Summary
UV laser ablation of polymers is a versatile method to structure polymers with high resolution. The mechanism of ablation is often discussed controversially, but it is necessary to keep in mind that polymers are complex systems with a wide variety of properties that can influence the ablation mechanism. Analyzing the data, it appears that the ablation mechanism is a complex interrelated system, where photochemical and photothermal reactions are very important. The pressure jump, which is associated with the creation of small molecules and originates from both types of reaction, is also important for ablation. The importance of each effect is strongly dependent on the type of polymer, the laser wavelengths, the pulse length, and the substrate. UV laser ablation can also be utilized to deposit directly thin polymer films by PLD, but this is limited to certain polymers. Alternative laser-based techniques (LIFT) utilize the decomposition of a thin layer to transfer complete layers with high spatial resolution. This approach can be used to transfer pixels of sensitive materials to a substrate with a minimal thermal and UV load.
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References
R. Srinivasan, V. Mayne-Banton, Appl. Phys. Lett. 41, 576 (1982)
Y. Kawamura, K. Toyoda, S. Namba, Appl. Phys. Lett. 40, 374 (1982)
R. Srinivasan, B. Braren, Chem. Rev. 89, 1303 (1989)
D. Bäuerle, Laser Processing and Chemistry, 3rd edn. (Springer Verlag, Berlin, 2000)
S. Lazare, V. Granier, Laser Chem. 10, 25 (1989)
T. Lippert, J.T. Dickinson, Chem. Rev. 103, 453 (2003)
T. Lippert, in Polymers and Light, vol. 168, ed. by T. Lippert (Springer, Berlin, 2004) p. 51
P.E. Dyer, in Photochemical Processing of Electronic Materials, ed. by I.W. Boyd, R.B. Jackman (Academic, London, 1992) p. 360
N. Bityurin, B.S. Luk’yanchuk, M.H. Hong, T.C. Chong, Chem. Rev. 103, 519 (2003)
T. Lippert, Plasma Process. Polym. 2, 525 (2005)
N. Bityurin, Annu. Rep. Progr. Chem. C 101, 216 (2005)
M. Karas, D. Bachmann, F. Hillenkamp, Anal. Chem. 57, 2935 (1985)
R. Zenobi, R. Knochenmuss, Mass Spectrom. Rev. 17, 337 (1998)
L.J. Radziemski, D.A. Cremers, Laser-Induced Plasmas and Applications (M. Dekker, New York, 1989)
G.B. Blanchet, Macromolecules 28, 4603 (1995)
G.B. Blanchet, Chemtech 26, 31 (1996)
W.B. Jiang, M.G. Norton, L. Tsung, J.T. Dickinson, J. Mater. Res. 10, 1038 (1995)
R.W. Eason, Pulsed Laser Deposition of Thin Films: Applications-Led Growth of Functional Materials (John Wiley, Hoboken, NJ, 2007)
D.B. Chrisey, G.K. Hubler, Pulsed Laser Deposition of Thin Films (John Wiley, New York, 1994)
