Abstract
Since the first experiments on femtosecond laser waveguide writing the question on which mechanisms are responsible for the refractive index change immediately arose. Several efforts have been made in that direction but no conclusive answer has been achieved yet. In fact, it has been observed that several factors determine the actual mechanism dominating the refractive index change, such as the irradiation conditions and the material composition. Understanding the materials change at the microscopic level is however important in terms of optimization of both the fs-laser processing conditions and the material composition. It also can provide more detailed insight into the physical mechanisms involved in the fs-laser modification process to enhance its capabilities. Confocal fluorescence and Raman spectroscopy are powerful tools to investigate the material structure. This chapter will review the results obtained by using these techniques to characterize fs-laser induced structural changes in glass. The focus will be on structures related to waveguides and refractive index changes, since this has been the most active research area of fs-laser processing in glass to date.
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G. Pacchioni, L. Skuja, D.L. Griscom (eds.), Defects inSiO 2 and Related Dielectrics: Science and Technology, NATO Science Series, Kluwer, Dordrecht, 2000)
L. Skuja, in Defects inSiO 2 and Related Dielectrics: Science and Technology, NATO Science Series II, vol. 2, ed. by G. Pacchioni, L. Skuja, D.L. Griscom. Optical Properties of Defects in Silica (Kluwer, Dordrecht, 2000), pp. 73–116
L. Skuja, T. Suzuki, K. Tanimura, Site-selective laser-spectroscopy studies of the intrinsic 1.9-eV luminescence center in glassy SiO2. Phys. Rev. B: Condens. Matter 52(21), 15208–15216 (1995)
L. Skuja, The origin of the intrinsic 1.9 eV luminescence band in glassy SiO2. J. Non-Cryst. Solids 179, 51–69 (1994)
L. Skuja, K. Tanimura, N. Itoh, Correlation between the radiation-induced intrinsic 4.8 eV optical absorption and 1.9 eV photoluminescence bands in glassy SiO2. J. Appl. Phys. 80(6), 3518–3525 (1996)
M. Cannas, M. Leone, Photoluminescence at 1.9 eV in synthetic wet silica. J. Non-Cryst. Solids 280(1–3), 183–187 (2001)
L. Skuja, M. Mizuguchi, H. Hosono, H. Kawazoe, The nature of the 4.8 eV optical absorption band induced by vacuum-ultraviolet irradiation of glassy SiO2. Nucl. Instrum. Meth. Phys. Res., Sect. B 166, 711–715 (2000)
K. Awazu, H. Kawazoe, O2 molecules dissolved in synthetic silica glasses and their photochemical reactions induced by arf excimer laser radiation. J. Appl. Phys. 68(7), 3584–3591 (1990)
L. Skuja, M. Hirano, H. Hosono, Oxygen-related intrinsic defects in glassy SiO2: interstitial ozone molecules. Phys. Rev. Lett. 84(2), 302–305 (2000)
M. Watanabe, S. Juodkazis, H.B. Sun, S. Matsuo, H. Misawa, Luminescence and defect formation by visible and near-infrared irradiation of vitreous silica. Phys. Rev. B 60(14), 9959–9964 (1999)
S. Juodkazis, M. Watanabe, H.B. Sun, S. Matsuo, J. Nishii, H. Misawa, Optically induced defects in vitreous silica. Appl. Surf. Sci. 154, 696–700 (2000)
H.B. Sun, S. Juodkazis, M. Watanabe, S. Matsuo, H. Misawa, J. Nishii, Generation and recombination of defects in vitreous silica induced by irradiation with a near-infrared femtosecond laser. J. Phys. Chem. B 104(15), 3450–3455 (2000)
M. Watanabe, S. Juodkazis, H.B. Sun, S. Matsuo, H. Misawa, M. Miwa, R. Kaneko, Transmission and photoluminescence images of three-dimensional memory in vitreous silica. Appl. Phys. Lett. 74(26), 3957–3959 (1999)
