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Cathodoluminescent Textures and Trace Elements in Hydrothermal Quartz

  • Brian RuskEmail author
Chapter
Part of the Springer Geology book series (SPRINGERGEOL)

Abstract

When viewed with scanning electron microscope-cathodoluminescence (SEM-CL), hydrothermal vein quartz displays textures that are unobservable using other techniques. These textures provide unique insights into the sequence of quartz precipitation and dissolution events during hydrothermal vein formation. Such textures relate specific quartz generations to specific mineralization events or fluid inclusion populations and may also relate quartz isotopic or trace element data to specific hydrothermal events. The most commonly observed CL textures in hydrothermal quartz include: (1) euhedral growth zones of oscillating CL intensity; (2) chalcedonic, coliform, and spheroidal textures; (3) mosaic textures; (4) CL-dark bands; (5) spider and cobweb texture; (6) rounded cores with overgrowths; (7) microbrecciation; (8) rounded or wavy concentric zonation; and (9) homogeneous (or slightly mottled) texture. These textures are present to varying degrees in quartz from different types of hydrothermal ore deposits depending on the pressure, temperature, or composition of hydrothermal fluids, and the rates and magnitude of fluctuations in these variables. In samples, where the geologic setting of quartz is not clear, CL textures distinguish among quartz derived from epithermal, porphyry-type, and orogenic Au deposits. CL textures result from defects in the quartz lattice, including those caused by trace element concentration variations. Like CL textures, trace element abundance and distribution result from variations in the physical and chemical conditions of quartz precipitation, followed by any subsequent solid-state changes in quartz chemistry. Here we show that CL textures, CL spectra, and trace element concentration vary systematically between quartz from various types of hydrothermal ore deposits. The information derived from quartz analysis can therefore be used to fingerprint the origin of quartz and make some inferences about the pressure, temperature, and fluid compositional changes that accompany hydrothermal quartz precipitation.

Keywords

Fluid Inclusion Trace Element Concentration Porphyry Copper Deposit Epithermal Deposit Hydrothermal Quartz 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

I would like to thank Mark Reed, David Krinsley, Alan Koenig, Heather Lowers, Yi Hu, and Kevin Blake for stimulating discussions about quartz and quartz analysis. I also thank Thomas Götte and Jens Götze for constructive reviews, which improved the content and presentation of the manuscript.

