Skip to main content

Fabrication Techniques Used for Structures with Superhydrophobicity, Self-Cleaning, Low Adhesion/Low Drag with Antifouling Properties

  • Chapter
  • First Online:

Part of the book series: Biological and Medical Physics, Biomedical Engineering ((BIOMEDICAL))

Abstract

Fabrication of superhydrophobic surfaces has been an area of active research since the mid-1990s. In general, the same techniques that are used for micro- and nanostructure fabrication, such as lithography, etching, deposition, and self-assembly, have been utilized for producing superhydrophobic surfaces (Fig. 5.1; Table 5.1). The pros and cons of these techniques are summarized in Table 5.2. Among especially interesting developments is the creation of switchable surfaces that can be turned from hydrophobic to hydrophilic by surface energy modification through electrowetting, light and X-ray irradiation, dynamic effects, optical effects (e.g., the transparence, reflectivity or non-reflectivity) combined with the Lotus effect, hydrophobic interactions, and so on (Feng et al., 2004; Xu et al., 2005; Shirtcliffe et al., 2005; Wang et al., 2007; Krupenkin et al., 2007). An important requirement for potential applications for optics and self-cleaning glasses is the creation of transparent superhydrophobic surfaces.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   119.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   159.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. Abdelsalam ME, Bartlett PN, Kelf T, Baumberg J (2005) Wetting of regularly structured gold surfaces. Langmuir 21:1753–1757

    Google Scholar 

  2. Bhushan B, Jung YC (2007) Wetting study of patterned surfaces for superhydrophobicity. Ultramicroscopy 107:1033–1041

    Google Scholar 

  3. Bhushan B, Koch K, Jung YC (2008a) Nanostructures for superhydrophobicity and low adhesion. Soft Matter 4:1799–1804

    Google Scholar 

  4. Bhushan B, Koch K, Jung YC (2008b) Biomimetic hierarchical structure for self-cleaning. Appl Phys Lett 93:093101

    Google Scholar 

  5. Bhushan B, Jung YC, Niemietz A, Koch K (2009a) Lotus-like biomimetic hierarchical structures developed by the self-assembly of tubular plant waxes. Langmuir 25:1659–1666

    Google Scholar 

  6. Bhushan B, Koch K, Jung YC (2009b) Fabrication and characterization of the hierarchical structure for superhydrophobicity. Ultramicroscopy 109:1029–1034

    Google Scholar 

  7. Bormashenko E, Stein T, Whyman G, Bormashenko Y, Pogreb E (2006) Wetting properties of the multiscaled nanostructured polymer and metallic superhydrophobic surfaces. Langmuir 22:9982–9985

    Google Scholar 

  8. Cappella B, Bonaccurso E (2007) Solvent-assisted nanolithography on polystyrene surfaces using the atomic force microscope. Nanotechnology 18:155307

    Google Scholar 

  9. Chiou N, Lu C, Guan J, Lee LJ, Epstein AJ (2007) Growth and alignment of polyaniline nanofibres with superhydrophobic, superhydrophilic and other properties. Nat Nanotechnol 2:354–357

    Google Scholar 

  10. Chong MAS, Zheng YB, Gao H, Tan LK (2006) Combinational template-assisted fabrication of hierarchically ordered nanowire arrays on substrates for device applications. Appl Phys Lett 89:233104

    Google Scholar 

  11. Cortese B, Amone SD, Manca M, Viola I, Cingolani R, Gigli G (2008) Superhydrophobicity due to the hierarchical scale roughness of PDMS surfaces. Langmuir 24:2712–2718

    Google Scholar 

  12. Coulson SR, Woodward I, Badyal JPS, Brewer SA, Willis C (2000) Super-repellent composite fluoropolymer surfaces. J Phys Chem B 104:8836–8840

    Google Scholar 

  13. del Campo A, Greiner C (2007) SU-8: a photoresist for high-aspect-ratio and 3D submicron lithography. J Micromech Microeng 17:R81–R95

    Google Scholar 

  14. Ebert D, Bhushan B (2012) Durable lotus-effect surfaces with hierarchical structure using micro- and nanosized hydrophobic silica particles. J Colloid Interface Sci 368:584–591

    Google Scholar 

  15. Feng XJ, Feng L, Jin MH, Zhai J, Jiang L, Zhu DB (2004) Reversible Super-hydrophobicity to super-hydrophilicity transition of aligned ZnO nanorod films. J Am Chem Soc 126:62–63

    Google Scholar 

  16. Fürstner R, Barthlott W, Neinhuis C, Walzel P (2005) Wetting and self-cleaning properties of artificial superhydrophobic surfaces. Langmuir 21:956–961

    Google Scholar 

  17. Han JT, Jang Y, Lee DY, Park JH, Song SH, Ban DY, Cho K (2005) Fabrication of a bionic superhydrophobic metal surface by sulfur-induced morphological development. J Mater Chem 15:3089–3092

