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Raman Imaging pp 119-143 | Cite as

Raman Imaging of Micro- and Nano-Structured Materials

  • Valérie Guieu
  • François Lagugné-Labarthet
Chapter
Part of the Springer Series in Optical Sciences book series (SSOS, volume 168)

Abstract

Raman microscopy has emerged as a powerful technique to characterize anisotropic materials with a submicrometer resolution. The use of polarized light allows one to get precise information about the local organization of the relevant molecular groups through the determination of the most probable distribution function. Such a polarized analysis can be conducted under a confocal microscope but caution must be considered because of the use of high numerical aperture objectives. The molecular orientation can be effectively correlated with the topography of the sample when atomic force microscopy experiments are conducted on the same object. In this chapter, we present 2D and 3D Raman imaging results that have been conducted on mesostructured polymer surfaces and on functionalized metallic surfaces that can serve as SERS platforms. In addition, we compare the results obtained on semiconductor nanowires in confocal Raman conditions or benefiting from local tip enhancement.

Keywords

Surface Enhance Raman Scattering Raman Signal Raman Imaging Raman Enhancement Polarization Configuration 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors would like to warmly acknowledge all the collaborators who have participated in experiments, data analysis, and interpretations of the numerous laboratory results in this manuscript in particular, C.Sourisseau, N.Marquestaut, N. Sojic, J. L. Bruneel and D. Talaga (Institut des Sciences Moléculaires, Université Bordeaux 1, France), P. Yang and P.Pauzauskie (Chemistry Department, University of California Berkeley, USA). The authors are also grateful for the financial support from the CNRS (Chemistry Department), the Agence Nationale pour la Recherche (ANR), the Région Aquitaine, and the Canadian discovery grant as well as the Canadian Research Chair program (FLL).