A. Pique, P. Wu, B.R. Ringeisen, D.M. Bubb, J.S. Melinger, R.A. McGill, D.B. Chrisey, Appl. Surf. Sci. 186, 408 (2002)
J. Bohandy, B.F. Kim, F.J. Adrian, J. Appl. Phys. 60, 1538 (1986)
K.D. Kyrkis, A.A. Andreadaki, D.G. Papazoglou, I. Zergioti, in Recent Advances in Laser Processing of Materials, vol. 241, ed. by J. Perrière, E. Millon, E. Fogarassy (Elsevier, Amsterdam, 2006) p. 213
H. Aoki (U.S. Patent 5736999, 1998)
R.S. Patel, T.A. Wassick, Proc. SPIE-Int. Soc. Opt. Eng. 2991, 217 (1997)
G. Kopitkovas, L. Urech, T. Lippert, in Recent Advances in Laser Processing of Materials, ed. by E. Millon, J. Perriere, E. Fogarassy (Elsevier, Kidlington, 2006) p. 105
H. Klank, J.P. Kutter, O. Geschke, Lab Chip 2, 242–246 (2002)
D. Snakenborg, H. Klank, J.P. Kutter, J. Micromech. Microeng. 14, 182 (2004)
D. Gomez, F. Tekniker, I. Goenaga, I. Lizuain, M. Ozaita, Opt. Eng. 44, 051105 (2005)
D.F. Farson, H.W. Choi, C.M. Lu, L.J. Lee, J. Laser Appl. 18, 210 (2006)
S. Lazare, W.P. Guan, D. Drilhole, Appl. Surf. Sci. 96–98, 605 (1996)
E.E. Ortelli, F. Geiger, T. Lippert, J. Wei, A. Wokaun, Macromolecules 33, 5090 (2000)
P. Lemoine, W. Blau, A. Drury, C. Keely, Polymer 34, 5020 (1993)
T. Lippert, A. Wokaun, J. Stebani, O. Nuyken, J. Ihlemann, Angew. Makromol. Chem. 213, 127 (1993)
G. Bounos, A. Selimis, S. Georgiou, E. Rebollar, M. Castillejo, N. Bityurin, J. Appl. Phys. 100, 114323 (2006)
E. Rebollar, G. Bounos, M. Oujja, S. Georgiou, M. Castillejo, J. Phys. Chem. B 110, 16452 (2006)
R. Srinivasan, J. Appl. Phys. 70, 7588 (1991)
R. Srinivasan, B. Braren, Appl. Phys. A 45, 289 (1988)
P.E. Dyer, S.D. Jenkins, J. Sidhu, Appl. Phys. Lett. 52, 1880 (1988)
P.E. Dyer, S.D. Jenkins, J. Sidhu, Appl. Phys. Lett. 49, 453 (1986)
J. Wei, N. Hoogen, T. Lippert, O. Nuyken, A. Wokaun, J. Phys. Chem. B 105, 1267 (2001)
F. Raimondi, S. Abolhassani, R. Brutsch, F. Geiger, T. Lippert, J. Wambach, J. Wei, A. Wokaun, J. Appl. Phys. 88, 3659 (2000)
J. Krüger, W. Kautek, in Polymers And Light, vol. 168, ed. by T. Lippert (Springer, Berlin, 2004) p. 247
T. Dumont, R. Bischofberger, T. Lippert, A. Wokaun, Appl. Surf. Sci. 247, 115 (2005)
T. Dumont, S. Lazare, T. Lippert, A. Wokaun, Appl. Phys. A 79, 1271 (2004)
R. Srinivasan, B. Braren, D.E. Seeger, R.W. Dreyfus, Macromolecules 19, 916 (1986)
R. Srinivasan, J. Appl. Phys. 73, 2743 (1993)
J.E. Andrew, P.E. Dyer, D. Forster, P.H. Key, Appl. Phys. Lett. 43, 717 (1983)
R. Srinivasan, B. Braren, J. Polym. Sci. A Polym. Chem. 22, 2601 (1984)
R. Srinivasan, B. Braren, K.G. Casey, J. Appl. Phys. 68, 1842 (1990)
S. Küper, M. Stuke, Appl. Phys. A 49, 211 (1989)
