Abstract
In this chapter, the design, fabrication and performance of thermo-responsive adsorption/desorption membranes for affinity separation are introduced. Firstly, the design of fabrication of thermo-responsive affinity membranes with nanostructured pores and grafted PNIPAM surface layer for hydrophobic adsorption are described. The membrane shows efficient “adsorbing at a temperature above the LCST-desorbing at a temperature below the LCST” performance for bovine serum albumin molecules. Then a temperature-dependent molecular-recognizable membrane with both grafted PNIPAM chains and immobilized β-CD moieties for affinity separation is introduced. Contrariwise to the first kind of membrane, this membrane demonstrates effective “adsorbing at a temperature below the LCST-desorbing at a temperature above the LCST” performance for guest molecules.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Schild H G. Poly(N-isopropylacrylamide): experiment, theory and application. Progress in Polymer Science, 1992, 17: 163–249.
Meng T, Xie R, Chen Y C, Cheng C J, Li P F, Ju X J, Chu L Y. A thermo-responsive affinity membrane with nano-structured pores and grafted poly(N-isopropylacrylamide) surface layer for hydrophobic adsorption. Journal of Membrane Science, 2010, 349: 258–267.
Xie R, Zhang S B, Wang H D, Yang M, Li P F, Zhu X L, Chu L Y. Temperature-dependent molecular-recognizable membranes based on poly (N-isopropylacrylamide) and β-cyclodextrin. Journal of Membrane Science, 2009, 326: 618–626.
Roper D K, Lightfoot E N. Separation of biomolecules using adsorptive membranes. Journal of Chromatography A, 1995, 702: 3–26.
Charcosset D. Purification of proteins by membrane chromatography. Journal of Chemical Technology and Biotechnology, 1998, 71: 95–110.
Guo W, Ruckenstein E. Separation and purification of horseradish peroxidase by membrane affinity chromatography. Journal of Membrane Science, 2003, 211: 101–111.
Zeng X, Ruckenstein E. Membrane chromatography: preparation and applications to protein separation. Biotechnology Progress, 1999, 15: 1003–1019.
Choi Y J, Yamaguchi T, Nakao S. A novel separation system using porous thermosensitive membranes. Industrial & Engineering Chemistry Research, 2000, 39: 2491–2495.
Feng L, Li S, Li Y, Li H, Zhang L, Zhai J, Song Y, Liu B, Jiang L, Zhu D. Super-hydrophobic surfaces: from natural to artificial. Advanced Materials, 2002, 14: 1857–1860.
Sun T, Wang G, Feng L, Liu B, Ma Y, Jiang L, Zhu D. Reversible switching between superhydrophilicity and superhydrophobicity. Angewandte Chemie International Edition, 2004, 43: 357–360.
Xia F, Feng L, Wang S, Sun T, Song W, Jiang W, Jiang L. Dual-responsive surfaces that switch between superhydrophilicity and superhydrophobicity. Advanced Materials, 2006, 18: 432–436.
Xia F, Ge H, Hou Y, Sun T, Chen L, Zhang G, Jiang L. Multiresponsive surfaces change between superhydrophilicity and superhydrophobicity. Advanced Materials, 2007, 19: 2520–2524.
Song W, Xia F, Bai Y, Liu F, Sun T, Jiang L. Controllable water permeation on a poly(N-isopropylacrylamide)-modified nanostructured copper mesh film. Langmuir, 2007, 23: 327–331.
Vladisavljevica G T, Shimizu M, Nakashima T. Permeability of hydrophilic and hydrophobic Shirasu-porous-glass (SPG) membranes to pure liquids and its microstructure. Journal of Membrane Science, 2005, 250: 69–77.
Zhang L, Li Y, Sun J, Shen J. Layer-by-layer fabrication of broad-band superhydrophobic antireflection coatings in near-infrared region. Journal of Colloid and Interface Science, 2008, 319: 302–308.
Stober W, Fink A, Bohn E. Controlled growth of monodisperse silica spheres in the micron size range. Journal of Colloid and Interface Science, 1968, 26: 62–69.
Wang R, Hashimoto K, Fujishima A, Chikuni M, Kojima E, Kitamura A, Shimohigoshi M, Watanabe T. Light-induced amphiphilic surfaces. Nature, 1997, 388: 431–432.
Ivanov D, Petrova H. Capillary effects. Physics Education, 2000, 35: 262–266.
Shamim N, Hong L, Hidajat K, Uddin M S. Thermosensitive-polymercoated magnetic nanoparticles: Adsorption and desorption of Bovine Serum Albumin. Journal of Colloid and Interface Science, 2006, 304: 1–8.
Kapur V, Charkoudian J, Anderson J L. Transport of proteins through gel-filled porous membranes. Journal of Membrane Science, 1997, 131: 143–153.
Peters T J. All about Albumin: Biochemistry, Genetics, and Medical Applications. Academic Press, San Diego, CA, 1996.
Rezwan K, Meier L P, Rezwan M, Voros J, Textor M, Gauckler L J. Bovine serum albumin adsorption onto colloidal Al2O3 particles: a new model based on zeta potential and UV-Vis measurements. Langmuir, 2004, 20: 10055–10061.
Alkan M, Demirbas O, Dogan M, Arslan O. Surface properties of bovine serum albumin-adsorbed oxides: adsorption, adsorption kinetics and electrokinetic properties. Microporous and Mesoporous Materials, 2006, 96: 331–340.
Cheng C J, Chu L Y, Ren P W, Zhang J, Hu L. Preparation of monodisperse thermo-sensitive poly(N-isopropylacrylamide) hollow microcapsules. Journal of Colloid and Interface Science, 2007, 313: 383–388.
Yanagioka M, Kurita H, Yamaguchi T, Nakao S. Development of a molecular recognition separation membrane using cyclodextrin complexation controlled by thermosensitive polymer chains. Industrial & Engineering Chemistry Research, 2003, 42: 380–385.
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 2011 Zhejiang University Press, Hangzhou and Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Chu, LY. (2011). Thermo-Responsive Membranes for Affinity Separation. In: Smart Membrane Materials and Systems. Advanced Topics in Science and Technology in China. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-18114-6_6
Download citation
DOI: https://doi.org/10.1007/978-3-642-18114-6_6
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-18113-9
Online ISBN: 978-3-642-18114-6
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)