References

  1. 1.
    K. Cimatu, S. Baldelli, J. Am. Chem. Soc. 128, 16016 (2006)CrossRefGoogle Scholar
  2. 2.
    E. Conor, X.S. Xie, Ann. Rev. Anal. Chem. 1, 883 (2008)CrossRefGoogle Scholar
  3. 3.
    F. Lagugné-Labarthet, Y.R. Shen, in Optical Imaging and Microscopy, ed. by P. Török, F.-J. Kao (Springer, New York, 2007), Vol. 87, p. 237Google Scholar
  4. 4.
    E. Betzig, G.H. Patterson, R. Sougrat, O.W. Lindwasser, S. Olenych, J.S. Bonifacino, M.W. Davidson, J. Lippincott-Schwartz, H.F. Hess, Science 313, 1642 (2006)ADSCrossRefGoogle Scholar
  5. 5.
    M.J. Rust, M. Bates, X. Zhuang, Nat Methods 3, 793 (2006)CrossRefGoogle Scholar
  6. 6.
    C. Matthäus, T. Chernenko, J.A. Newmark, C.M. Warner, M. Diem, Biophys. J. 93, 668 (2007)ADSCrossRefGoogle Scholar
  7. 7.
    C. Matthäus, Boydston-White, M. Miljkovic, M. Romeo, M. Diem. Appl. Spectrosc. 60, 1 (2006)Google Scholar
  8. 8.
    T. Lefèvre, M.-E. Rousseau, M. Pézolet, Appl. Spectrosc. 60, 841 (2006)ADSCrossRefGoogle Scholar
  9. 9.
    M.-E. Rousseau, L. Beaulieu, T. Lefèvre, J. Paradis, T. Asakura, M. Pézolet, Biomacromolecules 7, 2512 (2006)CrossRefGoogle Scholar
  10. 10.
    M.-E. Rousseau, T. Lefèvre, L. Beaulieu, T. Asakura, M. Pézolet, Biomacromolecules 5, 2245 (2004)CrossRefGoogle Scholar
  11. 11.
    P.R. Carey, Annu. Rev. Phys. Chem. 57, 527 (2006)ADSCrossRefGoogle Scholar
  12. 12.
    D.L. Jeanmaire, R.P. Van Duyne, J. Electroanal. Chem. 84, 1 (1977)CrossRefGoogle Scholar
  13. 13.
    M. Fleischmann, P.J. Hendra, A.J. McQuillan, Chem. Phys. Lett. 26, 163 (1974)ADSCrossRefGoogle Scholar
  14. 14.
    M. Moskovits, J. Raman Spectrosc. 36, 485 (2005)ADSCrossRefGoogle Scholar
  15. 15.
    Y. Li, W. Cai, G. Duan, Chem. Mater. 20, 615 (2008)CrossRefGoogle Scholar
  16. 16.
    C.E. Talley, J.B. Jackson, C. Oubre, N.K. Grady, C.W. Hollars, S.M. Lane, T.R. Huser, P. Nordlander, N.J. Halas, Nano Lett. 5, 1569 (2005)ADSCrossRefGoogle Scholar
  17. 17.
    N. Anderson, P. Anger, A. Hartschuh, L. Novotny, Nano Lett. 6, 744 (2006)ADSCrossRefGoogle Scholar
  18. 18.
    A.R. Tao, P. Yang, J. Phys. Chem. B 109, 15687 (2005)CrossRefGoogle Scholar
  19. 19.
    J.J. Baumberg, T.A. Kelf, Y. Sugawara, S. Cintra, M.E. Abdelsalam, P.N. Bartlett, A.E. Russell, Nano Lett. 5, 2262 (2005)ADSCrossRefGoogle Scholar
  20. 20.
    J. Henzie, K.L. Shuford, E.-S. Kwak, G.C. Schatz, T.W. Odom, J. Phys. Chem. B 110, 14028 (2006)CrossRefGoogle Scholar
  21. 21.
    Y. Lu, G.L. Liu, J. Kim, Y.X. Mejia, L.P. Lee, Nano Lett. 5, 119 (2005)ADSCrossRefGoogle Scholar
  22. 22.
    S.J. Oldenburg, J.B. Jackson, S.L. Wescott, N.J. Halas, J. Appl. Phys. Lett. 75, 2897 (1999)ADSCrossRefGoogle Scholar
  23. 23.
    R.A. Alvarez-Puebal, B. Cui, J.-P. Bravo-Vasquez, T. Veres, H. Fenniri, J. Phys. Chem. C 111, 6720 (2007)CrossRefGoogle Scholar
  24. 24.