S.V. Babu, G.C. D’Couto, F.D. Egitto, J. Appl. Phys. 72, 692 (1992)
M. Himmelbauer, E. Arenholz, D. Bauerle, Appl. Phys. A 63, 87 (1996)
G. Paraskevopoulos, D.L. Singleton, R.S. Irwin, R.S. Taylor, J. Appl.Phys. 70, 1938 (1991)
R.S. Taylor, D.L. Singleton, G. Paraskevopoulos, Appl. Phys. Lett. 50, 1779 (1987)
S. Küper, J. Brannon, K. Brannon, Appl. Phys. A 56, 43 (1993)
S.R. Cain, J. Phys. Chem. 97, 7572 (1993)
S.R. Cain, F.C. Burns, C.E. Otis, J. Appl. Phys. 71, 4107 (1992)
G.C. D’Couto, S.V. Babu, J. Appl. Phys. 76, 3052 (1994)
B. Lukyanchuk, N. Bityurin, M. Himmelbauer, N. Arnold, Nucl. Instrum. Methods Phys. Res. B 122, 347 (1997)
N. Arnold, B. Luk’yanchuk, N. Bityurin, Appl. Surf. Sci. 129, 184 (1998)
T.F. Deutsch, M.W. Geis, J. Appl. Phys. 54, 7201 (1983)
E. Sutcliffe, R. Srinivasan, J. Appl. Phys. 60, 3315 (1986)
G.D. Mahan, H.S. Cole, Y.S. Liu, H.R. Philipp, Appl. Phys. Lett. 53, 2377 (1988)
V. Srinivasan, M.A. Smrtic, S.V. Babu, J. Appl. Phys. 59, 3861 (1986)
H. Schmidt, J. Ihlemann, B. Wolff-Rottke, K. Luther, J. Troe, J. Appl. Phys. 83, 5458 (1998)
B. Lukyanchuk, N. Bityurin, S. Anisimov, N. Arnold, D. Bauerle, Appl. Phys. A 62, 397 (1996)
B. Lukyanchuk, N. Bityurin, S. Anisimov, D. Bauerle, Appl. Phys. A 57, 367 (1993)
N. Bityurin, A. Malyshev, B. Luk’yanchuk, S. Anisimov, D. Bäuerle, Proc. SPIE-Int. Soc. Opt. Eng. 2802, 103 (1996)
N. Bityurin, Appl. Surf. Sci. 139, 354 (1999)
G.V. Treyz, R. Scarmozzino, R.M. Osgood, Appl. Phys. Lett. 55, 346 (1989)
N. Arnold, N. Bityurin, Appl. Phys. A 68, 615 (1999)
Y.G. Yingling, B.J. Garrison, J. Phys. Chem. B 109, 16482 (2005)
Y.G. Yingling, B.J. Garrison, J. Phys. Chem. B 108, 1815 (2004)
P.F. Conforti, M. Prasad, B.J. Garrison, Appl. Surf. Sci. 253, 6386 (2007)
P.F. Conforti, M. Prasad, B.J. Garrison, J. Phys. Chem. C 111, 12024 (2007)
M. Prasad, P.F. Conforti, B.J. Garrison, J. Appl. Phys. 101, 103113 (2007)
M. Prasad, P.F. Conforti, B.J. Garrison, J. Chem. Phys. 127, 084705 (2007)
M. Prasad, P.F. Conforti, B.J. Garrison, Y.G. Yingling, Appl. Surf. Sci. 253, 6382 (2007)
Y.G. Yingling, B.J. Garrison, Appl. Surf. Sci. 253, 6377 (2007)
Y.G. Yingling, L.V. Zhigilei, B.J. Garrison, J. Photochem. Photobiol. A Chem. 145, 173 (2001)
L.V. Zhigilei, E. Leveugle, B.J. Garrison, Y.G. Yingling, M.I. Zeifman, Chem. Rev. 103, 321 (2003)
Y.G. Yingling, B.J. Garrison, Chem. Phys. Lett. 364, 237 (2002)
Y.G. Yingling, B.J. Garrison, Nucl. Instrum. Methods Phys. Res. B 202, 188 (2003)
N. Bityurin, A. Malyshev, J. Appl. Phys. 92, 605 (2002)
T. Lippert, A. Yabe, A. Wokaun, Adv. Mater. 9, 105 (1997)
T. Lippert, J. Stebani, O. Nuyken, A. Stasko, A. Wokaun, J. Photochem. Photobiol. A Chem. 78, 139 (1994)
