Abstract
Fabrication of superhydrophobic surfaces has been an area of active research since the mid-1990s. In general, the same techniques that are used for micro- and nanostructure fabrication, such as lithography, etching, deposition, and self-assembly, have been utilized for producing superhydrophobic surfaces (Fig. 5.1; Table 5.1). The pros and cons of these techniques are summarized in Table 5.2. Among especially interesting developments is the creation of switchable surfaces that can be turned from hydrophobic to hydrophilic by surface energy modification through electrowetting, light and X-ray irradiation, dynamic effects, optical effects (e.g., the transparence, reflectivity or non-reflectivity) combined with the Lotus effect, hydrophobic interactions, and so on (Feng et al., 2004; Xu et al., 2005; Shirtcliffe et al., 2005; Wang et al., 2007; Krupenkin et al., 2007). An important requirement for potential applications for optics and self-cleaning glasses is the creation of transparent superhydrophobic surfaces.
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Abdelsalam ME, Bartlett PN, Kelf T, Baumberg J (2005) Wetting of regularly structured gold surfaces. Langmuir 21:1753–1757
Bhushan B, Jung YC (2007) Wetting study of patterned surfaces for superhydrophobicity. Ultramicroscopy 107:1033–1041
Bhushan B, Koch K, Jung YC (2008a) Nanostructures for superhydrophobicity and low adhesion. Soft Matter 4:1799–1804
Bhushan B, Koch K, Jung YC (2008b) Biomimetic hierarchical structure for self-cleaning. Appl Phys Lett 93:093101
Bhushan B, Jung YC, Niemietz A, Koch K (2009a) Lotus-like biomimetic hierarchical structures developed by the self-assembly of tubular plant waxes. Langmuir 25:1659–1666
Bhushan B, Koch K, Jung YC (2009b) Fabrication and characterization of the hierarchical structure for superhydrophobicity. Ultramicroscopy 109:1029–1034
Bormashenko E, Stein T, Whyman G, Bormashenko Y, Pogreb E (2006) Wetting properties of the multiscaled nanostructured polymer and metallic superhydrophobic surfaces. Langmuir 22:9982–9985
Cappella B, Bonaccurso E (2007) Solvent-assisted nanolithography on polystyrene surfaces using the atomic force microscope. Nanotechnology 18:155307
Chiou N, Lu C, Guan J, Lee LJ, Epstein AJ (2007) Growth and alignment of polyaniline nanofibres with superhydrophobic, superhydrophilic and other properties. Nat Nanotechnol 2:354–357
Chong MAS, Zheng YB, Gao H, Tan LK (2006) Combinational template-assisted fabrication of hierarchically ordered nanowire arrays on substrates for device applications. Appl Phys Lett 89:233104
Cortese B, Amone SD, Manca M, Viola I, Cingolani R, Gigli G (2008) Superhydrophobicity due to the hierarchical scale roughness of PDMS surfaces. Langmuir 24:2712–2718
Coulson SR, Woodward I, Badyal JPS, Brewer SA, Willis C (2000) Super-repellent composite fluoropolymer surfaces. J Phys Chem B 104:8836–8840
del Campo A, Greiner C (2007) SU-8: a photoresist for high-aspect-ratio and 3D submicron lithography. J Micromech Microeng 17:R81–R95
Ebert D, Bhushan B (2012) Durable lotus-effect surfaces with hierarchical structure using micro- and nanosized hydrophobic silica particles. J Colloid Interface Sci 368:584–591
Feng XJ, Feng L, Jin MH, Zhai J, Jiang L, Zhu DB (2004) Reversible Super-hydrophobicity to super-hydrophilicity transition of aligned ZnO nanorod films. J Am Chem Soc 126:62–63
Fürstner R, Barthlott W, Neinhuis C, Walzel P (2005) Wetting and self-cleaning properties of artificial superhydrophobic surfaces. Langmuir 21:956–961
Han JT, Jang Y, Lee DY, Park JH, Song SH, Ban DY, Cho K (2005) Fabrication of a bionic superhydrophobic metal surface by sulfur-induced morphological development. J Mater Chem 15:3089–3092
