Abstract
A chemical reaction between reactants Aa, Ab, etc., which form the products Ac, Ad, etc. can be described in the following form
The ν i thereby designate the so-called stoichiometric coefficients of the reaction. Since every chemical reaction can in principle run both forwards as well as backwards, the reaction arrow in (5.1) can be replaced with an equal sign. We thereby obtain the general form of the reaction equation
whereby the stoichiometric coefficients are conventionally negative for all educts and positive for all products.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Antoni C (1998) Untersuchung des Verbrennungsvorgangs im direkteinspritzenden Dieselmotor mit zyklusaufgelöster Emissionsspektroskopie. Dissertation, RWTH Aachen
Chaos M, Kazakov A, Zhao Z, Dryer FL (2007) A high-temperature chemical kinetic model for primary reference fuels. Int J Chem Kinet 39:399–414
Curran HJ, Gaffuri P, Pitz WJ, Westbrook CK (1998) A comprehensive modeling study of n-heptane oxidation. Combust Flame 114:149–177
Curran HJ, Gaffuri P, Pitz WJ, Westbrook CK (2002) A comprehensive modeling study of iso-octane oxidation. Combust Flame 129:253–280
Farrell JT, Cernansky NP, Dryer FL, Friend DG, Hergart CA, Law CK, McDavid R, Mueller CJ, Pitsch H (2007) Development of an experimental database and kinetic models for surrogate diesel fuels. SAE Paper 2007-01-0201
Glassmann I (1996) Combustion. Academic, San Diego
Halstead M, Kirsch L, Quinn C (1977) The autoignition of hydrocarbon fuels at high temperatures and pressures – fitting of a mathematical model. Combust Flame 30:45–60
Kong S-C, Han Z, Reitz RD (1995) The developement and application of a diesel ignition and combustion model for multidimensional engine simulations. SAE Paper 950278
Leppard WR (1990) The chemical origin of fuel octane sensitivity. SAE paper 902137
Lu T, Law CK (2006) Linear time reduction of large kinetic mechanisms with directed relation graph: n-Heptane and iso-octane. Combust Flame 144:24–36
Lu T, Law CK (2009) Toward accommodating realistic fuel chemistry in large-scale computations. Progr Energ Combust Sci 35:192–215
Maas U, Pope SB (1992) Simplifying chemical-kinetics – intrinsic low-dimensional manifolds in composition space. Combust Flame 88:239–264
Meeks E, Ando H, Chou C-P, Dean AM, Hodgson D, Koshi M, Lengyel I, Maas U, Naik CV, Puduppakkam KV, Reitz RD, Wang C, Westbrook CK (1988) New modeling approaches using detailed kinetics for advanced engines. 7. International conf. on modeling and diagnostics for advanced engine systems (COMODIA), Sapporo
Moran MJ, Shapiro HN (1992) Fundamentals of engineering thermodynamics, 2nd edn. Wiley, New York, NY
Pitz WJ, Cernansky NP, Dryer FL, Egolfopoulos FN, Farrell JT, Friend DG, Pitsch H (2007) Development of an experimental database and kinetic models for surrogate gasoline fuels. SAE Paper 2007-01-0175
Reynolds WC (1986) The element potential method for chemical equilibrium analysis: implementation in the interactive program STANJAN, Stanford University
Semenov N (1935) Chemical kinetics and chain reactions. Oxford University Press, London
Smith GP, Golden DM, Frenklach M, Moriarty NW, Eiteneer B, Goldenberg M, Bowman CT, Hanson RK, Song S, Gardiner WC Jr, Lissianski VV, Qin Z (1999) http://www.me.berkeley.edu/gri_mech/
Tomlin AS, Turanyi T, Pilling MJ (1997) Mathematical tools for the construction, investigation and reduction of combustion mechanisms. In: Pilling MJ, Hancock G (eds) Low-temperature Combustion and Autoignition, vol 35, Comprehensive Chemical Kinetics., p 293
Warnatz J, Maas U, Dibble RW (2001) Verbrennung: Physikalisch-Chemische Grundlagen. Modellierung und Simulation, Experimente, Schadstoffentstehung. 3. Aufl., Springer, Berlin
Westbrook CK, Dryer FL (1981) Simplified Reaction Mechanism for the Oxidation of Hydrocarbon Fuels in Flames. Combustion Sci. Tech., Vol. 27, 31–48
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2012 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Stiesch, G., Eckert, P. (2012). Reaction Kinetics. In: Merker, G., Schwarz, C., Teichmann, R. (eds) Combustion Engines Development. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-14094-5_5
Download citation
DOI: https://doi.org/10.1007/978-3-642-14094-5_5
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-02951-6
Online ISBN: 978-3-642-14094-5
eBook Packages: EngineeringEngineering (R0)