O. Nuyken, J. Stebani, T. Lippert, A. Wokaun, A. Stasko, Macromol. Chem. Phys. 196, 751 (1995)
A. Stasko, V. Adamcik, T. Lippert, A. Wokaun, J. Dauth, O. Nuyken, Makromol. Chem. Macromol. Chem. Phys. 194, 3385 (1993)
O. Nuyken, J. Stebani, T. Lippert, A. Wokaun, A. Stasko, Macromol. Chem. Phys. 196, 739 (1995)
T. Lippert, L.S. Bennett, T. Nakamura, H. Niino, A. Ouchi, A. Yabe, Appl. Phys. A 63, 257 (1996)
T. Lippert, T. Nakamura, H. Niino, A. Yabe, Appl. Surf. Sci. 110, 227 (1997)
T. Lippert, C. David, J.T. Dickinson, M. Hauer, U. Kogelschatz, S.C. Langford, O. Nuyken, C. Phipps, J. Robert, A. Wokaun, J. Photochem. Photobiol. A Chem. 145, 145 (2001)
T. Lippert, A. Wokaun, S.C. Langford, J.T. Dickinson, Appl. Phys. A 69, S655 (1999)
T. Lippert, S.C. Langford, A. Wokaun, G. Savas, J.T. Dickinson, J. Appl. Phys. 86, 7116 (1999)
M. Hauer, J.T. Dickinson, S. Langford, T. Lippert, A. Wokaun, Appl. Surf. Sci. 197, 791 (2002)
H. Furutani, H. Fukumura, H. Masuhara, J. Phys. Chem. 100, 6871 (1996)
H. Furutani, H. Fukumura, H. Masuhara, S. Kambara, T. Kitaguchi, H. Tsukada, T. Ozawa, J. Phys. Chem. B 102, 3395 (1998)
T. Lippert, J.T. Dickinson, M. Hauer, G. Kopitkovas, S.C. Langford, H. Masuhara, O. Nuyken, J. Robert, H. Salmio, T. Tada, K. Tomita, A. Wokaun, Appl. Surf. Sci. 197, 746 (2002)
M. Hauer, D.J. Funk, T. Lippert, A. Wokaun, Appl. Surf. Sci. 208, 107–112 (2003)
J. Bonse, S.M. Wiggins, J. Solis, T. Lippert, Appl. Surf. Sci. 247, 440 (2005)
J. Bonse, S.M. Wiggins, J. Solis, T. Lippert, H. Sturm, Appl. Surf. Sci. 248, 157 (2005)
E.C. Buruiana, T. Buruiana, H. Lenuta, T. Lippert, L. Urech, A. Wokaun, J. Polym. Sci. A Polym. Chem. 44, 5271 (2006)
E.C. Buruiana, L. Hahui, T. Buruiana, L. Urech, T. Lippert, J. Photochem. Photobiol. A Chem. 195, 337 (2008)
E.C. Buruiana, V. Melinte, T. Buruiana, T. Lippert, H. Yoshikawa, H. Mashuhara, J. Photochem. Photobiol. A Chemistry 171, 261 (2005)
R. Fardel, M. Nagel, T. Lippert, F. Nuesch, A. Wokaun, B.S. Luk’yanchuk, Appl. Phys. A 90, 661 (2008)
G. Paltauf, P.E. Dyer, Chem. Rev. 103, 487 (2003)
D.E. Hare, D.D. Dlott, Appl. Phys. Lett. 64, 715 (1994)
D.E. Hare, J. Franken, D.D. Dlott, J. Appl. Phys. 77, 5950 (1995)
C.B. Arnold, P. Serra, A. Piqué, MRS Bull. 32, 23 (2007)
D.B. Chrisey, A. Pique, R.A. McGill, J.S. Horwitz, B.R. Ringeisen, D.M. Bubb, P.K. Wu, Chem. Rev. 103, 553 (2003)
X. Yang, Y. Tang, M. Yu, Q. Qin, Thin Solid Films 358, 187 (2000)
B. Losekrug, A. Meschede, H.U. Krebs, Appl. Surf. Sci. 254, 1312 (2007)
E. Suske, T. Scharf, H.U. Krebs, T. Junkers, M. Buback, J. Appl. Phys. 100, 014906 (2006)