References

  1. Adams SF (1920) A microscopic study of vein quartz. Econ Geol 15:623–664CrossRefGoogle Scholar
  2. Allan MM, Yardley BWD (2007) Tracking meteoric water infiltration into a magmatic hydrothermal system: A cathodoluminescence, oxygen isotope, and trace element study of quartz from Mt. Leyshon. Australia Chem Geol 240:343–360. doi: 10.1016/j.chemgeo.2007.03.004 CrossRefGoogle Scholar
  3. Behr W, Thomas J, Hervig R (2011) Calibrating Ti concentrations in quartz for SIMS determinations using NIST silicate glasses and application to the TitaniQ geothermobarometer. Am Mineral 96:1100–1106CrossRefGoogle Scholar
  4. Bernet M, Bassett K (2005) Provenance analysis by single-quartz grain SEM-CL/optical microscopy. J Sed Res 75:492–500CrossRefGoogle Scholar
  5. Bignall G, Sekine K, Tsuchiya N (2004) Fluid–rock interaction processes in the Te Kopia geothermal field (New Zealand) revealed by SEM-CL imaging. Geothermics 33:615–635CrossRefGoogle Scholar
  6. Boggs S Jr, Krinsley D (2006) Application of cathodoluminescence imaging to study of sedimentary rocks. Cambridge University Press, New YorkGoogle Scholar
  7. Boggs S Jr, Kwon Y, Goles GG, Rusk BG, Krinsley D, Seyedolali A (2002) Is quartz cathodoluminescence color a reliable provenance tool? A quantitative examination. J Sed Res 72:408–415CrossRefGoogle Scholar
  8. Boiron M, Essarraj S, Sellier E, Cathelineau M, Lespinasse M, Poty B (1992) Identification of fluid inclusions in relation to their host microstructural domains in quartz by cathodoluminescence. Geochim et Cosmochim Acta 56:175–185CrossRefGoogle Scholar
  9. Breiter K, Müller A (2009) Evolution of rare-metal granitic magmas documented by quartz chemistry. Eur J Mineral 21:335–346CrossRefGoogle Scholar
  10. Chang Z, Meinert LD (2004) The magmatic hydrothermal-transition-evidence from quartz phenocryst textures and endoskarn abundance in Cu-Zn skarns at the Empire Mine, Idaho, USA. Chem Geol 210:149–171CrossRefGoogle Scholar
  11. Cherniak DJ (2010) Diffusion in quartz, melilite, silicate perovskite, and mullite. In: Zhang Y, Cherniak DJ (eds) Diffusion in minerals and melts, vol 72, p 735–756. Reviews in mineralogy and geochemistry, mineralogical society of america and the geochemical society, Chantilly, VirginiaGoogle Scholar
  12. Dong G, Morrison G, Jaireth S (1995) Quartz textures in epithermal veins, queensland-classification, origin, and implication. Econ Geol 90:1841–1856CrossRefGoogle Scholar
  13. Donovan J, Lowers H, Rusk B (2011) Improved electron probe microanalysis of trace elements in quartz. Am Mineral 96:274–282CrossRefGoogle Scholar
  14. Dowling K, Morrison G (1989) Application of quartz textures to the classification of gold deposits using north Queensland examples. Econ Geol Monogr 6:342–355Google Scholar
  15. Fischer M, Roeller K, Kuester M, Stoeckhert B, McConnell VS (2003) Open fissure mineralization at 2600 m depth in long valley exploratory well (California); insight into the history of the hydrothermal system. J Volc Geotherm Res 127:347–363CrossRefGoogle Scholar
  16. Flem B, Larsen RB, Grimstvedt A, Mansfield J (2002) In situ analysis of trace elements in quartz by using laser ablation inductively coupled plasma mass spectrometry. Chem Geol 182:237–247CrossRefGoogle Scholar
  17. Götte T, Richter DK (2003) Late palaeozoic and early Mesozoic hydrothermal events in the northern Rhenish Massif; results from fluid inclusion analyses and cathodoluminescence investigations. J Geochem Explor 78–79:531–535CrossRefGoogle Scholar
  18. Götte T, Pettke T, Ramseyer K, Koch-Müller M, Mullis J (2011) Cathodoluminescence properties and trace element signature of hydrothermal quartz: a fingerprint of growth dynamics. Am Min 96:802–813CrossRefGoogle Scholar
  19. Götze J (2009) Chemistry, textures and physical properties of quartz- geological interpretation and technical application. Min Mag 73:645–671CrossRefGoogle Scholar
  20. Götze J, Plötze M, Fuchs H, Habermann D (1999) Defect structure and luminescence behavior of agate–results of electron paramagnetic resonance (EPR) and cathodoluminescence (CL) studies. Min Mag 63:149–163CrossRefGoogle Scholar
  21. Götze J, Plötze M, Habermann D (2001) Origin, spectral characteristics and practical applications of the cathodoluminescence of quartz—a review. Min Pet 71:225–250CrossRefGoogle Scholar