    Google Scholar 

  18. Hikita M, Tanaka K, Nakamura T, Kajiyama T, Takahara A (2005) Superliquid-repellent surfaces prepared by colloidal silica nanoparticles covered with fluoroalkyl groups. Langmuir 21:7299–7302

    Google Scholar 

  19. Hosono E, Fujihara S, Honma I, Zhou H (2005) Superhydrophobic perpendicular nanopin film by the bottom-up process. J Am Chem Soc 127:13458–13459

    Google Scholar 

  20. Huang L, Lau SP, Yang HY, Leong ESP, Yu SF (2005) Stable superhydrophobic surface via carbon nanotubes coated with a ZnO thin film. J Phys Chem 109:7746–7748

    Google Scholar 

  21. Jansen H, de Boer M, Legtenberg R, Elwenspoek M (1995) The black silicon method: a universal method for determining the parameter setting of a fluorine-based reactive ion etcher in deep silicon trench etching with profile control. J Micromech Microeng 5:115–120

    Google Scholar 

  22. Jung YC, Bhushan B (2006) Contact angle, adhesion, and friction properties of micro- and nanopatterned polymers for superhydrophobicity. Nanotechnology 17:4970–4980

    Google Scholar 

  23. Jung YC, Bhushan B (2009) Mechanically durable CNT-composite hierarchical structures with superhydrophobicity, self-cleaning, and low-drag. ACS Nano 3:4155–4163

    Google Scholar 

  24. Khorasani MT, Mirzadeh H, Kermani Z (2005) Wettability of porous polydimethylsiloxane surface: morphology study. Appl Surf Sci 242:339–345

    Google Scholar 

  25. Kim D, Hwang W, Park HC, Lee KH (2007) Superhydrophobic micro- and nanostructures based on polymer sticking. Key Eng Mater 334–335:897–900

    Google Scholar 

  26. Klein RJ, Biesheuvel PM, Yu BC, Meinhart CD, Lange FF (2003) Producing super-hydrophobic surfaces with nano-silica spheres. Z Metallkd 94:377–380

    Google Scholar 

  27. Koch K, Bhushan B, Jung YC, Barthlott W (2009b) Fabrication of artificial lotus leaves and significance of hierarchical structure for superhydrophobicity and low adhesion. Soft Matter 5:1386–1393

    Google Scholar 

  28. Krupenkin TN, Taylor JA, Wang EN, Kolodner P, Hodes M, Salamon TR (2007) Reversible wetting-dewetting transitions on delectrically tunable superhydrophobic nanostructured surfaces. Langmuir 23:9128–9133

    Google Scholar 

  29. Kuan CY, Hon MH, Chou JM, Leu IC (2009) Wetting characteristics on micro/nanostructured zinc oxide coatings. J Electrochem Soc 156:J32–J36

    Google Scholar 

  30. Lau KKS, Bico J, Teo KBK, Chhowalla M, Amaratunga GAJ, Milne WI, McKinley GH, Gleason KK (2003) Superhydrophobic carbon nanotube forests. Nano Lett 3:1701–1705

    Google Scholar 

  31. Lee H, Bhushan B (2012) Fabrication and characterization of hierarchical nanostructured smart adhesion surfaces. (unpublished)

    Google Scholar 

  32. Lee W, Jin M, Yoo W, Lee J (2004) Nanostructuring of a polymeric substrate with well-defined nanometer-scale topography and tailored surface wettability. Langmuir 20:7665–7669

    Google Scholar 

  33. Ma M, Hill RM (2006) Superhydrophobic surfaces. Curr Opin Colloid Interface Sci 11:193–202

    Google Scholar 

  34. Ma M, Hill RM, Lowery JL, Fridrikh SV, Rutledge GC (2005) Electrospun poly(styrene-block-dimethylsiloxane) block copolymer fibers exhibiting superhydrophobicity. Langmuir 21:5549–5554

    Google Scholar 

  35. Martin C, Rius G, Borrise X, Perez-Murano F (2005) Nanolithography on thin layers of PMMA using atomic force microscopy. Nanotechnology 16:1016–1022

    Google Scholar 

  36. Martines E, Seunarine K, Morgan H, Gadegaard N, Wilkinson CDW, Riehle MO (2005) Superhydrophobicity and superhydrophilicity of regular nanopatterns. Nano Lett 5:2097–2103

    Google Scholar 

  37. Ming W, Wu D, van Benthem R, de With G (2005) Superhydrophobic films from raspberry-like particles. Nano Lett 5:2298–2301

    Google Scholar 

  38. Nakajima A, Fujishima A, Hashimoto K, Watanabe T (1999) Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate. Adv Mater 11:1365–1368

    Google Scholar 

  39. Northen MT, Turner KL (2005) A batch fabricated biomimetic dry adhesive. Nanotechnology 16:1159–1166

    Google Scholar 

  40. Qian B, Shen Z (2005) Fabrication of superhydrophobic surfaces by dislocation-selective chemical etching on aluminum, copper, and zinc substrates. Langmuir 21:9007–9009