    B. Cui, T. Veres, Microelectron. Eng. 84, 1544 (2007)CrossRefGoogle Scholar
  25. 25.
    N. Félidj, J. Aubard, G. Lévi, J. R. Krenn, M. Salermo, G. Schider, B. Lamprecht, A. Leitner, F. R. Aussenegg: Phys. Rev. B 65, 075419(1) (2002)Google Scholar
  26. 26.
    A.G. Brolo, E. Arctander, R. Gordon, B. Leathem, K.L. Kavanagh, Nano Lett. 4, 2015 (2004)ADSCrossRefGoogle Scholar
  27. 27.
    M.A.D. Jesus, K.S. Giesfeldt, J.M. Oran, N.A. Abu-Hatab, N.V. Lavrik, M.J. Sepaniak, Appl. Spectrosc. 59, 1501 (2005)ADSCrossRefGoogle Scholar
  28. 28.
    B. Cui, L. Clime, K. Li, T. Veres, Nanotechnology 19, 145302/1 (2008)Google Scholar
  29. 29.
    C.L. Haynes, A.D. McFarland, R.P. Van Duyne, Anal. Chem. 77, 338A (2005)CrossRefGoogle Scholar
  30. 30.
    S. Nie, D.R. Emory, Science 275, 1102 (1997)CrossRefGoogle Scholar
  31. 31.
    K. Kneipp, H. Kneipp Appl, Spectrosc. 60, 322 (2006)ADSCrossRefGoogle Scholar
  32. 32.
    A. Rasmussen, V. Deckert, J. Raman Spectrosc. 37, 311 (2006)ADSCrossRefGoogle Scholar
  33. 33.
    Y. Saito, N. Hayazama, H. Kataura, T. Murakami, K. Tsukagoshi, Y. Inouye, S. Kawata, Chem. Phys. Lett. 136, (2005)Google Scholar
  34. 34.
    B. Pettinger, G. Picardi, R. Schuster, G. Ertl, Single Mol. 5, 285 (2002)Google Scholar
  35. 35.
    A. Hartschuh, Angew. Chem. Int. Ed. 47, 8178 (2008)CrossRefGoogle Scholar
  36. 36.
    C.C. Neacsu, J. Dreyer, N. Behr, M.B. Raschke, Phys. Rev. B 73, 193406/1 (2006)Google Scholar
  37. 37.
    F. Wei, D. Zhang, N.J. Halas, J.D. Hartgerink, J. Phys. Chem. B 113, 9158 (2008)Google Scholar
  38. 38.
    C. Dana, T. Deckert-Gaudig, C. Budich, M. Laue, R. Moeller, D. Naumann, V. Deckert, J. Popp J. Raman Spectrosc. 40, 240 (2009)ADSCrossRefGoogle Scholar
  39. 39.
    W. Zhang, B.S. Yeo, T. Schmid, R. Zenobi, J. Phys. Chem. C 111, 1733 (2007)CrossRefGoogle Scholar
  40. 40.
    P. Pauzauskie, T. Kuykendall, Y. Zhuang, J. Goldberger, D. Suirbully, J. Denlinger, P. Yang, Nat. Mater. 3, 524 (2004)ADSCrossRefGoogle Scholar
  41. 41.
    H. Choi, J. Johnson, R. He, S.-K. Lee, F. Kim, P. Pauzauskie, J. Goldberger, R. Saykally, P. Yang, J. Phys. Chem. B 107, 8721 (2003)Google Scholar
  42. 42.
    Y. Huan, X. Duan, Y. Cui, C.M. Lieber, Nano Lett. 2, 101 (2002)ADSCrossRefGoogle Scholar
  43. 43.
    P.J. Pauzauskie, D. Talaga, K. Seo, P. Yang, F. Lagugné-Labarthet, J. Am. Chem. Soc. 127, 17146 (2005)CrossRefGoogle Scholar
  44. 44.
    H. Harima, J. Phys. Condens Matter. 14, R967 (2002)Google Scholar
  45. 45.
    T. Azuhata, T. Sota, K. Suzuki, S. Nakamura, J. Phys. Condens Matter. 7, L129 (1995)Google Scholar
  46. 46.
    J. Liu, X.-M. Meng, Y. Jiang, C.-S. Lee, I. Bello, S.-T. Lee, Appl. Phys. Lett. 83, 4241 (2003)ADSCrossRefGoogle Scholar
  47. 47.
    H.-L. Liu, C.-C. Chen, C.-T. Chia, C.-C. Yeh, C.-H. Chen, M.-Y. Yu, S. Keller, S.P. DenBaars, Chem. Phys. Lett. 345, 245 (2001)ADSCrossRefGoogle Scholar
