Some Problems Related to the Surface Thermodynamics of “Solid Electrodes”
Abstract
In this chapter, existing thermodynamic theories for solid–liquid interfaces are critically reviewed. The definition of the “generalized surface intensive parameter” is discussed. Some critical remarks have been made concerning the approach generally used in the literature. A brief review of the derivation of the “generalized Lippmann equation” held to be valid generally for solid electrodes is given. Special attention has been paid to the mathematical consequences of the homogeneous property of the fundamental equation. Inconsistencies in the derivation are cited. Problems related to the so-called “surface Gibbs−Duhem equation” are discussed. Some remarks concerning a recent theoretical debate on the derivation of the Shuttleworth equation are also included.
Keywords
Liquid Interface Surface Stress Fundamental Equation Homogeneous Function Extensive VariableReferences
- 1.Trasatti S, Parsons R (1986) Pure Appl Chem 58:437–454CrossRefGoogle Scholar
- 2.Láng G, Heusler KE (1994) J Electroanal Chem 377:1–7CrossRefGoogle Scholar
- 3.Láng G, Heusler KE (1999) J Electroanal Chem 472:168–173CrossRefGoogle Scholar
- 4.Marichev VA (2006) Surf Sci 600:4527–4536CrossRefGoogle Scholar
- 5.Marichev VA (2010) Adv Colloid Interface Sci 157:34–60CrossRefGoogle Scholar
- 6.Go J-Y, Pyun S-I (2004) J Kor Electrochem Soc 7:211–219CrossRefGoogle Scholar
- 7.Guidelli R (1998) J Electroanal Chem 453:69–77Google Scholar
- 8.Guidelli R (1999) J Electroanal Chem 472:174–177Google Scholar
- 9.Lipkowski J, Schmickler W, Kolb DM, Parsons R (1998) J Electroanal Chem 452:193–197Google Scholar
- 10.Schmickler W, Leiva E (1998) J Electroanal Chem 453:61–67CrossRefGoogle Scholar
- 11.Valincius G (1999) J Electroanal Chem 478:40–49CrossRefGoogle Scholar
- 12.Haiss W (2001) Rep Prog Phys 64:591–648CrossRefGoogle Scholar
- 13.Tian F, Pei JH, Hedden DL, Brown GM, Thundat T (2004) Ultramicroscopy 100:217–223CrossRefGoogle Scholar
- 14.Tabard-Cossa V, Godin M, Burgess IJ, Monga T, Lenox RB, Grütter P (2007) Anal Chem 79:8136–8143CrossRefGoogle Scholar
- 15.Kramer D (2007) Phys Chem Chem Phys 10:168–177CrossRefGoogle Scholar
- 16.Garcia-Araez N (2011) J Phys Chem C 115:501–510CrossRefGoogle Scholar
- 17.Eriksson JC (1969) Surf Sci 14:221–246CrossRefGoogle Scholar
- 18.Linford RG (1973) J Electroanal Chem 43:155–157CrossRefGoogle Scholar
- 19.Linford RG (1978) Chem Rev 78:81–95CrossRefGoogle Scholar
- 20.Couchman PR, Jesser WA, Kuhlmann-Wilsdorf D (1972) Surf Sci 33:429–436CrossRefGoogle Scholar
- 21.Couchman PR, Jesser WA (1973) Surf Sci 34:212–224CrossRefGoogle Scholar
- 22.Couchman PR, Everett DH, Jesser WA (1975) J Colloid Interface Sci 52:410–411CrossRefGoogle Scholar
- 23.Couchman PR, Everett DH (1976) J Electroanal Chem 67:382–386CrossRefGoogle Scholar
- 24.Couchman PR, Davidson CR (1977) J Electroanal Chem 85:407–409CrossRefGoogle Scholar
- 25.Gutman EM (1995) J Phys Condens Matter 7:L663–L667CrossRefGoogle Scholar
- 26.Shuttleworth R (1950) Proc Phys Soc A 63:444–457CrossRefGoogle Scholar
- 27.Herring C (1953) The use of classical macroscopic concepts in surface energy problem. In: Gomer R, Smith CS (eds) Structure and properties of solid surfaces. The University of Chicago Press, ChicagoGoogle Scholar
- 28.Bottomley DJ, Makkonen L, Kolari K (2009) Surf Sci 603:97–101CrossRefGoogle Scholar
- 29.Hermann R (1973) Geometry, physics and systems. Marcel Dekker, New YorkGoogle Scholar
- 30.Bottomley DJ, Makkonen L, Kolari K (2009) Surf Sci 603:2347CrossRefGoogle Scholar
- 31.Bottomley DJ, Makkonen L, Kolari K (2009) Surf Sci 603:2350–2351CrossRefGoogle Scholar
- 32.Bottomley DJ, Makkonen L, Kolari K (2009) Surf Sci 603:2356–2357CrossRefGoogle Scholar
- 33.Eriksson JC, Rusanov AI (2009) Surf Sci 603:2348–2349CrossRefGoogle Scholar
- 34.Marichev VA (2009) Surf Sci 603:2345–2346CrossRefGoogle Scholar
- 35.Ibach H (2009) Surf Sci 603:2352–2355CrossRefGoogle Scholar
- 36.Rusanov AI, Shchekin AK, Tatyanenko DV (2009) J Chem Phys 131:161104CrossRefGoogle Scholar
- 37.Marichev VA (2009) Colloids Surf A Physicochem Eng Asp 345:1–12CrossRefGoogle Scholar
- 38.Bottomley DJ, Makkonen L, Kolari K (2010) Surf Sci 604:2066–2068CrossRefGoogle Scholar
- 39.Eriksson JC, Rusanov AI (2010) Surf Sci 603:1062–1063CrossRefGoogle Scholar
- 40.Eriksson JC, Rusanov AI (2010) Surf Sci 604:2069–2071CrossRefGoogle Scholar
- 41.Marichev VA (2010) Prot Met 46:383–402Google Scholar
- 42.Marichev VA (2011) Prot Met 47:25–30Google Scholar
- 43.Marichev VA (2011) Colloids Surf A Physicochem Eng Asp 389:63–68CrossRefGoogle Scholar