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Trace Element Characteristics, Luminescence Properties and Real Structure of Quartz

  • Thomas Götte
  • Karl Ramseyer
Chapter
Part of the Springer Geology book series (SPRINGERGEOL)

Abstract

Recent results on the cathodoluminescence (CL) and the trace element composition of quartz are the starting point to review the properties of quartz from different origin. CL-spectroscopy revealed five emission bands to be important in quartz additionally to one at approx. 340 nm which has been reported in the literature: the first one in the near-UV at 395 nm, the second in the blue range of the spectrum at 450 nm, the third at 505 nm (greenish blue), the forth at 570 nm (greenish yellow) and the last one in the red range of the spectrum at 650 nm. The bands at 395 and 505 nm are characterised by a strong decrease of intensities during irradiation while the band at 650 nm increases with increasing dose. This phenomenon is very common in quartz grown from aqueous solutions while magmatic quartz may show more stable luminescence emission. Trace element analyses display also differences in the composition between these two groups of quartz. Aluminium, Li and H have been found to be most important in authigenic, hydrothermal and metamorphic quartz but magmatic quartz is generally enriched in Ti. Germanium, Fe, B and Na is present at low levels in all quartz samples. A strong linear correlation between Al and Li indicates combined incorporation in [AlO4|Li+]-defects. A high unstable intensity at 395 nm has been observed especially in Al-rich quartz. In these samples, the luminescence commonly attenuates completely. However, different quartz samples show different correlation with Al. This result puts doubt on the interpretation that Al-related centres are the only reason for the near-UV emission. The emission band at 505 nm which also shows unstable behaviour in pegmatitic and hydrothermal quartz might also be related to trace elements, but the correlation is not well established. The increasing emission at 650 nm might be influenced by the water content of quartz, but the indicators for this interpretation are even more ambiguous than in the case of the 395 nm-band because SiOH-centres are commonly only present at very low levels. The emission bands at 450 nm, 505 nm (at least partly) and 570 nm are probably of intrinsic origin.

Keywords

Emission Band Trace Element Composition Luminescence Centre Quartz Sample Luminescence Emission 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

We wish to thank Thomas Pettke (Bern) and Jan Meijer (Bochum) for technical support with the LA-ICP-MS and the proton microprobe, respectively. Frank Preusser (Bern) kindly provided crystalline quartz samples from New Zealand. We gratefully acknowledge the financial support from the German Research foundation (DFG, Go 1089/3-1). We also thank an anonymous reviewer, Jens Götze (Freiberg), and Robert Möckel (Freiberg) for their suggestions on an earlier draft of the manuscript.