  22. Götze J, Plötze M, Trautmann T (2005) Structure and luminescence characteristics of quartz from pegmatite’s. Am Min 90:13–21CrossRefGoogle Scholar
  23. Graupner T, Götze J, Kempe U, Wolf D (2000) CL for characterizing quartz and trapped fluid inclusions in mesothermal quartz veins: Muruntau Au ore deposit, Uzbekistan. Min Mag 64:1007–1016CrossRefGoogle Scholar
  24. Ioannou SE, Götze J, Weiershäuser L, Zubowski SM, Spooner ETC (2004) Cathodoluminescence characteristics of Archean VMS–related quartz: Noranda, Ben Nevis, and Matagami districs, Abitibi subprovince. Canada Geochem Geophys Geosys. doi: 10.1029/2003GC000613 Google Scholar
  25. Jacamon F, Larsen RB (2009) Trace element evolution of quartz in the charnockitic Kleivan granite, SW Norway: the Ge/Ti ratio of quartz as an index of igneous differentiation. Lithos 107:281–191CrossRefGoogle Scholar
  26. Jourdan A, Vennemann TW, Mullis J, Ramseyer K (2009) Oxygen isotope sector zoning in natural hydrothermal quartz. Min Mag 73:615–632CrossRefGoogle Scholar
  27. Kanaori Y (1986) A SEM cathodoluminescence study of quartz in mildly deformed granite from the region of Atotsugawa fault, central Japan. Tectonophys 131:133–146CrossRefGoogle Scholar
  28. King EM, Barrie CT, Valley JW (1997) Hydrothermal alteration of oxygen isotope ratios in quartz phenocrysts, Kidd Creek mine, Ontario: magmatic values are preserved in zircon. Geol 25:1079–1082CrossRefGoogle Scholar
  29. Landtwing M, Pettke T (2005) Relationships between SEM–cathodoluminescence response and trace element composition of hydrothermal vein quartz. Am Min 90:122–131CrossRefGoogle Scholar
  30. Landtwing M, Pettke T, Halter WE, Heinrich CA, Redmond PB, Einaudi MT, Kunze K (2005) Copper deposition during quartz dissolution by cooling magmatic hydrothermal fluids: the Bingham porphyry. Earth Planet Sci Lett 235:229–243CrossRefGoogle Scholar
  31. Larsen RB, Henderson I, Ihlen PM, Jacamon F (2004) Distribution and petrogenetic behaviour of trace elements in granitic quartz from South Norway. Contrib Mineral Petrol 147:615–628CrossRefGoogle Scholar
  32. Larsen RB, Jacamon F, Krontz A (2009) Trace element chemistry and textures of quartz during the magmatic-hydrothermal transition of Oslo Rift granites. Min Mag 73:691–707CrossRefGoogle Scholar
  33. Leach DL, Marsh E, Emsbo P, Rombach CS, Kelley KD, Anthony M (2005) Nature of Hydrothermal Fluids at the Shale-Hosted Red Dog Zn-Pb-Ag Deposits, Brooks Range, Alaska. Econ Geol 99:1449–1480Google Scholar
  34. Lehmann K, Berger A, Götte T, Ramseyer K, Wiedenbeck M (2009) Growth related zonations in authigenic and hydrothermal quartz characterized by SIMS-, EPMA-, SEM-CL- and SEM-CC-imaging. Min Mag 73:633–643CrossRefGoogle Scholar
  35. Lehmann K, Pettke T, Ramseyer K (2011) Significance of trace elements in syntaxial quartz cement, Haushi group sandstones, Sultanate of Oman. Chem Geol 280:47–57Google Scholar
  36. Lowenstern JB, Sinclair WD (1996) Exsolved magmatic fluid and its role in the formation of comb–layered quartz at the Cretaceous Logtung W-Mo deposit, Yukon Territory, Canada. Trans Roy Soc Edinburgh Earth Sci 87:291–303CrossRefGoogle Scholar
  37. Lubben J (2004) Silicification across the Betze-Post carlin-type Au deposit; clues to ore fluid properties and sources, northern Carlin Trend, Nevada. Unpublished masters thesis, University of Nevada, Las VegasGoogle Scholar
  38. Machel HG, Burton EA (1991) Factors governing cathodoluminescence in calcite and dolomite, and their implications for studies of carbonate diagenesis. In: Barker CE, Kopp OC (eds) Luminescence microscopy and spectroscopy: qualitative and quantitative applications: SEPM short course, Tulsa, 25:37–57Google Scholar
  39. Marshall DJ (1988) Cathodoluminescence of geological materials. Unwin Hyman, BostonGoogle Scholar
  40. Miyoshi N, Yamaguchi Y, Makino K (2005) Successive zoning of Al and H in hydrothermal vein quartz. Am Mineral 90:310–315CrossRefGoogle Scholar
  41. Monecke T, Kempe U, Götze J (2002) Genetic significance of the trace element content in metamorphic and hydrothermal quartz: A reconnaissance study. Earth Planet Sci Let 202:709–724CrossRefGoogle Scholar
  42. Müller A, Koch-Müller M (2009) Hydrogen speciation and trace element contents of igneous, hydrothermal and metamorphic quartz from Norway. Min Mag 73:569–583CrossRefGoogle Scholar
