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Nanostructured Biomaterials pp 83–132Cite as

Inorganic-organic Hybrid Materials Based on Nano-polyoxometalates and Surfactants

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Part of the book series: Advanced Topics in Science and Technology in China ((ATSTC))

Abstract

A series of nano-scale polyoxometalates (POMs) with beautiful topologies have been successfully synthesized by destroying the hydration shell of metal oxides. Their magnetic, electronic, and photoluminescent properties and valuable applications in catalysis, medicine, and material science are discussed. By interaction with oppositely charged surfactants, an interesting phase transfer of POMs occurs from aqueous solution to chloroform solution by forming hydrophobic surfactant-encapsulated clusters (HSECs), and then to aqueous solution with more surfactants. Moreover, inorganic-organic hybrids composed of polyoxometalates and surfactants or polyelectrolytes are fabricated by layer-by-layer (LbL) and Langmuir-Blodgett (LB) techniques. A simple solvent-evaporation method is also delicately carried out, and consequently, ordered honeycomb films are self-assembled at air/water interfaces without any extra moist airflow. It is speculated that the condensed water micro-droplets induced by the quick evaporation of solvents play an important role as template for the formation of pores. And many types of modulation are being investigated to construct thin films with different morphologies. The incorporation of functional polyoxometalates in thin films will bridge polyoxometalate chemistry and material chemistry.

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Authors and Affiliations

  1. Key Laboratory for Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan, 250100, China

    Peiqin Tang & Jingcheng Hao

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  1. Peiqin Tang
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  2. Jingcheng Hao
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Correspondence to Jingcheng Hao .

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  1. Key Lab of the Colloid and Interface Sciences International Joint Lab with the German Max Planck Institute of Colloids & Interfaces Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China

    Junbai Li

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Tang, P., Hao, J. (2010). Inorganic-organic Hybrid Materials Based on Nano-polyoxometalates and Surfactants. In: Li, J. (eds) Nanostructured Biomaterials. Advanced Topics in Science and Technology in China. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-05012-1_3

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