nanoscale particles and processes: a new dimension in soil science. Adv Agron 100:123–153CrossRefGoogle Scholar
  28. Mcbride MB (1989) Surface chemistry of soil minerals. In: Dixon JB, Weed SB (eds) Minerals in soil environments, 2nd edn. Soil Science Society of America, MadisonGoogle Scholar
  29. Mcbride MB (1994) Environmental chemistry of soils. Oxford University Press, New YorkGoogle Scholar
  30. Qafoku NP, Van Ranst E, Noble A, Baert G (2004) Variable charge soils: their mineralogy, chemistry and management. Adv Agron 84:159–215CrossRefGoogle Scholar
  31. Rai D, Kittrick JA (1989) Mineral equilibria and the soil system. In: Dixon JB, Weed SB (eds) Minerals in soil environments, 2nd edn. Soil Science Society of America, MadisonGoogle Scholar
  32. Reddy KR, DeLaune RD (2008) Biogeochemistry of wetlands—science and applications. CRC Press, Boca RatonCrossRefGoogle Scholar
  33. Ritchie GSP, Sposito G (1995) Speciation in soils. In: Ure AM, Davidson CM (eds) Chemical speciation in the environment. Blackie and Son, GlasgowGoogle Scholar
  34. Robin A, Vansuyt G, Hinsinger P, Meyer JM, Briat JF, Lemanceau P (2008) Iron dynamics in the rhizosphere: consequences for plant health and nutrition. Adv Agron 99:183–225CrossRefGoogle Scholar
  35. Schnitzer M (2000) A lifetime perspective on the chemistry of soil organic matter. Adv Agron 68:1–58CrossRefGoogle Scholar
  36. Schwarzenbach RP, Gschwend PM, Imboden DM (2003) Environmental organic chemistry, 2nd edn. Wiley, HobokenGoogle Scholar
  37. Sparks DL (2001) Elucidating the fundamental chemistry of soils: past and recent achievements and future frontiers. Geoderma 100:303–319CrossRefGoogle Scholar
  38. Sparks DL (2003) Environmental soil chemistry, 2nd edn. Academic Press, San DiegoGoogle Scholar
  39. Sposito G (1989) The chemistry of soils. Oxford University Press, New YorkGoogle Scholar
  40. Sposito G (1994) Chemical equilibria and kinetics in soils. Oxford University Press, New YorkGoogle Scholar
  41. Sposito G (ed) (1995) The environmental chemistry of aluminum, 2nd edn. CRC Press, Boca RatonGoogle Scholar
  42. Sposito G (2004) The surface chemistry of natural particles. Oxford University Press, New YorkGoogle Scholar
  43. Stevenson FJ (1994) Humus chemistry: genesis, composition, reactions, 2nd edn. Wiley, New YorkGoogle Scholar
  44. Sumner ME (ed) (2000) Handbook of soil sciences. CRC Press, Boca RatonGoogle Scholar
  45. Sutton R, Sposito G (2005) Molecular structure in soil humic substances: the new view. Environ Sci Technol 39:9009–9015CrossRefGoogle Scholar
  46. Tipping E (2002) Cation binding by humic substances. Cambridge University Press, CambridgeCrossRefGoogle Scholar

