Abstract
An approach to further increase the sensitivity of LIBS for the determination of traces is the combination of LIBS and laser-induced fluorescence (LIF, also called laser-excited atomic fluorescence spectrometry, LEAFS) [12.1]. Limit of detections for, e.g., heavy metals in soil according to regulatory demands are required to be significantly below 1 μg∕g, which is still difficult to achieve with LIBS only.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
K. Niemax, W. Sdorra, Optical emission spectrometry and laser-induced fluorescence of laser produced plasma plumes. Appl. Optics 29, 5000–5006 (1990)
R. Measures, H. Kwong, TABLASER: trace (element) analyzer based on laser ablation and selectively excited radiation. Appl. Optics 18, 281–286 (1979)
H. Kwong, R. Measures, Trace element laser microanalyzer with freedom from chemical matrix effect. Anal. Chem. 51, 428–432 (1979)
I. Gornushkin, S. Baker, B. Smith, J. Winefordner, Determination of lead in metallic reference materials by laser ablation combined with laser excited atomic fluorescence. Spectrochim. Acta 52B, 1653–1662 (1997)
W. Sdorra, A. Quentmeier, K. Niemax, Basic investigations for laser microanalysis: II. Laser-induced fluorescence in laser-produced sample plumes. Microchim. Acta II 98, 201–218 (1989)
W. Sdorra, K. Niemax, Temporal and spatial distribution of analyte atoms and ions in microplasmas produced by laser ablation of solid samples. Spectrochim. Acta 45B, 917–926 (1990)
R. Neuhauser, U. Panne, R. Niessner, G. Petrucci, P. Cavalli, N. Omenetto, On-line and in situ detection of lead in ultrafine aerosols by laser-excited atomic fluorescence spectroscopy. Sensor Actuator B 39, 344–348 (1997)
I. Gornushkin, J. Kim, B. Smith, S. Baker, J. Winefordner, Determination of cobalt in soil, steel and graphite using excited-state laser fluorescence induced in a laser spark. Appl. Spectrosc. 51, 1055–1059 (1997)
F. Hilbk-Kortenbruck, R. Noll, P. Wintjens, H. Falk, C. Becker, Analysis of heavy metals in soils using laser-induced breakdown spectrometry combined with laser-induced fluorescence. Spectrochim. Acta B 56, 933–945 (2001)
V. Sturm, L. Peter, R. Noll, Steel analysis with laser-induced breakdown spectrometry in the vacuum ultraviolet. Appl. Spectrosc. 54, 1275–1278 (2000)
H. Didra, M. Baumann, Cadmium (51P1 → 53P J ) excitation transfer and 53P J intramultiplett relaxation by collisions with molecular gases. Z. Phys. D 37, 29–37 (1996)
B. Smith, M. Glick, K. Spears, J. Winefordner, A comprehensive table of atomic fluorescence detection limits and experimental conditions. Appl. Spectrosc. 43, 376–414 (1989)
M. Bolshov, S. Rudnev, B. Hütsch, Determination of trace amounts of cadmium by laser excited atomic fluorescence spectrometry. J. Anal. At. Spectrom. 7, 1–6 (1992)
A. Zaidel, V. Prokofev, S. Raiskii, V. Slavnyi, E. Shreider, Tables of Spectral Lines (IFI–Plenum, New York, 1970)
N. Omenetto, P. Cavalli, M. Broglia, P. Qi, G. Rossi, Laser-induced single-resonance and double-resonance atomic fluorescence spectrometry in a graphite tube atomizer. J. Anal. At. Spectrom. 3, 231–235 (1988)
F. Hilbk-Kortenbruck, C. Rieck, R. Noll, Multi-elemental analysis of heavy metals in soil samples using laser-based analytical techniques, Abstracts of the lecture groups “Environmental Technology and Fundamentals of Laser-aided In-situ Soil Analysis”, Int. Meeting on Chem. Eng., Environmental Protection and Biotechnology, ACHEMA 2000, Conf. Proc. 2000, DECHEMA e.V., Frankfurt a. M. 386–388 (2000)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2012 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Noll, R. (2012). Combination of LIBS and LIF. In: Laser-Induced Breakdown Spectroscopy. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20668-9_12
Download citation
DOI: https://doi.org/10.1007/978-3-642-20668-9_12
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-20667-2
Online ISBN: 978-3-642-20668-9
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)