Hikita M, Tanaka K, Nakamura T, Kajiyama T, Takahara A (2005) Superliquid-repellent surfaces prepared by colloidal silica nanoparticles covered with fluoroalkyl groups. Langmuir 21:7299–7302
Hosono E, Fujihara S, Honma I, Zhou H (2005) Superhydrophobic perpendicular nanopin film by the bottom-up process. J Am Chem Soc 127:13458–13459
Huang L, Lau SP, Yang HY, Leong ESP, Yu SF (2005) Stable superhydrophobic surface via carbon nanotubes coated with a ZnO thin film. J Phys Chem 109:7746–7748
Jansen H, de Boer M, Legtenberg R, Elwenspoek M (1995) The black silicon method: a universal method for determining the parameter setting of a fluorine-based reactive ion etcher in deep silicon trench etching with profile control. J Micromech Microeng 5:115–120
Jung YC, Bhushan B (2006) Contact angle, adhesion, and friction properties of micro- and nanopatterned polymers for superhydrophobicity. Nanotechnology 17:4970–4980
Jung YC, Bhushan B (2009) Mechanically durable CNT-composite hierarchical structures with superhydrophobicity, self-cleaning, and low-drag. ACS Nano 3:4155–4163
Khorasani MT, Mirzadeh H, Kermani Z (2005) Wettability of porous polydimethylsiloxane surface: morphology study. Appl Surf Sci 242:339–345
Kim D, Hwang W, Park HC, Lee KH (2007) Superhydrophobic micro- and nanostructures based on polymer sticking. Key Eng Mater 334–335:897–900
Klein RJ, Biesheuvel PM, Yu BC, Meinhart CD, Lange FF (2003) Producing super-hydrophobic surfaces with nano-silica spheres. Z Metallkd 94:377–380
Koch K, Bhushan B, Jung YC, Barthlott W (2009b) Fabrication of artificial lotus leaves and significance of hierarchical structure for superhydrophobicity and low adhesion. Soft Matter 5:1386–1393
Krupenkin TN, Taylor JA, Wang EN, Kolodner P, Hodes M, Salamon TR (2007) Reversible wetting-dewetting transitions on delectrically tunable superhydrophobic nanostructured surfaces. Langmuir 23:9128–9133
Kuan CY, Hon MH, Chou JM, Leu IC (2009) Wetting characteristics on micro/nanostructured zinc oxide coatings. J Electrochem Soc 156:J32–J36
Lau KKS, Bico J, Teo KBK, Chhowalla M, Amaratunga GAJ, Milne WI, McKinley GH, Gleason KK (2003) Superhydrophobic carbon nanotube forests. Nano Lett 3:1701–1705
Lee H, Bhushan B (2012) Fabrication and characterization of hierarchical nanostructured smart adhesion surfaces. (unpublished)
Lee W, Jin M, Yoo W, Lee J (2004) Nanostructuring of a polymeric substrate with well-defined nanometer-scale topography and tailored surface wettability. Langmuir 20:7665–7669
Ma M, Hill RM (2006) Superhydrophobic surfaces. Curr Opin Colloid Interface Sci 11:193–202
Ma M, Hill RM, Lowery JL, Fridrikh SV, Rutledge GC (2005) Electrospun poly(styrene-block-dimethylsiloxane) block copolymer fibers exhibiting superhydrophobicity. Langmuir 21:5549–5554
Martin C, Rius G, Borrise X, Perez-Murano F (2005) Nanolithography on thin layers of PMMA using atomic force microscopy. Nanotechnology 16:1016–1022
Martines E, Seunarine K, Morgan H, Gadegaard N, Wilkinson CDW, Riehle MO (2005) Superhydrophobicity and superhydrophilicity of regular nanopatterns. Nano Lett 5:2097–2103
Ming W, Wu D, van Benthem R, de With G (2005) Superhydrophobic films from raspberry-like particles. Nano Lett 5:2298–2301
Nakajima A, Fujishima A, Hashimoto K, Watanabe T (1999) Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate. Adv Mater 11:1365–1368
Northen MT, Turner KL (2005) A batch fabricated biomimetic dry adhesive. Nanotechnology 16:1159–1166
Qian B, Shen Z (2005) Fabrication of superhydrophobic surfaces by dislocation-selective chemical etching on aluminum, copper, and zinc substrates. Langmuir 21:9007–9009