  48. 48.
    T. Livneh, J. Zhang, G. Cheng, M. Moskovits, Phys. Rev. B 74, 035320/1 (2006)Google Scholar
  49. 49.
    V. Poborchii, T. Tada, T. Kanayama, Appl. Phys. Lett. 89, 233505/1 (2006)Google Scholar
  50. 50.
    A. Hartschuh, E.J. Sanchez, X.S. Xie, L. Novotny, Phys. Rev. Lett. 90, 095503 (2003)ADSCrossRefGoogle Scholar
  51. 51.
    A. Hartschuh, H. Qian, A.J. Meixner, N. Anderson, L. Novotny, Surf. Interface Anal. 38, 1472 (2006)CrossRefGoogle Scholar
  52. 52.
    R. Matsui, P. Verma, T. Ichimura, Y. Inouye, S. Kawata, Appl. Phys. Lett. 90, 061906 (2007)ADSCrossRefGoogle Scholar
  53. 53.
    J. Delaire, K. Nakatani, Chem. Rev. 100, 1817 (2000)CrossRefGoogle Scholar
  54. 54.
    A. Natansohn, P. Rochon, Chem. Rev. 102, 4139 (2002)CrossRefGoogle Scholar
  55. 55.
    R.D. Schaller, R. Saykally, Y.R. Shen, F. Lagugné-Labarthet, Opt. lett. 28, 1296 (2003)ADSCrossRefGoogle Scholar
  56. 56.
    F. Lagugné-Labarthet, C. Sourisseau, R.D. Schaller, R.J. Saykally, P. Rochon, J. Phys. Chem. B 108, 17059 (2004)CrossRefGoogle Scholar
  57. 57.
    F. Lagugné-Labarthet, F. Adamietz, V. Rodriguez, C. Sourisseau, J. Phys. Chem. B. 110, 13689 (2006)CrossRefGoogle Scholar
  58. 58.
    F. Lagugné-Labarthet, T. Buffeteau, C. Sourisseau, J. Phys. Chem. B. 103, 6690 (1999)CrossRefGoogle Scholar
  59. 59.
    Z. Sekkat, M. Dumont, Synth. Met. 54, 373 (1993)CrossRefGoogle Scholar
  60. 60.
    C. Sourisseau, Chem. Rev. 104, 3851 (2004)CrossRefGoogle Scholar
  61. 61.
    C. Sourisseau, D. Talaga, Appl. Spectrosc. 60, 1368 (2006)ADSCrossRefGoogle Scholar
  62. 62.
    C. Brémard, P. Dhamelincourt, J. Laurens, G. Turell, Appl. Spectrosc. 39, 1036 (1985)ADSCrossRefGoogle Scholar
  63. 63.
    C. Brémard, J. Laureyns, J.C. Merlin, G. Turell, J. Raman Spectrosc. 18, 305 (1987)ADSCrossRefGoogle Scholar
  64. 64.
    G. Turrell, J. Raman Spectrosc. 15, 103 (1984)ADSCrossRefGoogle Scholar
  65. 65.
    S. Lal, N.K. Grady, J. Kundu, C.S. Levin, J.B. Lassiter, N.J. Halas, Chem. Soc. Rev. 37, 898 (2008)CrossRefGoogle Scholar
  66. 66.
    N. Marquestaut, A. Martin, D. Talaga, L. Servant, S. Ravaine, S. Reculusa, D.M. Bassani, E. Gillies, F. Lagugné-Labarthet, Langmuir 24, 11313 (2008)CrossRefGoogle Scholar
  67. 67.
    C.L. Haynes, R.P. Van Duyne, J. Phys. Chem. B 105, 5599 (2001)CrossRefGoogle Scholar
  68. 68.
    G.C. Schatz, M.A. Young, R.P. Van Duyne, in Surface-Enhanced Raman Scattering, ed. by K. Kneipp, M. Moskovits, H. Kneipp (Springer, Berlin, 2006) Vol. 103, p 19Google Scholar
  69. 69.
    N. Félidj, S. Truong, J. Aubard, G. Lévi, J.R. Krenn, A. Hohenau, A. Leitner, F.R. Aussenegg, J. Chem. Phys. 120, 7141 (2004)ADSCrossRefGoogle Scholar
  70. 70.
    E.C. Le Ru, E. Blackie, M. Meyer, P.G. Etchegoin, J. Phys. Chem. C 111, 13794 (2007)CrossRefGoogle Scholar
  71. 71.
    O. Schubert, J. Becker, L. Carbone, Y. Khalavka, T. Provalska, I. Zins, C. Sönnichsen, Nano Lett. 8, 2345 (2008)ADSCrossRefGoogle Scholar
  72. 72.
    D.S. Hubbard, M.P. Houlne, G.E. Kiefer, K. McMillan, D.J. Bornhop, Bioimaging 6, 63 (1998)CrossRefGoogle Scholar
  73. 73.
    Y. Kiomacho, H. Sato, K. Aizawa, H. Tashiro, Appl. Opt. 44, 4722 (2005)ADSCrossRefGoogle Scholar
  74. 74.
    J.M. Song, P.M. Kasili, G.D. FGriffin, T. Vo-Dinh, Anal. Chem. 76, 2591 (2004)Google Scholar
  75. 75.
    C. Amatore, A. Chauvin, P. Garrigue, L. Servant, N. Sojic, S. Szunerits, L. Thouin, Anal. Chem. 76, 7202 (2004)CrossRefGoogle Scholar
  76. 76.
    E.J. Smythe, M.D. Dickey, J. Bao, G.M. Whitesides, F. Capasso, Nano Lett. 9, 1132 (2009)ADSCrossRefGoogle Scholar
  77. 77.
    D.J. White, A.P. Mazzolini, P.R. Stoddart, J. Raman Spectrosc. 38, 377 (2007)ADSCrossRefGoogle Scholar
  78. 78.
    D.J. White, P.R. Stoddart, Opt. Lett. 30, 598 (2005)ADSCrossRefGoogle Scholar
  79. 79.
    M.E. Hankus, H. Li, G.J. Gibson, B.M. Cullum, Anal. Chem. 78, 7535 (2006)CrossRefGoogle Scholar
  80. 80.
    T. Murphy, S. Lucht, H. Schmidt, H.-D. Kronfeldt, J. Raman Spectrosc. 31, 943 (2000)ADSCrossRefGoogle Scholar
  81. 81.
    E. Polwart, R.L. Keir, C.M. Davidson, W.E. Smith, D.A. Sadler, Appl. Spectrosc. 54, 522 (2000)ADSCrossRefGoogle Scholar
  82. 82.
    V. Guieu, F. Lagugné-Labarthet, L. Servant, D. Talaga, N. Sojic, Small 4, 96 (2008)CrossRefGoogle Scholar
  83. 83.
    V. Guieu, D. Talaga, L. Servant, N. Sojic, F. Lagugné-Labarthet, J. Phys. Chem. C 113, 874 (2009)CrossRefGoogle Scholar
  84. 84.
    P. Pantano, D.R. Walt, Rev. Sci. Instrum. 68, 1357 (1997)ADSCrossRefGoogle Scholar
  85. 85.
    J. Engelking, M. Witteman, M. Rehahn, H. Menzel, Langmuir 16, 3407 (2000)CrossRefGoogle Scholar
  86. 86.
    R.M. Roth, N.C. Panoiu, M.M. Adams, R.M. Osgood, C.C. Neacsu, M.B. Raschke, Opt. Express 14, 2922 (2006)ADSGoogle Scholar
  87. 87.
    C.C. Neacsu, G.A. Steudle, M.B. Raschke, App. Phys. B. 80, 295 (2005)ADSCrossRefGoogle Scholar
  88. 88.
    A.L. Demming, F. Festy, D. Richards, J. Chem. Phys. 122, 184716 (2005)ADSCrossRefGoogle Scholar
  89. 89.
    D.P. Fromm, A. Sundaramurthy, P.J. Schuck, G. Kino, W.E. Moerner, Nano Lett. 4, 957 (2004)ADSCrossRefGoogle Scholar
  90. 90.
    D.P. Fromm, A. Sundaramurthy, A. Kinkhabwala, P.J. Schuck, G.S. Kino, W.E. Moerner, J. Chem. Phys. 124, 061101 (2006)ADSCrossRefGoogle Scholar
  91. 91.
    L. Novotny, Nature 455, 887 (2008)ADSCrossRefGoogle Scholar
  92. 92.
    T. Deckert-Gaudig, V. Deckert, Small 5, 432 (2009)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.Institut des Sciences moléculaires, UMR 5255Université Bordeaux 1Talence CedexFrance
  2. 2.University Of Western OntarioDepartment of ChemistryLondonCanada

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