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Transition Metal Complexes of Neutral eta1-Carbon Ligands pp 219–252Cite as

Heteroatom-Conjugated Allenylidene and Related Cumulenylidene Ligands

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Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 30))

Abstract

In this chapter, aspects related to the synthesis, structure, and reactivity of metallacumulenes [M]=C(=C) n =CR1R2 (n = 1, 3, 5) in which one or both substituents R1/R2 are heteroatomic π-donor groups (NR2, OR, SR, SeR) are discussed. The coordination chemistry of related heteroatom-cumulated ligands, i.e., phosphonioacetylides and tricarbon monoxide, is also presented.

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Abbreviations

Cp:

Cyclopentadienyl

Cp*:

Pentamethylcyclopentadienyl

depe:

1,2-Bis(diethylphosphino)ethane

DFT:

Density functional theory

dhpm:

Bis(dihydrophosphino)methane

dppe:

1,2-Bis(diphenylphosphino)ethane

dppm:

Bis(diphenylphosphino)methane

Fc:

Ferrocenyl

MO:

Molecular orbital

NLO:

Nonlinear optics

tppe:

1,1,2-Tris(diphenylphosphino)ethane

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Acknowledgments

Financial support by the Ministerio de Educación y Ciencia (MEC) of Spain (Projects CTQ2006-08485/BQU and Consolider Ingenio 2010 (CSD2007-00006)) and the Gobierno del Principado de Asturias (FICYT Project IB08-036) is gratefully acknowledged. S.-E.G.G. also thanks MEC and the European Social Fund for the award of a “Ramón y Cajal” contract.

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Authors and Affiliations

  1. Departamento de Química Orgánica e Inorgánica, IUQOEM-CSIC, Facultad de Química, Universidad de Oviedo, E-33071, Oviedo, Spain

    Victorio Cadierno & Sergio E. García-Garrido

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  1. Victorio Cadierno
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  2. Sergio E. García-Garrido
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Correspondence to Victorio Cadierno .

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Editors and Affiliations

  1. CNRS, Université Toulouse III, route de Narbonne 205 , Toulouse CX 4, 31077, France

    Remi Chauvin

  2. CNRS, Université Toulouse III, route de Narbonne 205 , Toulouse CX 4, 31077, France

    Yves Canac

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Cadierno, V., García-Garrido, S.E. (2010). Heteroatom-Conjugated Allenylidene and Related Cumulenylidene Ligands. In: Chauvin, R., Canac, Y. (eds) Transition Metal Complexes of Neutral eta1-Carbon Ligands. Topics in Organometallic Chemistry, vol 30. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-04722-0_7

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