D.L. Griscom, E.J. Friebele, K.J. Long, J.W. Fleming, Fundamental defect centers in glass – electron-spin resonance and optical absorption studies of irradiated phosphorus-doped silica glass and optical fibers. J. Appl. Phys. 54(7), 3743–3762 (1983)
D. Ehrt, P. Ebeling, U. Natura, UV transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses. J. Non-Cryst. Solids 263(1–4), 240–250 (2000)
U. Natura, D. Ehrt, Modeling of excimer laser radiation induced defect generation in fluoride phosphate glasses. Nucl. Instrum. Meth. Phys. Res., Sect. B 174(1–2), 151–158 (2001)
U. Natura, D. Ehrt, Generation and healing behavior of radiation-induced optical absorption in fluoride phosphate glasses: the dependence on UV radiation sources and temperature. Nucl. Instrum. Meth. Phys. Res., Sect. B 174(1–2), 143–150 (2001)
A. Pasquarello, R. Car, Identification of Raman defect lines as signatures of ring structures in vitreous silica. Phys. Rev. Lett. 80(23), 5145–5147 (1998)
A.E. Geissberger, F.L. Galeener, Raman studies of vitreous SiO2 versus fictive temperature. Phys. Rev. B 28(6), 3266–3271 (1983)
J.C. Mikkelsen Jr., F.L. Galeener, Thermal equilibrium of Raman active defects in vitreous silica. J. Non-Cryst. Solids 37(1), 71–84 (1980)
F.L. Galeener, Raman and ESR studies of the thermal history of amorphous SiO2. J. Non-Cryst. Solids 71(1–3), 373–386 (1985)
F.L. Galeener, Planar rings in vitreous silica. J. Non-Cryst. Solids 49(1–3), 53–62 (1982)
R.K. Brow, Review: the structure of simple phosphate glasses. J. Non-Cryst. Solids 263 & 264, 1–28 (2000)
S.H. Morgan, R.H. Magruder III, E. Silberman, Raman spectra of rare-earth phosphate glasses. J. Am. Ceram. Soc. 70, 378–380 (1987)
D. Ilieva, B. Jivov, G. Bogachev, C. Petkov, I. Penkov, Y. Dimitriev, Infrared and Raman spectra of \(\mathrm{G{a}_{2}{O}_{3}}\mbox{ \textendash }\mathrm{{P}_{2}{O}_{5}}\) glasses. J. Non-Cryst. Solids 283, 195–202 (2001)
J.J. Hudgens, R.K. Brow, D.R. Tallant, S.W. Martin, Raman spectroscopy study of the structure of lithium and sodium ultraphosphate glasses. J. Non-Cryst. Solids 223, 21–31 (1998)
R. Lebullenger, L.A.O. Nunes, A.C. Hernandes, Properties of glasses from fluoride to phosphate composition. J. Non-Cryst. Solids 284, 55–60 (2001)
R.H. Webb, Confocal optical microscopy. Rep. Progr. Phys. 59(3), 427–471 (1996)
D.R. Sandison, W.W. Webb, Background rejection and signal-to-noise optimization in confocal and alternative fluorescence microscopes. Appl. Opt. 33(4), 603–615 (1994)
J.W. Chan, T.R. Huser, S.H. Risbud, D.M. Krol, Structural changes in fused silica after exposure to focused femtosecond laser pulses. Opt. Lett. 26(21), 1726–1728 (2001)
J.W. Chan, T.R. Huser, S.H. Risbud, D.M. Krol, Modification of the fused silica glass network associated with waveguide fabrication using femtosecond laser pulses. Appl. Phys. A 76, 367–372 (2003)
H. Nishikawa, E. Watanabe, D. Ito, Y. Sakurai, K. Nagasawa, Y. Ohki, Visible photoluminescence from Si clusters in irradiated amorphous SiO2. J. Appl. Phys. 80, 3513–3519 (1996)
S. Demos, M. Staggs, K. Minoshima, J. Fujimoto, Characterization of laser induced damage sites in optical components. Opt. Express 10, 1444–1450 (2002)
W.J. Reichman, J.W. Chan, C.W. Smelser, S.J. Mihailov, D.M. Krol, Spectroscopic characterization of different femtosecond laser modification regimes in fused silica. J. Opt. Soc. Am. B 24, 1627 (2007)
W.J. Reichman, D.M. Krol, C.W. Smelser, S.J. Mihailov, Fluorescence spectroscopy of fiber gratings written with an ultrafast infrared laser and a phase mask 2005 conference on lasers and electro-optics (CLEO). IEEE 2, 1106 (2005)
J.B. Bates, R.W. Hendricks, L.B. Shaffer, J. Chem. Phys. 61, 4163 (1974)
M. Okuno, B. Reynard, Y. Shimada, Y. Syono, C. Willaine, Phys. Chem. Minerals 26, 304 (1999)