  43. Müller A, Wanvik J (2012) Petrological and chemical characterisation of high-purity quartz deposits with examples from Norway, This volumeGoogle Scholar
  44. Müller A, Lennox P, Trzebski R (2002) Cathodoluminescence and micro-structural evidence for crystallization and deformation processes of granites in the Eastern Lachlan Fold Belt (SE Australia). Cont Min Pet 143:510–524Google Scholar
  45. Müller A, Wiedenbeck M, Van den Kerkhof AM, Kronz A, Simon K (2003) Trace elements in quartz: a combined electron microprobe, secondary ion mass spectrometry, laser–ablation ICPMS, and cathodoluminescence study. Eur J Min 15:747–763CrossRefGoogle Scholar
  46. Müller A, Breiter K, Seltman R, Pecskay Z (2005) Quartz and feldspar zoning in the Eastern Erzgebirge pluton (Germany, Czech Republic): Evidence of multiple magma mixing. Lithos 80:201–207CrossRefGoogle Scholar
  47. Müller A, Herrington R, Armstrong R, Seltman R, Kirwin D, Stenina N, Kronz A (2010) Trace elements and cathodoluminescence of quartz in stockwork veins of Mongolian porphyry-style deposits. Mineralium Deposita 45:707–727CrossRefGoogle Scholar
  48. Mullis J, Dubessy J, Poty B, O’Neil J (1994) Fluid regimes during late stages of a continental collision: Physical, chemical, and stable isotope measurements of fluid inclusions in fissure quartz from a geotraverse through the Central Alps, Switzerland. Geochim Cosmochim Acta 58:2239–2267CrossRefGoogle Scholar
  49. Pagel M, Barbin V, Blanc P, Ohnenstetter D (eds) (2000) Cathodoluminescence in geoscience. Springer, Berlin, Heidelberg, New York, p 514Google Scholar
  50. Penniston-Dorland SC (2001) Illumination of vein quartz textures in a porphyry copper ore deposit using scanned cathodoluminescence: grasberg igneous complex, Irian Jaya, Indonesia. Am Min 86:652–666Google Scholar
  51. Peppard BT, Steele IM, Davis AM, Wallace PJ, Anderson AT (2001) Zoned quartz phenocrysts from the rhyolitic Bishop Tuff. Am Min 81:1034–1052Google Scholar
  52. Perny B, Eberhardt P, Ramseyer K, Mullis J, Pankrath R (1992) Microdistribution of Al, Li, and Na in alpha quartz: possible causes and correlation with short-lived cathodoluminescence. Am Min 77:534–544Google Scholar
  53. Ramseyer K, Mullis J (2000) Geologic application of cathodoluminescence of silicates. In: Pagel M, Barbin B, Blanc C, Ohnstetter (eds) Cathodoluminescence in geosciences. Springer, Berlin, pp 177–191Google Scholar
  54. Ramseyer K, Baumann J, Matter A, Mullis J (1988) Cathodoluminescence colours of alpha-quartz. Mineral Mag 52:669–677CrossRefGoogle Scholar
  55. Redmond PB, Einaudi MT, Inan EE, Landtwing MR, Heinrich CA (2004) Copper deposition by fluid cooling in intrusion–centered systems: new insights from the Bingham porphyry ore deposit, Utah. Geol 32:217–220CrossRefGoogle Scholar
  56. Richter DK, Götte T, Götze J, Neuser RD (2003) Progress in application of cathodoluminescence in sedimentary petrology. Min Pet 79:127–166CrossRefGoogle Scholar
  57. Rusk B (2009) Insights into hydrothermal processes from cathodoluminescence and trace elements in quartz. In: Williams PJ, Rusk B, Oliver N (eds) Smart sciences for exploration and mining, proceedings of the 10th Biennial SGA meeting. Townsville, pp 749–751. https://www.e-sga.org/index.php?id=231&tx_commerce_pi1[showUid]=1650&tx_commerce_pi1[catUid]=43&cHash=3feeb527d1
  58. Rusk BG, Reed MH (2002) Scanning electron microscope–cathodoluminescence of quartz reveals complex growth histories in veins from the Butte porphyry copper deposit, Montana. Geol 30:727–730CrossRefGoogle Scholar
  59. Rusk B, Reed M, Dilles J, Kent A (2006) Intensity of quartz cathodoluminescence and trace element content of quartz from the porphyry copper deposit in Butte, Montana. Am Min 91:1300–1312Google Scholar
  60. Rusk B, Lowers H, Reed M (2008) Trace elements in hydrothermal quartz; relationships to cathodoluminescent textures and insights into hydrothermal processes. Geol 36:547–550Google Scholar
  61. Rusk B, Koenig A, Lowers H (2011) Visualizing trace element distribution in quartz using cathodoluminescence, electron microprobe, and laser ablation inductively coupled plasma mass spectrometry. Am Mineral 96:703–708CrossRefGoogle Scholar
