Application of Noble Gases to the Viability of CO2 Storage

Chapter
Part of the Advances in Isotope Geochemistry book series (ADISOTOPE)

Abstract

Unequivocable evidence for warming of the climate system is a reality. An important factor for reducing this warming is mitigation of anthropogenic CO2 in the atmosphere. This requires us to engineer technologies for capture of our carbon emissions and identify reservoirs for storing these captured emissions. This chapter reviews advances made in understanding multiphase interactions and processes operating in a variety of subsurface reservoirs using noble gases. We begin by discussing the types of reservoir available for carbon storage and the mechanisms of viable CO2 storage, before summarising the physical chemistry involved in data interpretation and the sampling/sample storage techniques and requirements critical to successful sample collection. Theory of noble gas partitioning is interspersed with examples from a variety reservoirs to aid our knowledge of long term CO2 storage in the subsurface. These include hydrocarbon reservoir and natural CO2 reservoirs. In these examples we show how good progress has been made in using noble gases to explain the fate of CO2 in the subsurface, to quantify the extent of groundwater interaction and to understand CO2 behaviour after injection into oil fields for enhanced oil recovery. We also present recent work using noble gases for monitoring of subsurface CO2 migration and leakage in CO2 rich soils, CO2 rich springs and groundwaters. Noble gases are chemically inert, persistent and environmentally safe and they have the potential to be extremely useful in tracing migration of CO2. It is imperative that the many upcoming pilot CO2 injection studies continue to investigate the behaviour of noble gases in the subsurface and develop suitable noble gas monitoring strategies.

Keywords

Colorado Plateau Rayleigh Fractionation High Pressure Hose Anomalous Spring Geological Carbon Storage Site 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

References

  1. Allis R, Bergfeld D, Moore J, McClure K, MorganC, Chidsey T, Heath JE, McPherson B (2005) Implications of results from CO2 flux surveys over known CO2 systems for long-term monitoring.In: Fourth annual conference on carbon capture and sequestration, DOE/NETL, 2–5 May 2005Google Scholar
  2. Allis R, Chidsey T, GwynnW, Morgan C, White S, Adams M, Moore J (2001) Natural CO2 reservoirs on the colorado plateau and southern rocky mountains: candidates for CO2 sequestration. DOE/NETL: 1st National conference of carbon sequestration. Procedings VolumeGoogle Scholar
  3. Baines SJ, Worden RH (2004a) Geological storage of carbon dioxide. In: Baines SJ, Worden RH (eds) Geological storage of carbon dioxide. The Geological Society of London, London, pp 1–6Google Scholar
  4. Baines SJ, Worden RH (2004b) The long term fate of CO2 in the subsurface: natural analogues for CO2 storage. In: Bains SJ, Worden RH (eds) Geological storage of carbon dioxide. Geological Society, London, pp 59–85Google Scholar
  5. Ballentine CJ, O’Nions RK, Coleman CL (1996) A magnus opus: helium, neon and argon isotopes in a North Sea oilfield. Geochimica Cosmochim Acta 60:831–849CrossRefGoogle Scholar
  6. Ballentine CJ (1997) Resolving the mantle He/Ne and crustal 21-Ne/22-Ne in well gases. Earth Planet Sci Lett 152:233–249CrossRefGoogle Scholar