    Google Scholar 

  41. Shang HM, Wang Y, Limmer SJ, Chou TP, Takahashi K, Cao GZ (2005) Optically transparent superhydrophobic silica-based films. Thin Solid Films 472:37–43

    Google Scholar 

  42. Shi F, Song Y, Niu J, Xia X, Wang Z, Zhang X (2006) Facile method to fabricate a large-scale superhydrophobic surface by galvanic cell reaction. Chem Mater 18:1365–1368

    Google Scholar 

  43. Shibuichi S, Onda T, Satoh N, Tsujii K (1996) Super-water-repellent surfaces resulting from fractal structure. J Phys Chem 100:19512–19517

    Google Scholar 

  44. Shirtcliffe NJ, McHale G, Newton MI, Chabrol G, Perry CC (2004) Dual-scale roughness produces unusually water-repellent surfaces. Adv Mater 16:1929–1932

    Google Scholar 

  45. Shirtcliffe NJ, McHale G, Newton MI, Perry CC, Roach P (2005) Porous materials show superhydrophobic to superhydrophilic switching. Chem Commun 3135–3137

    Google Scholar 

  46. Shiu J, Kuo C, Chen P, Mou C (2004) Fabrication of tunable superhydrophobic surfaces by nanosphere lithography. Chem Mater 16:561–564

    Google Scholar 

  47. Sun M, Luo C, Xu L, Ji H, Ouyang Q, Yu D, Chen Y (2005) Artificial lotus leaf by nanocasting. Langmuir 21:8978–8981

    Google Scholar 

  48. Teshima K, Sugimura H, Inoue Y, Takai O, Takano A (2005) Transparent ultra water-repellent poly(ethylene terephthalate) substrates fabricated by oxygen plasma treatment and subsequent hydrophobic coating. Appl Surf Sci 244:619–622

    Google Scholar 

  49. Wang Y, Zhu Q, Zhang H (2006) Fabrication and magnetic properties of hierarchical porous hollow nickel microspheres. J Mater Chem 16:1212–1214

    Google Scholar 

  50. Wang S, Liu H, Liu D, Ma X, Fang X, Jiang L (2007) Enthalpy driven three state switching of a superhydrophilic/superhydrophobic surfaces. Angew Chem Int Ed 46:3915–3917

    Google Scholar 

  51. Wu X, Zheng L, Wu D (2005) Fabrication of superhydrophobic surfaces from microstructured ZnO-based surfaces via a wet-chemical route. Langmuir 21:2665–2667

    Google Scholar 

  52. Xu L, Chen W, Mulchandani A, Yan Y (2005) Reversible conversion of conducting polymer films from superhydrophobic to superhydrophilic. Angew Chem Int Ed 44:6009–6012

    Google Scholar 

  53. Yabu H, Shimomura M (2005) Single-step fabrication of transparent superhydrophobic porous polymer films. Chem Mater 17:5231–5234

    Google Scholar 

  54. Zhai L, Cebeci FC, Cohen RE, Rubner MF (2004) Stable superhydrophobic coatings from polyelectrolyte multilayers. Nano Lett 4:1349–1353

    Google Scholar 

  55. Zhang JL, Li JA, Han YC (2004a) Superhydrophobic PTFE surfaces by extension. Macromol Rapid Commun 25:1105–1108

    Google Scholar 

  56. Zhang X, Feng S, Yu X, Liu H, Fu Y, Wang Z, Jiang L, Li X (2004b) Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface. J Am Chem Soc 126:3064–3065

    Google Scholar 

  57. Zhao N, Xie QD, Weng LH, Wang SQ, Zhang XY, Xu J (2005) Superhydrophobic surface from vapor-induced phase separation of copolymer micellar solution. Macromolecules 38:8996–8999

    Google Scholar 

  58. Zhao Y, Tong T, Delzeit L, Kashani A, Meyyappan M, Majumdar A (2006) Interfacial energy and strength of multiwalled-carbon-nanotube-based dry adhesive. J Vac Sci Technol B 24:331–335

    Google Scholar 

  59. Zhao Y, Li M, Lu Q, Shi Z (2008) Superhydrophobic polyimide films with a hierarchical topography: combined replica molding and layer-by-layer assembly. Langmuir 24:12651–12657

    Google Scholar 

  60. Zhu L, Xiu Y, Xu J, Tamirisa PA, Hess DW, Wong C (2005) Superhydrophobicity on two-tier rough surfaces fabricated by controlled growth of aligned carbon nanotube arrays coated with fluorocarbon. Langmuir 21:11208–11212

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Bharat Bhushan .

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Bhushan, B. (2012). Fabrication Techniques Used for Structures with Superhydrophobicity, Self-Cleaning, Low Adhesion/Low Drag with Antifouling Properties. In: Biomimetics. Biological and Medical Physics, Biomedical Engineering. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-25408-6_5

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-25408-6_5

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-25407-9

  • Online ISBN: 978-3-642-25408-6

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics