Abstract
5 to 20 mol% hybrid inorganic organic porous silica (SO3H-Si) and polymer polytetrafluoroethane (PTFE) was mixed together to produce 10 to 300 μm thick membrane (S03H-Si-PTFE). Proton conductivity of resultant hybrid silica before and after mixing with PTFE determined in dry nitrogen and 100 % relative humidity (RH) using impedance spectroscopy. 20 % S03H-Si-PTFE shows proton conductivity up to 10–2 S/cm, similar to Nafion117 at room temperature at 100 % relative humidity. Membrane electrode assembly (MEA) was developed and used in direct methanol fuel cell technology. Power density of the MEA was 55 mW/cm2 at 40 °C. Materials were characterized using various instrumental techniques, such as ICP, XRD, TG-DTA, XPS, N2 sorption, 29Si and 13C MAS NMR, FT-IR, particle size analyzer and TDS.
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References
S. Hamoudi, S. Royer, and S. Kaliaguine; J. Micro. Meso. Mater. 71 (2004) 17.
S. Mikhailenko, D.D. Giscard, C. Danumah, and S. Laliaguine; J. Micro. Meso. Mater. 52 (2002) 29.
I. Diaz, C.M. Alvarez, F. Mohino, J.P. Pariente, and E. Sastre ; J. Micro. Meso. Mater. 44 (2001) 295.
Y. Mori, and T.J. Pinnavaia. Chem. Mater. 13 (2001) 2173.
D. Margolese, J.A. Melero, S.C. Christiansen, B.F. Chmelka, and G.D. Stucky; Chem. Mater. 12 (2000) 2448.
D. Isabel, M.A. Carlos, M. Federic, P.P. Joaquin and S. Enrique; J. Catal. 193 (2000) 283.
C.D. Wagner, W.M. Riggs, L.E. Devis, J.F. Moulder and G.E. Muilenberg; X-Ray photoelectron Spectroscopy. Perkin-Elmer, Eden Prairie, MN.), 1979.
M.H. Zong, Z.Q. Duan, W.Y. Lou, T.J. Smith and H. Wu; Green Chemistry. 9 (2007) 434.
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Mal, N., Hinokuma, K. (2012). Proton Conducting Membrane from Hybrid Inorganic Organic Porous Materials for Direct Methanol Fuel Cell. In: Khemani, L., Srivastava, M., Srivastava, S. (eds) Chemistry of Phytopotentials: Health, Energy and Environmental Perspectives. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23394-4_43
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DOI: https://doi.org/10.1007/978-3-642-23394-4_43
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