  7. Ballentine CJ, Schoell M, Coleman D, Cain BA (2001) 300-Myr-old magmatic CO2 in natural gas reservoirs of the west Texas Permian basin. Nature 409:327–331CrossRefGoogle Scholar
  8. Ballentine CJ, Burgess R, MartyB (2002) Tracing fluid origin, transport and interaction in the crust. In: Porcelli DR, Ballentine CJ, Weiler R (eds) Noble gases in geochemistry and cosmochemistry, pp 539–614Google Scholar
  9. Ballentine CJ, BurnardPG (2002) Production, release and transport of noble gases in the continental crust. In: Porcelli DR, BallentineCJ, Weiler R (eds) Noble gases in geochemistry and cosmochemistry, pp 481–538Google Scholar
  10. Ballentine CJ, Marty B, Lollar BS, Cassidy M (2005) Neon isotopes constrain convection and volatile origin in the Earth’s mantle. Nature 433:33–38CrossRefGoogle Scholar
  11. Battani A, Deville E, Faure JL, Jeandel E, Noirez S, Tocqué E, Benoît Y, Schmitz J, Parlouar D, Sarda P, Gal F, Le Pierres K, Brach M, Braibant G, Beny C, Pokryszka Z, Charmoille A, Bentivegna G, Pironon J, de Donato P, Garnier C, Cailteau C, Barrès O, Radilla G, Bauer A (2010) Geochemical study of natural CO2 emissions in the French Massif Central: how to predict origin, processes and evolution of CO2 leakage. Oil Gas Sci Technol: Rev IFP 65(4):615–633CrossRefGoogle Scholar
  12. Battani A, Sarda P, Prinzhofer A (2000) Basin scale natural gas source, migration and trapping traced by noble gases and major elements: the Pakistan Indus basin. Earth Planet Sci Lett 181(1–2):229–249CrossRefGoogle Scholar
  13. Becker J (2005) Quantification of Himalayan Metamorphic CO2 fluxes: impact on global carbon budgets. PhD thesis, University of Cambridge, Cambridge. UKGoogle Scholar
  14. Bosch A, Mazor E (1988) Natural-gas association with water and oil as depicted by atmodspheric Noble Gases—Case studies from the southeastern mediterranean coastal-plain. Earth Planet Sci Lett 87(3):338–346CrossRefGoogle Scholar
  15. Bradshaw J, Boreham C, La Pedalina F (2004) Storage retention time of CO2 in sedimentary basins; examples from petroleum systems. In: Rubin E, Keith D, Brewer PG, Friederich G, Peltzer ET, Orr FM Jr (1999) Direct experiments on the Ocean disposal of fossil fuel CO2. Science 284:943–945Google Scholar
  16. Brewer PG, Friederich G, Peltzer ET, Orr FM Jr (1999) Direct experiments on the Ocean disposal of fossil fuel CO2. Science 284(5416):943–945. doi: 10.1126/science.284.5416.943 CrossRefGoogle Scholar
  17. Broadhead RF (1998) Natural accumulations of carbon dioxide in the New Mexico region—Where are they, how do they occur and what are the uses for CO2? Lite Geol 20:2–6Google Scholar
  18. Brohan P, Kennedy JJ, Harris I, Tett SFB, Jones PD (2006) Uncertainty estimates in regional and global observed temperature changes: a new data set from 1850. J Geophys Res 111(D12):D12106 doi: 10.1029/2005jd006548
  19. Burnard P, Graham D, Turner G (1997) Vesicle-specific noble gas analyses of “Popping Rock”: implications for primordial Noble Gases in Earth. Science 276:568–570Google Scholar
  20. Burnard PG, Graham DW, Farley KA (2002) Mechanisms of magmatic gas loss along the Southeast Indian Ridge and the Amsterdam -St. Paul Plateau. Earth Planet Sci Lett 203:131CrossRefGoogle Scholar
