Abstract
Chemically prepared nanoparticles are an exceptional class of materials that owe their properties to both the three-dimensional confinement and their large surface area. To characterize their electronic and geometric structural properties, X-ray methods offer unique capabilities. In this chapter, we demonstrate how a combination of X-ray spectroscopy and X-ray diffraction techniques allows one to characterize these nanoparticles with respect to their local atomic properties, their long-range crystalline order and their nanoscale core–shell structure.
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E. Suljoti, M. Nagasono, A. Pietzsch, K. Hickmann, D. Trots, M. Haase, W. Wurth, A. Föhlisch, J. Chem. Phys. 128, 134706 (2008)
O. Lehmann, H. Meyssamy, K. Kömpe, H. Schnablegger, M. Haase, J.Phys. Chem. B 107, 7449 (2003)
R.D. Cowan, The Theory of Atomic Structure and Spectra (University of California Press, Berkeley, CA, 1981)
B.T. Thole, G. van der Laan, J.C. Fuggle, G.A. Sawatzky, R.C. Karnatak, J.-M.Esteva, Phys. Rev. B 32, 5107 (1985)
B.T. Thole, G. van der Laan, Europhys. Lett. 4(9), 1083 (1987)
B.T. Thole, Phys. Rev. B 38, 3158 (1988)
Y. Ni, J.M. Hughes, A.N. Mariano, Am. Mineral. 80, 21 (1995)
T. Roisnel, J. Rodriquez-Carvajal, Mater. Sci. Forum 378/381, 118 (2001)
P. Scherrer, Nachr. Ges. Wiss. Gottingen, Math.-Phys. Kl. 2, 98 (1918)
S. Howard, K. Preston, Modern Powder Diffraction, vol. 20 (Mineralogical Society of America, Chantilly, VA, 1989)
B.O. Dabbousi, J. Rodriguez-Viejo, F.V. Mikulec, J.R. Heine, H. Mattoussi, R. Ober, K.F. Jensen, M.G. Bawendi, J. Phys. Chem. B 101, 9463 (1997)
A.P. Alivisatos, Nat. Biotech. 22, 47 (2004)
V.I. Klimov, A.A. Mikhailovsky, D.W. McBranch, C.A. Leatherdale, M.G. Bawendi, Science 287(5455), 1011 (2000). doi:10.1126/science.287.5455.1011
V.I. Klimov, A.A. Mikhailovsky, S. Xu, A. Malko, J.A. Hollingsworth, C.A. Leatherdale, H.J. Eisler, M.G. Bawendi, Science 290(5490), 314 (2000)
X. Brokmann, G. Messin, P. Desbiolles, E. Giacobino, M. Dahan, J.P. Hermier, New J. Phys. 6, 99 (2004)
D. Talapin, I. Mekis, S. Götzinger, A. Kornowski, O. Benson, H. Weller, J. Phys. Chem. 108, 18826 (2004)
X. Peng, M.C. Schlamp, A.V. Kadavanich, A.P. Alivisatos, J. Am. Chem. Soc. 119(30), 7019 (1997). http://dx.doi.org/10.1021/ja970754m
C.L. Cleveland, U. Landman, T.G. Schaaff, M.N. Shafigullin, P.W. Stephens, R.L. Whetten, Phys. Rev. Lett. 79(10), 1873 (1997)
A. Pietzsch, E. Suljoti, M. Nagasono, A. Föhlisch, W. Wurth, J. Electron Spectrosc. Relat. Phenom. 81–83, 166 (2008)
K.S. Hamad, R. Roth, J. Rockenberger, T. van Buuren, A.P. Alivisatos, Phys. Rev. Lett. 83(17), 3474 (1999)
S. Hüfner, Photoemission Spectrocsopy: Principles and Applications (Springer, Berlin, 1996)
K. Fauth, Appl. Phys. Lett. 85(15), 3271 (2004)
I. Mekis, D. Talapin, A. Kornowski, M. Haase, H. Weller, J. Phys. Chem. B 107(30), 7454 (2003)
J.E.B. Katari, V.L. Colvin, A.P. Alivisatos, J. Phys. Chem. 98, 4109 (1994)
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Suljoti, E., Pietzsch, A., Wurth, W., Föhlisch, A. (2010). How X-Ray Methods Probe Chemically Prepared Nanoparticles from the Atomic- to the Nano-Scale. In: Heitmann, D. (eds) Quantum Materials, Lateral Semiconductor Nanostructures, Hybrid Systems and Nanocrystals. NanoScience and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-10553-1_17
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DOI: https://doi.org/10.1007/978-3-642-10553-1_17
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