References

  1. Alonso PJ, Halliburton LE, Kohnke EE, Bossoli RB (1983) X-ray-induced luminescence in crystalline SiO2. J Appl Phys 54(9):5369–5375CrossRefGoogle Scholar
  2. Bambauer HU (1961) Spurenelemente und γ-Farbzentren in Quarzen aus Zerrklüften der Schweizer Alpen. Schweiz Miner Petrogr Mitt 41:335–369Google Scholar
  3. Bernstein LR (1985) Germanium geochemistry and mineralogy. Geochim Cosmochim Acta 49:2409–2422CrossRefGoogle Scholar
  4. Botis S, Nokhirn SM, Pan A, Xu Y, Bonli Th, Sopuck V (2005) Natural radiation-induced damage in quartz. I. correlations between cathodoluminescence colors and paramagnetic defects. Can Mineral 43:1565–1580CrossRefGoogle Scholar
  5. Demars C, Pagel M, Deloule E, Blanc P (1996) Cathodoluminescence of quartz from sandstones: Interpretation of the UV range by determination of trace element distributions and fluid-inclusion P-T-X properties in authigenic quartz. Am Mineral 81(7–8):891–901Google Scholar
  6. Dersch O (2001) Wasseraufnahme von Quarz: Grundlage für eine Methode zur Datierung archäologischer Quarzartefakte. Ph.D Thesis Goethe-University Frankfurt, 250 S, Frankfurt am Main, GermanyGoogle Scholar
  7. Glinka YD, Lin S-H, Chen Y-T (1999) The photoluminescence from hydrogen-related species in composites of SiO2 nanoparticles. Appl Phys Lett 75(6):778–780CrossRefGoogle Scholar
  8. Glinka YD, Lin S-H, Hwang LP, Chen YT (2000) Photoluminescence from mesoporous silica: similarity of properties to porous silicon. Appl Phys Lett 77(24):3968–3970CrossRefGoogle Scholar
  9. Gorton NT, Walker G, Burley SD (1997) Experimental analysis of the composite blue cathodoluminescence emission in quartz. J Lumin 72–4:669–671CrossRefGoogle Scholar
  10. Götte T (2004) Petrographische und geochemische Untersuchungen zu den postvariszischen Mineralisationen im devonischen Massenkalk des nordwestlichen rechtsrheinischen Schiefergebirges unter besonderer Berücksichtigung der Kathodolumineszenz, Ph.D Thesis, University of Bochum, Bochum, Germany, pp 186Google Scholar
  11. Götte Th, Richter DK (2003) Late Palaeozoic and Early Mesozoic hydrothermal events in the northern Rhenish Massif: results from fluid inclusion analyses and cathodoluminescence investigations. J Geochem Explor 78–79:531–535CrossRefGoogle Scholar
  12. Götte Th, Richter DK (2006) Cathodoluminescence characterization of quartz particles in mature arenites. Sedimentology 53(6):1347–1359CrossRefGoogle Scholar
  13. Götte Th, Pettke Th, Ramseyer K, Koch-Müller M, Mullis J (2011) Cathodoluminescence properties and trace element signature of hydrothermal quartz: A fingerprint of growth dynamics. Am Mineral 96:802–813CrossRefGoogle Scholar
  14. Götze J (2001) Cathodoluminescence microscopy and spectroscopy in applied mineralogy. Freiberger Forschungshefte C 485:1–128Google Scholar
  15. Götze J (2009) Chemistry, textures and physical properties of quartz—geological interpretation and technical application. Mineral Mag 73:645–671CrossRefGoogle Scholar
  16. Götze J, Plötze M, Fuchs H, Habermann D (1999) Defect structure and luminescence behaviour of agate—results of electron paramagnetic resonance (EPR) and cathodoluminescence (CL) studies. Mineral Mag 63(2):149–163CrossRefGoogle Scholar
  17. Götze J, Plötze M, Graupner T, Hallbauer DK, Bray CJ (2004) Trace element incorporation into quartz: a combined study by ICP-MS, electron spin resonance, cathodoluminescence, capillary ion analysis, and gas chromatography. Geochim Cosmochim Acta 68:3741–3759CrossRefGoogle Scholar
  18. Götze J, Plötze M, Trautmann T (2005) Structure and luminescence characteristics of quartz from pegmatites. Am Mineral 90:13–21CrossRefGoogle Scholar
  19. Ismail-Beigi S, Louie SG (2005) Self-trapped excitons in silicon dioxide: Mechanism and properties. Phys Rev Lett 95:156401-1-4Google Scholar
  20. Itoh C, Tanimura K, Itoh N (1988) Optical studies of self-trapped excitons in SiO2. J Phys C-Solid State Phys 21(26):4693–4702CrossRefGoogle Scholar
  21. Kempe U, Götze J, Dandar S, Habermann D (1999) Magmatic and metasomatic processes during formation of the Nb-Zr-REE deposits Khaldzan Buregte and Tsakhir (Mongolian Altai): indications from a combined CL-SEM study. Mineral Mag 63(2):165–177CrossRefGoogle Scholar
  22. King GE, Finch AA, Robinson RAJ, Hole DE (2010) The problem of dating quartz 1: spectroscopic ionoluminescence of dose dependence. Radiat meas 46:1–9CrossRefGoogle Scholar
  23. Komuro K, Horikawa Y, Toyoda S (2002) Development of radiation damage halos in low-quartz: cathodoluminescence measurement after He+ ion implantation. Mineral Petrol 76:261–266CrossRefGoogle Scholar
  24. Krickl R, Nasdala L, Götze J, Grambole D, Wirth R (2008) Alpha-irradiation effects in SiO2. Eur J Mineral 20:517–522CrossRefGoogle Scholar
  25. Kuzuu N, Matsumoto Y, Murahara M (1993) Characteristics of ArF-eximer-laser-induced 1.9 eV emission bands in type-III and soot-remelted silicas. Phys Rev B 48(19):6952–6956Google Scholar
  26. Landtwing MR, Pettke T (2005) Relationships between SEM-cathodoluminescence response and trace-element composition of hydrothermal vein quartz. Am Mineral 90(1):122–131CrossRefGoogle Scholar
  27. Larsen RB, Henderson I, Ihlen PM, Jacamon F (2004) Distribution and petrogenetic behaviour of trace elements in granitic pegmatite quartz from South Norway. Contrib Mineral Petrol 147:615–628CrossRefGoogle Scholar
  28. Larsen RB, Jacamon F, Sørensen B (2008) Petrogenetic significance of trace elements in igneous quartz. 33rd International Geological Congress, Oslo, 2008Google Scholar
  29. Larsen RB, Jacamon F, Kronz A (2009) Trace element chemistry and textures of quartz during the magmatic hydrothermal transition of Oslo Rift granites. Mineral Mag 73(4):691–707CrossRefGoogle Scholar
  30. Lehmann K, Pettke T, Ramseyer K (2011) Significance of trace elements in syntaxial quartz cement, Haushi Group sandstones, Sultanate of Oman. Chem Geol 280:47–57CrossRefGoogle Scholar
  31. Luff BJ, Townsend PD (1990) Cathodoluminescence of synthetic quartz. J Phys-Condens Matter 2(40):8089–8097CrossRefGoogle Scholar
  32. Meijer J, Stephan A, Adamczewski J, Bukow HH, Rolfs C, Pickart T, Bruhn F, Veizer J (1994) PIXE microprobe for geoscience applications. Nucl Instrum Methods B89:229–232Google Scholar
  33. McKeever SWS, Chen CY, Halliburton LE (1985) Point-defects and the predose effect in natural quartz. Nucl Tracks Radiat Meas 10(4–6):489–495Google Scholar
  34. Monecke T, Kempe U, Götze J (2002) Genetic significance of the trace element content in metamorphic and hydrothermal quartz: a reconnaissance study. Earth Planet Sci Lett 202:709–724CrossRefGoogle Scholar
  35. Müller A (2000) Cathodoluminescence of defect structures in quartz with applications to the study of granitic rocks. Ph.D Thesis, University Göttingen, Göttingen, p 229Google Scholar
  36. Müller A, Koch-Müller M (2009) Hydrogen speciation and trace element contents of igneous, hydrothermal and metamorphic quartz from Norway. Mineral Mag 73(4):569–583CrossRefGoogle Scholar
  37. Neuser RD, Bruhn F, Götze J, Habermann D, Richter DK (1996) Kathodolumineszenz: methodik und anwendung. Zentralblatt für Geologie und Paläontologie, Teil I 1:287–306 1995Google Scholar
  38. Perny B, Eberhardt P, Ramseyer K, Mullis J, Pankrath R (1992) Microdistribution of Al, Li, and Na in α-quartz—possible causes and correlation with short-lived cathodoluminescence. Am Mineral 77(5–6):534–544Google Scholar
  39. Preusser F, Ramseyer K, Schlüchter Ch (2006) Characterisation of low OSL intensity quartz from the New Zealand Alps. Radiat Meas 41:871–877CrossRefGoogle Scholar
  40. Ramseyer K, Baumann J, Matter A, Mullis J (1988) Cathodoluminescence colors of quartz. Mineral Mag 52(368):669–677CrossRefGoogle Scholar
  41. Ramseyer K, Mullis J (1990) Factors influencing short-lived blue cathodoluminescence of α -quartz. Am Mineral 75(7–8):791–800Google Scholar
  42. Rosa AL, El-Barbary AA, Heggi MI, Briddon PR (2005) Structural and thermodynamic properties of water related defects in quartz. Phys Chem Mineral 32:323–331CrossRefGoogle Scholar
  43. Rossman GR (1994) Colored varieties of the Silica minerals. In: Heaney PJ, Prewitt CT, Gibbs GV (eds) Silica—physical behaviour, Geochemistry and materials applications. Reviews in Mineralogy, vol 29, pp 433–367Google Scholar
  44. Schilles T, Poolton NRJ, Bulur R, Bøtter-Jensen L, Murray AS, Smith GM, Riedi PC, Wagner GA (2001) A multi-spectroscopic study of luminescence sensitivity changes in natural quartz induced by high-temperature annealing. J Phys D-Appl Phys 34(5):722–731CrossRefGoogle Scholar
  45. Skuja L (1998) Optically active oxygen-deficiency related centers in amorphous silicon dioxide. J Non-Cryst Solids 239:16–48CrossRefGoogle Scholar
  46. Skuja L, Naber A (1997) Laser-induced luminescence in glassy SiO2 and neutron-irradiated alpha-quartz: three types of non-bridging oxygen hole centres. Mater Sci Forum 239–241:25–28CrossRefGoogle Scholar
  47. Stenina NG (2004) Water related defects in quartz. Bulletin Geosci 79:251–268Google Scholar
  48. Stevens-Kalceff MAS, Phillips MR (1995) Cathodoluminescence microcharacterization of the defect structure of quartz. Phys Rev B 52(5):3122–3134CrossRefGoogle Scholar
  49. Stevens-Kalceff MAS (2009) Cathodoluminescence microcharacterization of point defects in quartz. Mineral Mag 73:585–605CrossRefGoogle Scholar
  50. Tanimura K, Halliburton LE (1986) Polarization of the x-ray-induced blue luminescence in quartz. Phys Rev B 34(4):2933–2935CrossRefGoogle Scholar
  51. Wark DA, Watson EB (2006) TitaniQ: a titanium-in-quartz geothermometer. Contrib Mineral Petrol 152:743–754CrossRefGoogle Scholar
  52. Woda C, Schilles T, Rieser U, Mangini A, Wagner GA (2002) Point defects and the blue emission in fired quartz at high dose: a comparative luminescence and EPR study. Radiat Prot Dosim 100(1–4):261–264CrossRefGoogle Scholar
  53. Xu Y, Ching WY (1991) Electronic and optical properties for all polymorphic forms of silicon dioxide. Phys Rev B 44:11048–11059CrossRefGoogle Scholar
  54. Yang XH, McKeever SWS (1990) Point-defects an the predose effect in quartz. Radiat Prot Dosim 33(1–4):27–30Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  • Thomas Götte
    • 1
  • Karl Ramseyer
    • 2
  1. 1.Institute of Geosciences, Goethe-University FrankfurtFrankfurtGermany
  2. 2.Institute of Geological Sciences, University BernBernSwitzerland

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