  21. Casanova J, Bodénan F, Négrel P, Azaroual M (1999) Microbial control on the precipitation of modern ferrihydrite and carbonate deposits from the Cézallier hydrothermal springs (Massif Central, France). Sed Geol 126(1–4):125–145. doi: 10.1016/s0037-0738(99)00036-6 CrossRefGoogle Scholar
  22. Castro MC, Goblet P (2003) Calibration of regional groundwater flow models: working toward a better understanding of site-specific systems. Water Resouces Res 39:1172CrossRefGoogle Scholar
  23. Castro MC, Goblet P, Ledoux E, Violette S, de Marsily G (1998) Noble gases as natural tracers of water circulation in the Paris Basin 2. Calibration of a groundwater flow model using noble gas isotope data. Water Resouces Res 34:2467–2483CrossRefGoogle Scholar
  24. Cathles LM, Schoell M (2007) Modeling CO2 generation, migration and titration in sedimentary basins. Geofluids 7:441–450CrossRefGoogle Scholar
  25. Craig H, Lupton JE, Horibe Y (1978) A mantle helium component in circum Pacific volcanic gases. In: Alexander EC, Ozima M (eds) Terrestrial rare gases. Japan Science Societies Press, Tokyo, pp 3–16CrossRefGoogle Scholar
  26. Deines P, Langmuir D, Harmon RS (1974) Stable carbon isotopes and the existence of a gas phase in the evolution of carbonate groundwaters. Geochim Cosmochim Acta 38:1147–1184CrossRefGoogle Scholar
  27. Drescher J, Kirsten T, Schafer K (1998) The rare gas inventory of the continental crust, recovered by the KTB continental deep drilling project. Earth Planet Sci Lett 119:271–281Google Scholar
  28. EU (2009) Directive 2009/31/EC of the European Parliament and of the Council on the geological storage of carbon dioxide. Official J Eur Union L140:114–136Google Scholar
  29. Fanale FP, Cannon WA (1971) Physical adsorption of rare gases on terrigenous sediments. Earth Planet Sci Lett 11:362–368CrossRefGoogle Scholar
  30. Farley KA, Craig H (1994) Atmospheric argon contamination of ocean island basalt olivine phenocrysts. Geochim Cosmochim Acta 58:2509–2517CrossRefGoogle Scholar
  31. Fitton JG, James D, Leeman WP (1991) Basic magmatism associated with late cenozoic extension in the Western United-States—Compositional variations in space and time. J Geophys Res Solid Earth Planet 96(B8):13693–13711Google Scholar
  32. Fontes J-Ch, Andrews JN, Walgenwitz F (1991) Évaluation de la production naturelle in situ d’argon-36 via le chlore-36: implications géochimiques et géochronologiques. C. R. Acad. 856 Paris 313, Série II, pp 649–654Google Scholar
  33. Gautheron C, Moreira M (2002) Helium signature of the subcontinental lithospheric mantle. Earth Planet Sci Lett 199(1–2):39CrossRefGoogle Scholar
  34. Gilfillan SMV, Ballentine CJ, Holland G, Sherwood Lollar B, Stevens S, Schoell M, Cassidy M (2008) The noble gas geochemistry of natural CO2 gas reservoirs from the Colorado Plateau and Rocky Mountain provinces, USA. Geochim Cosmochim Acta 72:1174–1198CrossRefGoogle Scholar
  35. Gilfillan SMV, Lollar BS, Holland G, Blagburn D, Stevens S, Schoell M, Cassidy M, Ding Z, Zhou Z, Lacrampe-Couloume G, Ballentine CJ (2009) Solubility trapping in formation water as dominant CO2 sink in natural gas fields. Nature 458:614–618CrossRefGoogle Scholar
  36. Gilfillan SMV, Wilkinson M, Haszeldine RS, Shipton ZK, Nelson ST, Poreda RJ (2011) He and Ne as tracers of natural CO2 migration up a fault from a deep reservoir. Int J Greenhouse Gas Control 5(6):1507–1516. doi: 10.1016/j.ijggc.2011.08.008 CrossRefGoogle Scholar
