Abstract
The degradation of perchloroethylene (PCE) adsorbed on hydrophobic modified bentonite was investigated. The degradation occurred via reduction of iron particles with zero valence (ZVI) incorporated in hydrophobic surface of bentonite. We compared two different systems, one containing ZVI and another without ZVI. The degradation of PCE was accompanied by decreasing concentrations of PCE and the increase of resulting compounds such as trichloroethylene (TCE), 1,2-dichloroethylene, trans and cis forms, (1,2-cis-DCE and 1,2- trans-DCE). The results show that the PCE is rapidly adsorbed and in contact with ZVI particles is degraded to less toxic compounds, while in the systems without ZVI no significant decrease of PCE was observed, clearly demonstrating that the degradation process occurs through the reduction with ZVI. The rate constant for the system containing ZVI was 0.215 h−1, while for the system without ZVI it was only 0.031 h−1. The results agree with other research, however the reaction was conducted in columns and the clay was zeolite. It can be concluded that the system impregnated with ZVI is extremely interesting as an alternative application for removal of organic compounds containing chlorine due to their persistence and toxic effect on the microorganisms. The system can also be applied as barrier content.
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References
Arnold WA, Roberts AL (2000) Pathways and kinetics of chlorinated ethylene and chlorinated acetylene reaction with Fe(0) particles. Environ. Sci. Technol. 34: 1794–1805
Froehner S, Furukawa W, Martins RF, Errera MR (2009) Water remediation by adsorption of phenol onto hydrophobic modified clay. Water Air Soil Poll. 199: 107–113
Froehner S, Machado KS, Falcão F (2009) Exploring the adsorption of dibenzothiophene by vermiculite in hydrophobic form, impregnated with copper ions and in natural form. Water Air Soil Pollution. Submitted
Li Z, Willms C, Alley J, Zhang P, Bowman RS (2006) A shift in pathway of iron-mediated perchloroethylene reduction in the presence of sorbed surfactant—A column study. Water Research 40: 3811–3819
Sung HJ, Feitz AJ, Waite TD (2004) Oxidative degradation of the carbothioate herbicide, molinate, using nanoscale zero-valent iron. Environ. Sci. Technol. 38: 2242–2247
Wang J, Farrell J (2003) Investigating the role of atomic hydrogen on chloroethene reactions with iron using Tafel analysis and electrochemical impedance spectroscopy. Environ. Sci. Technol. 37: 3891–3896
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© 2010 Zhejiang University Press, Hangzhou and Springer-Verlag Berlin Heidelberg
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Froehner, S., Maceno, M., Da Luz, E.C., Machado, K.S., Falcão, F. (2010). Degradation of Organochlorine Compounds Using Zero Valent Iron (ZVI) Nano Particles Impregnated in Hydrophobic Modified Bentonite. In: Xu, J., Huang, P.M. (eds) Molecular Environmental Soil Science at the Interfaces in the Earth’s Critical Zone. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-05297-2_73
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DOI: https://doi.org/10.1007/978-3-642-05297-2_73
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-05296-5
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