S.G. Demos, L. Sheehan, M.R. Kozlowski, Proc. SPIE 3933, 316 (2000)
R. Bruckner, J. Non-Cryst. Solids 5, 123 (1970)
W.J. Reichman, D.M. Krol, L. Shah, F. Yoshino, A. Arai, S.M. Eaton, P.R. Herman, A spectroscopic comparison of femtosecond-laser-modified fused silica using kilohertz and megahertz laser systems. J. Appl. Phys. 99, 123112 (2006)
J.W. Chan, T.R. Huser, S.H. Risbud, J.S. Hayden, D.M. Krol, Waveguide fabrication in phosphate glasses using femtosecond laser pulses. Appl. Phys. Lett. 82, 2371 (2003)
J.W. Chan, T. Huser, J.S. Hayden, S.H. Risbud, D.M. Krol, Fluorescence spectroscopy of color centers generated in phosphate glasses after exposure to femtosecond laser pulses. J. Am. Ceram. Soc. 85(5), 1037–1040 (2002)
D.M. Krol, J.W. Chan, T.R. Huser, S.H. Risbud, J.S. Hayden, Fs-Laser Fabrication of Photonic Structures in Glass: the Role of Glass Composition. Fifth International Symposium on Laser Precision Microfabrication, vol. 5662, ed. by I. Miyamoto, H. Helvajian, K. Itoh, K.F. Kobayashi, A. Ostendorf, K. Sugioka. Proceedings of SPIE (2004), p. 30
V.R. Bhardwaj, E. Simova, P.B. Corkum, D.M. Rayner, C. Hnatovsky, R.S. Taylor, B. Schreder, M. Kluge, J. Zimmer, Femtosecond laser-induced refractive index modification in multicomponent glasses. J. Appl. Phys. 97, 083102–1 – 083102–9 (2005)
W. Reichman, C.A. Click, D.M. Krol, Femtosecond laser writing of waveguide structures in sodium calcium silicate glasses. Proc. SPIE 5714, 238 (2005)
M. Ams, G.D. Marshall, P. Dekker, M. Dubov, V.K. Mezentsev, I. Bennion, M.J. Withford, Investigation of ultrafast laser–photonic material interactions: challenges for directly written glass photonics. IEEE J. Sel. Top. Quant. Electron. 14, 1370 (2008)
S. Taccheo, G. Della Valle, R. Osellame, G. Cerullo, N. Chiodo, P. Laporta, O. Suelto, A. Killi, U. Morgner, M. Lederer, D.l. Kopf, Er:Yb-doped waveguide laser fabricated by femtosecond laser pulses. Opt. Lett. 29, 2626–2628 (2004)
R. Osellame, N. Chiodo, G. Della Valle, G. Cerillo, R. Ramponi, P. Laporta, A. Killi, U. Morgner, O. Suelto, Waveguide lasers in the C-band fabricated by laser inscription with a compact femtosecond oscillator. J. Sel. Top. Quant. Electron. 12, 277–285 (2006)
R. Osellame, N. Chiodo, G. Della Valle, S. Taccheo, R. Ramponi, G. Cerullo, A. Killi, U. Morgner, M. Lederer, D.l. Kopf, Optical waveguide writing with a diode-pumped femtosecond oscillator. Opt. Lett. 29, 1900–1902 (2004)
M. Ams, G.D. Marshall, D. Spence, M.J. Withford, Slit beam shaping method for femtosecond laser direct-write fabrication of symmetric waveguides in bulk glasses. Opt. Express 13, 5676–5681 (2005)
L.B. Fletcher, J.J. Witcher, W.J. Reichman, J. Bovatsek, A. Arai, D.M. Krol, Structural modifications in Er–Yb doped phosphate glass induced by femtosecond laser waveguide writing. Proc. of SPIE 6881, 688111–1 (2008)
L.B. Fletcher, J.J. Witcher, W.B. Reichman, A. Arai, J. Bovatsek, D.M. Krol, Changes to the network structure of Er–Yb doped phosphate glass induced by femtosecond laser pulses, submitted for publication
Acknowledgements
The author would like to thank James Chan, Luke Fletcher, Wilbur Reichman, and Jon Witcher for their contributions to this chapter. The author acknowledges financial support from the National Science Foundation under Grant No. DMR-0801786.
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Krol, D.M. (2012). Spectroscopic Characterization of Waveguides. In: Osellame, R., Cerullo, G., Ramponi, R. (eds) Femtosecond Laser Micromachining. Topics in Applied Physics, vol 123. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23366-1_3
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