Shang HM, Wang Y, Limmer SJ, Chou TP, Takahashi K, Cao GZ (2005) Optically transparent superhydrophobic silica-based films. Thin Solid Films 472:37–43
Shi F, Song Y, Niu J, Xia X, Wang Z, Zhang X (2006) Facile method to fabricate a large-scale superhydrophobic surface by galvanic cell reaction. Chem Mater 18:1365–1368
Shibuichi S, Onda T, Satoh N, Tsujii K (1996) Super-water-repellent surfaces resulting from fractal structure. J Phys Chem 100:19512–19517
Shirtcliffe NJ, McHale G, Newton MI, Chabrol G, Perry CC (2004) Dual-scale roughness produces unusually water-repellent surfaces. Adv Mater 16:1929–1932
Shirtcliffe NJ, McHale G, Newton MI, Perry CC, Roach P (2005) Porous materials show superhydrophobic to superhydrophilic switching. Chem Commun 3135–3137
Shiu J, Kuo C, Chen P, Mou C (2004) Fabrication of tunable superhydrophobic surfaces by nanosphere lithography. Chem Mater 16:561–564
Sun M, Luo C, Xu L, Ji H, Ouyang Q, Yu D, Chen Y (2005) Artificial lotus leaf by nanocasting. Langmuir 21:8978–8981
Teshima K, Sugimura H, Inoue Y, Takai O, Takano A (2005) Transparent ultra water-repellent poly(ethylene terephthalate) substrates fabricated by oxygen plasma treatment and subsequent hydrophobic coating. Appl Surf Sci 244:619–622
Wang Y, Zhu Q, Zhang H (2006) Fabrication and magnetic properties of hierarchical porous hollow nickel microspheres. J Mater Chem 16:1212–1214
Wang S, Liu H, Liu D, Ma X, Fang X, Jiang L (2007) Enthalpy driven three state switching of a superhydrophilic/superhydrophobic surfaces. Angew Chem Int Ed 46:3915–3917
Wu X, Zheng L, Wu D (2005) Fabrication of superhydrophobic surfaces from microstructured ZnO-based surfaces via a wet-chemical route. Langmuir 21:2665–2667
Xu L, Chen W, Mulchandani A, Yan Y (2005) Reversible conversion of conducting polymer films from superhydrophobic to superhydrophilic. Angew Chem Int Ed 44:6009–6012
Yabu H, Shimomura M (2005) Single-step fabrication of transparent superhydrophobic porous polymer films. Chem Mater 17:5231–5234
Zhai L, Cebeci FC, Cohen RE, Rubner MF (2004) Stable superhydrophobic coatings from polyelectrolyte multilayers. Nano Lett 4:1349–1353
Zhang JL, Li JA, Han YC (2004a) Superhydrophobic PTFE surfaces by extension. Macromol Rapid Commun 25:1105–1108
Zhang X, Feng S, Yu X, Liu H, Fu Y, Wang Z, Jiang L, Li X (2004b) Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface. J Am Chem Soc 126:3064–3065
Zhao N, Xie QD, Weng LH, Wang SQ, Zhang XY, Xu J (2005) Superhydrophobic surface from vapor-induced phase separation of copolymer micellar solution. Macromolecules 38:8996–8999
Zhao Y, Tong T, Delzeit L, Kashani A, Meyyappan M, Majumdar A (2006) Interfacial energy and strength of multiwalled-carbon-nanotube-based dry adhesive. J Vac Sci Technol B 24:331–335
Zhao Y, Li M, Lu Q, Shi Z (2008) Superhydrophobic polyimide films with a hierarchical topography: combined replica molding and layer-by-layer assembly. Langmuir 24:12651–12657
Zhu L, Xiu Y, Xu J, Tamirisa PA, Hess DW, Wong C (2005) Superhydrophobicity on two-tier rough surfaces fabricated by controlled growth of aligned carbon nanotube arrays coated with fluorocarbon. Langmuir 21:11208–11212
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Bhushan, B. (2012). Fabrication Techniques Used for Structures with Superhydrophobicity, Self-Cleaning, Low Adhesion/Low Drag with Antifouling Properties. In: Biomimetics. Biological and Medical Physics, Biomedical Engineering. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-25408-6_5
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DOI: https://doi.org/10.1007/978-3-642-25408-6_5
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