Cited References

  1. Berner E, Berner R (1996) Global environment: water, air, and geochemical cycles. Prentice Hall, Upper Saddle RiverGoogle Scholar
  2. Bradford GR, Bair FL, Hunsacker V (1971) Trace and major element contents of soil saturation extracts. Soil Sci 112:225–230CrossRefGoogle Scholar
  3. Brown BA, Munsell RI, Holt RF, King AV (1956) Soil reactions at various depths as influenced by time since application and amounts of limestone. Soil Sci Soc Am Proc 20:518–522CrossRefGoogle Scholar
  4. Campbell DJ, Beckett PHT (1988) The soil solution in a soil treated with digested sewage sludge. J Soil Sci 39:283–298CrossRefGoogle Scholar
  5. Christl I, Kretzschmar R (1999) Competitive sorption of copper and lead at the oxide-water interface: implications for surface site density. Geochim Cosmochim Acta 63:2929–2938CrossRefGoogle Scholar
  6. Christl I, Knicker H, Kogel-Knabner I, Kretzschmar R (2000) Chemical heterogeneity of humic substances: characterization of size fractions obtained by hollow-fibre ultrafiltration. Eur J Soil Sci 51:617–625CrossRefGoogle Scholar
  7. Essington ME (2004) Soil and water chemistry: an integrative approach. CRC Press, Boca RatonGoogle Scholar
  8. Fieldes M, Schofield RK (1960) Mechanisms of ion adsorption by inorganic soil colloids. New Zealand J Sci 3:563–679Google Scholar
  9. Fischer L, Brummer GW, Barrow NJ (2007) Observations and modelling of the reactions of 10 metals with goethite: adsorption and diffusion processes. Eur J Soil Sci 58:1304–1315CrossRefGoogle Scholar
  10. Furrer G, Stumm W (1986) The coordination chemistry of weathering: I. Dissolution kinetics of d-Al2O3 and BeO. Geochim Cosmochim Acta 50:1847–1860CrossRefGoogle Scholar
  11. Kreuzer K (1995) Effects of forest liming on soil processes. Plant Soil 168:447–470CrossRefGoogle Scholar
  12. Langmuir D (1997) Aqueous environmental geochemistry. Prentice Hall, Upper Saddle RiverGoogle Scholar
  13. Okazaki MK, Sakaidani K, Saigusa T, Sakaida N (1989) Ligand exchange of oxyanions on synthetic hydrated oxides of iron and aluminum. Soil Sci Plant Nutr 35:337–346CrossRefGoogle Scholar
  14. van Raij B, Peech M (1972) Electrochemical properties of some Oxisols and Alfisols of the tropics. Soil Sci Soc Am Proc 36:587–593CrossRefGoogle Scholar
  15. Robarge WP (1999) Precipitation/dissolution reactions in soils. In: Sparks DL (ed) Soil physical chemistry, 2nd edn. CRC Press, Boca RatonGoogle Scholar
  16. Stumm W (1992) Chemistry of the solid-water interface. Wiley, New YorkGoogle Scholar
  17. Stumm W, Morgan JJ (1996) Aquatic chemistry: chemical equilibria and rates in natural waters. Wiley, New YorkGoogle Scholar
  18. Suarez DL (1999) Thermodynamics of the soil solution. In: Sparks DL (ed) Soil physical chemistry, 2nd edn. CRC Press, Boca RatonGoogle Scholar
  19. Walthert L, Zimmermann S, Blaser P, Lüscher P (2004) Waldböden der Schweiz. Band 1. Grundlagen und Region Jura, Hep Verlag, BernGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Hans-Peter Blume
    • 1
  • Gerhard W. Brümmer
    • 6
  • Heiner Fleige
    • 1
  • Rainer Horn
    • 1
  • Ellen Kandeler
    • 2
  • Ingrid Kögel-Knabner
    • 3
  • Ruben Kretzschmar
    • 4
  • Karl Stahr
    • 2
  • Berndt-Michael Wilke
    • 5
  1. 1.Institute of Plant Nutrition and Soil SciencesChristian-Albrechts-University zu KielKielGermany
  2. 2.Institute for Soil Science and Land EvaluationHohenheim UniversityStuttgartGermany
  3. 3.Chair of Soil ScienceTechnische Universität MünchenFreising-WeihenstephanGermany
  4. 4.Institute of Biogeochemistry and Pollutant DynamicsETH ZurichZurichSwitzerland
  5. 5.Institute of EcologyTechnical University BerlinBerlinGermany
  6. 6.Institute of Crop Science and Resource ConservationUniversity of BonnBonnGermany

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