Skip to main content

Role of Biomolecules in Influencing Transformation Mechanisms of Metals and Metalloids in Soil Environments

  • Conference paper
Molecular Environmental Soil Science at the Interfaces in the Earth’s Critical Zone
  • 3273 Accesses

Abstract

Characterizing the factors which affect the mobility, bioavailability, leaching and toxicity of metals and metalloids in soil environments is of paramount importance. Special attention is devoted to the influence of biomolecules, mainly roots exudates, as well as pH, nature of the sorbents, redox reactions on the transformation mechanisms of trace elements in cationic and anionic forms in soils. Time of reaction and the surface coverage have a great influence on the sorption/desorption processes of trace elements in the presence of organic ligands. Leaching and extraction tests are widely used for assessing trace element phytoavailability.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 319.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Beveridge TJ (1989) Metal ions and bacteria. In: Beveridge TJ, and Doyle RJ (eds.), Metal Ions and Bacteria. Wiley, New York, pp.1–29

    Google Scholar 

  • Huang PM, Germida JJ (2002) Chemical and Biochemical Processes in the Rhizosphere: Metal Pollutants. In: Huang PM, Bollag JM, Senesi N (eds.), Interactions between Soil Particles and Microorganisms: Impact on the Terrestrial Ecosystem, John Wiley & Sons, New York, 381–438

    Google Scholar 

  • Jackson TA (1998) The Biogeochemical and Ecological Significance of Interactions between Colloidal Minerals and Trace Elements. In: Parker A, Rae JE (eds.), Environmental Interactions of Clays, Springer-Verlag, Berlin, pp.93–205

    Google Scholar 

  • Pigna M, Krishnamurti GSR, Violante A (2006) Kinetics of arsenate sorption-desorption from metal oxides: Effect of residence time. Soil Sci. Soc. Am. J. 70: 2017–2027

    Article  CAS  Google Scholar 

  • Sparks DL (2003) Environmental Soil Chemistry. 2nd Edition. Academic Press, San Diego

    Google Scholar 

  • Violante A, Huang PM, Gadd G (2008) Biophysico-Chemical Processes of Metals and Metalloids in Soil Environments. John Wiley & Sons

    Google Scholar 

  • Violante A, Pigna M (2002) Competitive sorption of arsenate and phosphate on different clay minerals and soils. Soil Sci. Soc. Am. J. 66: 1788–1796

    Article  CAS  Google Scholar 

  • Violante A, Pucci M, Cozzolino V, Zhu J, Pigna M (2009) Sorption/desorption of arsenate on/from Mg-Al layered double hydroxides: Influence of phosphate. J. Colloid Interface Sci. 333: 63–70

    Article  CAS  Google Scholar 

  • Violante A, Krishnamurti GSR, Huang PM (2002) Impact of organic substances on the formation of metal oxides in soil environments. In: Huang PM, Bollag JM, Senesi N (eds.), Interactions between Soil Particles and Microorganisms: Impact on the Terrestrial Ecosystem. John Wiley & Sons, New York, pp.381–438

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Antonio Violante .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Zhejiang University Press, Hangzhou and Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Violante, A. (2010). Role of Biomolecules in Influencing Transformation Mechanisms of Metals and Metalloids in Soil Environments. In: Xu, J., Huang, P.M. (eds) Molecular Environmental Soil Science at the Interfaces in the Earth’s Critical Zone. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-05297-2_13

Download citation

Publish with us

Policies and ethics