  62. Sekine K (2003) Development of fracture and fluid migration in granite during uplift and emplacement. Dissertation, Tohoku University, p 256Google Scholar
  63. Seyedolali A, Krinsley DH, Boggs S, O’Hara PF, Dypvik H, Goles GG (1997) Provenance interpretation of quartz by scanning electron microscope-cathodoluminescence fabric analysis. Geol 25:783–786CrossRefGoogle Scholar
  64. Sippel RF (1968) Sandstone petrology, evidence from luminescence petrography. J Sed Pet 38: 530–554Google Scholar
  65. Smith JV, Stenstrom RC (1965) Electron-excited luminescence as a petrological tool. J Geol 73:627–635CrossRefGoogle Scholar
  66. Spear FS, Wark DA (2009) Cathodoluminescence imaging and titanium thermometry in metamorphic quartz. J Metamorph Geol 27:187–205CrossRefGoogle Scholar
  67. Sprunt ES, Dengler LA, Sloan D (1978) Effects of metamorphism on quartz cathodoluminescence. Geol 6:305–308CrossRefGoogle Scholar
  68. Spurr JE (1926) Successive banding around rock fragments in veins. Econ Geol 21:519–537CrossRefGoogle Scholar
  69. Stenina NG (2004) Water-related defects in quartz. Bullet Geosci 79:251–268Google Scholar
  70. Stevens-Kalceff M (2009) Cathodoluminescence microcharacterization of point defects in a-quartz. Min Mag 73:585–605CrossRefGoogle Scholar
  71. Stevens-Kalceff MA (2012) Cathodoluminescence microanalysis of the defect microstructures of bulk and nanoscale ultrapure silicon dioxide polymorphs for device applications. (this volume)Google Scholar
  72. Stevens-Kalceff MA, Phillips MR (1995) Cathodoluminescence microcharacterization of the defect structure of quartz. Phys Rev B 52:3122–3134CrossRefGoogle Scholar
  73. Stevens-Kalceff MA, Phillips MR, Moon AR, Kalceff W (2000) Cathodoluminescence microcharacterization of silicon dioxide polymorphs. In: Pagel M, Barbin B, Blanc C, Ohnstetter D (eds) Cathodoluminescence in geosciences, Springer, Berlin, pp 193–224Google Scholar
  74. Tarashchan AN, Waychunas G (1995) Interpretation of luminescence spectra in terms of band theory and crystal field theory. Sensitization and quenching, photoluminescence, radioluminescence, and cathodoluminescence. In: Marfunmin AS (ed) Advanced mineralogy 2, Methods and instrumentations: results and recent developments. Springer, Berlin, pp 124–135Google Scholar
  75. Thomas SM, Koch-Müller M, Reichart P, Rhede D, Thomas R, Wirth R (2009) IR calibrations for water determination in olivine, r-GeO2 and SiO2 polymorphs. Phys Chem Miner 36:489–509Google Scholar
  76. Thomas JB, Watson EB, Spear FS, Shemella PT, Nayak SK, Lanzirotti A (2010) TitaniQ under pressure: the effect of pressure and temperature on the solubility of Ti in quartz. Contrib Mineral Petrol 160:743–759CrossRefGoogle Scholar
  77. Valley JW, Graham CM (1996) Ion microprobe analysis of oxygen isotope ratios in quartz from Skye granite: healed micro–cracks, fluid flow, and hydrothermal exchange. Contrib Min Pet 124:225–234Google Scholar
  78. Vearncombe JR (1993) Quartz vein morphology and implications for formation depth and classification of Archaean gold-vein deposits. Ore Geol Rev 8:407–424CrossRefGoogle Scholar
  79. Walker G (2000) Physical parameters for the identification of luminescence centres in minerals. In: Pagel M, Barbin B, Blanc C, Ohnstetter D (eds) Cathodoluminescence in geosciences. Springer, Berlin, pp 23–40Google Scholar
  80. Wark DA, Spear FS (2005) Titanium in quartz: cathodoluminescence and thermometry. Geochim Cosmochim Acta Suppl 69:A592Google Scholar
  81. Wark DA, Watson BE (2006) TitaniQ: a titanium in quartz geothermometer. Contrib Min Pet 152:743–754. doi: 10.1007/s00410-006-0132-1 CrossRefGoogle Scholar
  82. Wark DA, Hildreth W, Spear FS, Cherniak DJ, Watson EB (2007) Pre-eruption recharge of the Bishop magma system. Geol 35:235–238CrossRefGoogle Scholar
  83. Wilkinson JJ, Johnston JD (1996) Pressure fluctuations, phase separation, and gold precipitation during seismic fracture propagation. Geol 24:395–398CrossRefGoogle Scholar
  84. Wilkinson JJ, Boyce AJ, Earls G, Fallick AE (1999) Gold remobilization by low–temperature brines: evidence from the Curraghinalt gold deposit, northern Ireland. Econ Geol 94:289–296CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.Economic Geology Research UnitSchool of Earth and Environmental Sciences, James Cook UniversityTownsvilleAustralia

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