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Palladium/Nickel-Cocatalyzed [2+2+2] Cycloaddition of 1,3-o-Carboryne with Alkynes

  • Zaozao Qiu
Chapter
Part of the Springer Theses book series (Springer Theses)

Abstract

1,2-o-Carboryne is a three-dimentional relative of benzyne (Chart 6.1). It can react with alkenes, dienes, and alkynes in [2+2], [2+4] cycloaddition and ene-reaction patterns similar to those of benzyne. This reactive species can be stabilized by transition metals, leading to the formation of metal-1,2-o-carboryne complexes.
Chart 6.1

Structures of benzyne and carborynes

Keywords

Catalyst Loading Cycloaddition Reaction Alkyl Chloride Insertion Product Unsaturated Molecule 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.Department of ChemistryThe Chinese University of Hong KongHong KongPeople’s Republic of China

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