  37. Gilfillan SMV, Haszeldine RS 2011 Report of noble gas, carbon stable isotope and HCO3- measurements from the Kerr Quarter and surrounding area, Goodwater, Saskatchewan. In: Sherk GW (ed) The Kerr investigation: final report, vol. IPAC-CO2 Research Inc, ReginaGoogle Scholar
  38. Goldberg DS, Takahashi T, Slagle AL (2008) Carbon dioxide sequestration in deep-sea basalt. Proc Nat Acad Sci 105:9920–9925CrossRefGoogle Scholar
  39. Graham D (2002) Noble gas isotope geochemistry of Mid-Ocean Ridge and Ocean Island Basalt: characterization of mantle source reservoirs. In: Porcelli D, Ballentine CJ, Wieler R (eds) Noble gases in geochemistry and cosmochemistry 47:247–317Google Scholar
  40. Haszeldine RS (2009) Carbon capture and storage: how green can black be? Science 325:1647–1652CrossRefGoogle Scholar
  41. Heath JE (2004) Hydrogeochemical characterization of CO2 charged fault zones: the Little Grand Wash and Salt Wash fault zones, Emery and Grand counties, Utah. PhD thesis Utah State University, LoganGoogle Scholar
  42. Hilton D, Fischer T, Marty B (2002) Noble gases and volitile recycling at subduction zones. In: Porcelli DR, Ballentine CJ, Weiler R (eds) Noble gases in geochemistry and cosmochemistry 47:319–370Google Scholar
  43. Hiyagon H, Kennedy BM (1992) Noble gases in CH4-rich gas fields, Alberta, Canada. Geochimica Cosmochimica Acta 56:1569–1589CrossRefGoogle Scholar
  44. Holland G, Ballentine CJ (2006) Seawater subduction controls the heavy noble gas composition of the mantle. Nature 441(7090):186–191CrossRefGoogle Scholar
  45. Holland G, Cassidy M, Ballentine CJ (2009) Meteorite Kr in Earth’s mantle suggests a late accretionary source for the atmosphere. Science 326:1522–1525CrossRefGoogle Scholar
  46. House KZ, Schrag DP, Harvey CF, Lackner KS (2006) Permanent carbon dioxide storage in deep-sea sediments. Proc Nat Acad Sci 103:12291–12295CrossRefGoogle Scholar
  47. IEA (2009) Technology roadmap: carbon capture and storage, Paris, p. www.iea.org
  48. IPCC (2005) IPCC special report on carbon dioxide capture and storage. Cambridge University Press, CambridgeGoogle Scholar
  49. IPCC (2007) Climate change 2007: synthesis report. Contribution of working groups I, II and III to the fourth assessment: report of the intergovernmental panel on climate change. IPCC, Geneva, SwitzerlandGoogle Scholar
  50. Javoy M, Pineau F, Delorme H (1986) Carbon and nitrogen isotopes in the mantle. Chem Geol 57:41–62CrossRefGoogle Scholar
  51. Jenden PD, Hilton DR, Kaplan IR, Craig H (1993) Abiogenic hydrocarbons in and mantle helium in oil and gas fields. In: Howell DG (ed) The future of energy gases, U.S. Geological Survey Professional Paper 1570. U.S. Geological Survey, pp 31–56Google Scholar
  52. Kennedy BM, Hiyagon H, Reynolds JH (1990) Crustal neon—A striking uniformity. Earth Planet Sci Lett 98:277–286CrossRefGoogle Scholar
  53. Kennedy BM, Torgersen T, van Soest MC (2002) Multiple atmospheric noble gas components in hydrocarbon reservoirs: a study of the Northwest Shelf, Delaware Basin, SE New Mexico. Geochim Cosmochim Acta 66:2807–2822CrossRefGoogle Scholar
  54. Kharaka YK, Cole DR, Hovorka SD, Gunter WD, Knauss KG, Freifeld BM (2006) Gas-water-rock interactions in Frio Formation following CO2 injection: implications for the storage of greenhouse gases in sedimentary basins. Geology 34:577–580CrossRefGoogle Scholar
  55. Kipfer R, Aeschbach-Gertig W, Peeters F, StuteM (2002) Noble gases in lakes and groundwaters, noble gases in geochemistry and cosmochemistry, pp 615–700Google Scholar
  56. Klara SM, Srivastava RD, McIlvried HG (2003) Integrated collaborative technology, development program for CO2 sequestration in geologic formations—United States Department of Energy R&D. Energy Convers Manage 44:2699–2712CrossRefGoogle Scholar
  57. Kurz MD, Jenkins WJ (1981) The distribution of helium in oceanic basalt glasses. Earth Planet Sci Lett 53(1):41–54. doi: 10.1016/0012-821x(81)90024-8 CrossRefGoogle Scholar
  58. Lafleur P (2010) Geochemical Soil Gas Survey—a site investigation of SW30-5-13-W2 M, Weyburn Field, Saskatchewan. Petro-Find Geochem Ltd, SaskatoonGoogle Scholar
  59. Mackintosh SJ, Ballentine CJ (2012) Using 3He/4He isotope ratios to identify the source of deep reservoir contributions to shallow fluids and soil gas. Chem Geol 304–305:142–150. doi: 10.1016/j.chemgeo.2012.02.006 CrossRefGoogle Scholar
  60. Marland G, Boden TA, Andres RJ (2008) Global, regional, and national fossil fuel CO2 emissions, trends: a compendium of data on global change. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tenn., USAGoogle Scholar
  61. Marland G, Schlamadinger B (1999) The Kyoto Protocol could make a difference for the optimal forest-based CO2 mitigation strategy: some results from GORCAM. Environ Sci Policy 2:111–124CrossRefGoogle Scholar
  62. Marty B, Jambon A (1987) C/3He in volatile fluxes from the solid Earth: implications for carbon geodynamics. Earth Planet Sci Lett 83:16–26CrossRefGoogle Scholar
  63. Marty B, O’Nions RK, Oxburgh ER, Martel D, Lombardi S (1992) Helium isotopes in alpine regions. Tectonophysics 206:71–78CrossRefGoogle Scholar
  64. Marty B, Zimmermann L (1999) Volatiles (He, C, N, Ar) in mid-ocean ridge basalts: assesment of shallow-level fractionation and characterization of source composition. Geochim Cosmochim Acta 63(21):3619–3633. doi: 10.1016/s0016-7037(99)00169-6 CrossRefGoogle Scholar
  65. Maughan EK (1988) Geology and petroleum potential, Colorado Park Basin Province, North-Central Colorado. US Geological Survey Open-File Report 88-450 EGoogle Scholar
  66. Mazor E (1972) Paleotemperatures ans other hydrological parameters deduced from noble gases dissolved in groundwater, Jordan Rift Valley, Israel. Geochimica Cosmochimica Acta 36:1321–1326CrossRefGoogle Scholar
  67. Moore J, Adams M, Allis R, Lutz S, Rauzi S (2005) Mineralogical and geochemical consequences of the long-term presence of CO2 in natural reservoirs: an example from the Springerville-St. Johns Field, Arizona, and New Mexico, USA. Chem Geol 217:365CrossRefGoogle Scholar
  68. Moreira M, Kunz J, Allegre C (1998) Rare gas systematics in popping rock: isotopic and elemental compositions in the Upper Mantle. Science 279:1178–1181CrossRefGoogle Scholar
  69. Nimz GJ, Hudson GB (2005) The use of noble gas isotopes for monitoring leakage of geologically stored CO2. In: Thomas DC, Benson SM (eds) Carbon dioxide capture for storage in deep geologic formations. Elsevier, Amsterdam, pp 1113–1128Google Scholar
  70. O’Nions RK, Oxburgh ER (1988) Helium, volatile fluxes and the development of continental crust. Earth Planet Sci Lett 90(3):331–347Google Scholar
  71. Oxburgh ER, O’Nions RK, Hill RI (1986) Helium isotopes in sedimentary basins. Nature 324:632–635CrossRefGoogle Scholar
  72. Ozima M, Podosek PA (2001) Noble gas geochemistry, 2nd edn. Cambridge University Press, CambridgeCrossRefGoogle Scholar
  73. Pashin JC, McIntyr MR (2003) Temperature-pressure conditions in coalbed methane reservoirs of the Black Warrior basin: implications for carbon sequestration and enhanced coalbed methane recovery. Int J Coal Geol 54:167–183CrossRefGoogle Scholar
  74. Petroleum Technology Research Centre 2011 Response to a soil gas study by Petro-Find Geochem LtdGoogle Scholar
  75. Pinti DL, Marty B (1995) Noble gases in crude oils from the Paris Basin, France—implications for the origin of fluids and constraints on oil-water-gas interactions. Geochimica Cosmochimica Acta 59:3389–3404CrossRefGoogle Scholar
  76. Pinti DL, Marty B (1998) Separation of noble gas mixtures from petroleum and their isotopic analysis by mass spectrometry. J Chromatogr A 824(1):109–117CrossRefGoogle Scholar
  77. Pinti DL, Wada N, Matsuda J (1999) Neon excesses in pumice: volcanological implications. J Volcanol Geoth Res 88:279–289CrossRefGoogle Scholar
  78. Podosek PA (1980) Sedimentary noble gases. Geochim Cosmochim Acta 44:1875–1884CrossRefGoogle Scholar
  79. Porcelli D, Woolum D, Cassen P (2001) Deep earth rare gases: initial inventories, capture from the solar nebula, and losses during Moon formation. Earth Planet Sci Lett 193:237–251CrossRefGoogle Scholar
  80. Porcelli D, Ballentine CJ (2002) Models for the distribution of terrestrial noble gases and evolution of the atmosphere. Reviews in Mineralogy and Geochemistry 47:411–480Google Scholar
  81. Porcelli D, Ballentine CJ, Wieler R (2002) An overview of noble gas—Geochemistry and cosmochemistry, noble gases in geochemistry and cosmochemistry, pp 1–19Google Scholar
  82. Rahmstorf S (2010) A new view on sea level rise. Nat Rep Clim Change 4:44–45CrossRefGoogle Scholar
  83. Raistrick M, Mayer B, Shevalier M, Perez RJ, Hutcheon I, Perkins EH, Gunter WD (2006) Using chemical and isotopic data to quantify inoic trapping of carbon dioxide in oil field brines. Environ Sci Technol 40:6744–6749CrossRefGoogle Scholar
  84. Rauzi SL (1999) Carbon dioxde in the St. Johns—Springerville Area, Apache County, Arizonia. Arizonia Geological Survey, Open-File Report 99-2Google Scholar
  85. Sarda P, Battani A, Prinzhofer A (2000) The 20Ne/36Ar ratio as a tracer for ancient oil: the oil–water and gas-water double distillation model. In: Goldschimidt 2000 vol 5(2). Cambridge Publications, Cambridge, p 876Google Scholar
  86. Sarda P, Staudacher T, Allègre CJ et al (1985) 40Ar/36Ar in MORB glasses: constraints on atmosphere and mantle evolution. Earth Planet Sci Lett 72:357–375CrossRefGoogle Scholar
  87. Sherwood Lollar B, Ballentine CJ (2009) Insights into deep carbon derived from noble gases. Nat Geosci 2:543–547CrossRefGoogle Scholar
  88. Sherwood Lollar B, Ballentine CJ, O’Nions RK (1997) The fate of mantle-derived carbon in a continental sedimentary basin: integration of C/He relationships and stable isotope signatures. Geochim Cosmochim Acta 61:2295–2308CrossRefGoogle Scholar
  89. Sherwood Lollar B, O’Nions RK, Ballentine CJ (1994) Helium and neon isotope systematics in carbon dioxide-rich and hydrocarbon-rich gas reservoirs. Geochim Cosmochim Acta 58:5279CrossRefGoogle Scholar
  90. Sherwood Lollar B, Slater GF, Ahad J, Sleep B, Spivack J, Brennan M, MacKenzie P (1999) Contrasting carbon isotope fractionation during biodegradation of trichloroethylene and toluene: Implications for intrinsic bioremediation. Org Geochem 30:813–820CrossRefGoogle Scholar
  91. Shipton ZK, Evans JP, Kirschner D, Kolesar PT, Williams AP, J H (2004) Analysis of leakage through ‘low-peameability’ faults from natural reservoirs in the Colorado Plateau, east-central Utah. In: Baines SJ, Worden RH (eds) Geological storage of carbon dioxide. Geological Society, London, pp 43–58Google Scholar
  92. Spycher N, Pruess K (2005) CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning Chloride Brines at 12–100°C and up to 600 bar. 69(13):3309Google Scholar
  93. Stevens SH, Fox C, White T, Melzer S (2006) Natural CO2 analogs for Carbon Sequestration. Final Report for USDOEGoogle Scholar
  94. Tolstikhin IN, Lehmann BE, Loosli HH, Gautschi A (1996) Helium and argon isotopes in rocks, minerals, and related groundwaters: a case study in northern Switzerland. Geochim Cosmochim Acta 60:1497–1514CrossRefGoogle Scholar
  95. Torgersen T, Clarke WB (1985) Helium accumulation in groundwater, (i): an evaluation of sources and the continental flux of crustal 4He in the Great Artesian Basin, Australia. Geochim Cosmochim Acta 49:1211–1218CrossRefGoogle Scholar
  96. Torgersen T, Kennedy B, van Soest M (2004) Diffusive separation of noble gases and noble gas abundance patterns in sedimentary rocks. Earth Planet Sci Lett 226:477–489CrossRefGoogle Scholar
  97. Torgersen T, Kennedy BM (1999) Air-Xe enrichments in Elk Hills oil field gases: role of water in migration and storage. Earth Planet Sci Lett 167:239–253CrossRefGoogle Scholar
  98. Treiloff M, Kunz J, Clague DA, Harrison D, Allegre CJ (2000) The nature of pristine noble gases in mantle plumes. Science 288:1036–1038CrossRefGoogle Scholar
  99. Trull T, Nadeau S, Pineau F, Polve M, Javoy M (1993) C-He systematics in hotspot xenoliths: Implications for mantle carbon contents and carbon recycling. Earth Planet Sci Lett 118:43CrossRefGoogle Scholar
  100. Wilkinson M, Gilfillan SMV, HaszeldineRS, BallentineCJ (2010) Plumbing the depths: testing natural tracers of subsurface CO2 origin and migration, Utah. In: Grobe M, PashinJC, DodgeRL (eds) Carbon dioxide sequestration in geological media—State of the science. AAPG StudiesGoogle Scholar
  101. Woodward LA (1983) Geology and hydrocarbon potential of the raton basin, New Mexico. In: Fassett JE (ed) Oil and gas fields of the four corners area, vol 3. Four Corners Geological Society, pp 789–799Google Scholar
  102. Wycherley H, Fleet A, Shaw H (1999) Some observations on the origins of large volumes of carbon dioxide accumulations in sedimentary basins. Mar Pet Geol 16:489–494CrossRefGoogle Scholar
  103. Zartman RE, Wasserburg GJ, Reynolds JH (1961) Helium, argon and carbon in some natural gases. J Geophys Res 66:277–306CrossRefGoogle Scholar
  104. Zhou Z, Ballentine CJ, Kipfer R, Schoell M, Thibodeaux S (2005) Noble gas tracing of groundwater/coalbed methane interaction in the San Juan Basin, USA. Geochim Cosmochim Acta 69:5413–5428CrossRefGoogle Scholar

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© Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  1. 1.Lancaster Environment CentreLancaster UniversityLancasterUK
  2. 2.School of GeosciencesUniversity of Edinburgh EdinburghUK

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