D.B. Chrisey, A. Pique, J. Fitz-Gerald, R.C.Y. Auyeung, R.A. McGill, H.D. Wu, M. Duignan, Appl. Surf. Sci. 154, 593 (2000)
C. Germain, L. Charron, L. Lilge, Y.Y. Tsui, Appl. Surf. Sci. 253, 8328 (2007)
A. Klini, A. Mourka, V. Dinca, C. Fotakis, F. Claeyssens, Appl. Phys. A 87, 17 (2007)
H. Fukumura: J. Photochem. Photobiol. A Chem. 106, 3 (1997)
H. Fukumura, Y. Kohji, K. Nagasawa, H. Masuhara, J. Am. Chem. Soc. 116, 10304 (1994)
D.M. Karnakis, T. Lippert, N. Ichinose, S. Kawanishi, H. Fukumura, Appl. Surf. Sci. 129, 781 (1998)
J.Y. Lee, S.T. Lee, Adv. Mater. 16, 51 (2004)
H.P. Le, J. Imaging Sci. Technol. 42, 49 (1998)
F. Pschenitzka, J.C. Sturm, Appl. Phys. Lett. 74, 1913 (1999)
D.B. Chrisey, A. Piqué, J. Fitz-Gerald, R.C.Y. Auyeung, R.A. McGill, H.D. Wu, M. Duignan, Appl. Surf. Sci. 154–155, 593 (2000)
J.M. Fitz-Gerald, H.D. Wu, A. Pique, J.S. Horwitz, R.C.Y. Auyeung, W. Chang, W.J. Kim, D.B. Chrisey, Integrated Ferroelectrics 29, 13 (2000)
A. Pique, D.B. Chrisey, R.C.Y. Auyeung, J. Fitz-Gerald, H.D. Wu, R.A. McGill, S. Lakeou, P.K. Wu, V. Nguyen, M. Duignan, Appl. Phys. A 69, S279 (1999)
A. Pique, R.A. McGill, D.B. Chrisey, D. Leonhardt, T.E. Mslna, B.J. Spargo, J.H. Callahan, R.W. Vachet, R. Chung, M.A. Bucaro, Thin Solid Films 356, 536 (1999)
D.B. Chrisey, A. Pique, R. Modi, H.D. Wu, R.C.Y. Auyeung, H.D. Young, Appl. Surf. Sci. 168, 345 (2000)
D. Young, R.C.Y. Auyeung, A. Pique, D.B. Chrisey, D.D. Dlott, Appl. Phys. Lett. 78, 3169 (2001)
S.G. Koulikov, D.D. Dlott, J. Imaging Sci. Technol. 44, 111 (2000)
I.Y.S. Lee, W.A. Tolbert, D.D. Dlott, M.M. Doxtader, D.M. Foley, D.R. Arnold, E.W. Ellis, J. Imaging Sci. Technol. 36, 180 (1992)
W.A. Tolbert, I.Y.S. Lee, M.M. Doxtader, E.W. Ellis, D.D. Dlott, J. Imaging Sci. Technol. 37, 411 (1993)
W.A. Tolbert, I.YS. Lee, X.N. Wen, D.D. Dlott, M.M. Doxtader, E.W. Ellis, J. Imaging Sci. Technol. 37, 485 (1993)
G.R. Pinto, J. Imaging Sci. Technol. 38, 565 (1994)
J.M. Fernandez-Pradas, M. Colina, P. Serra, J. Dominguez, J.L. Morenza, Thin Solid Films 453, 27 (2004)
P. Serra, M. Colina, J.M. Fernandez-Pradas, L. Sevilla, J.L. Morenza, Appl. Phys. Lett. 85, 1639 (2004)
P. Serra, J.M. Fernandez-Pradas, F.X. Berthet, M. Colina, J. Elvira, J.L. Morenza, Appl. Phys. A 79, 949 (2004)
V. Dinca, E. Kasotakis, J. Catherine, A. Mourka, A. Mitraki, A. Popescu, M. Dinescu, M. Farsari, C. Fotakis, Appl. Surf. Sci. 254, 1160 (2007)
B. Hopp, T. Smausz, N. Kresz, N. Barna, Z. Bor, L. Kolozsvari, D.B. Chrisey, A. Szabo, A. Nogradi, Tissue Eng. 11, 1817 (2005)
B. Hopp, T. Smausz, Z. Antal, N. Kresz, Z. Bor, D.B. Chrisey, J. Appl. Phys. 96, 3478 (2004)
B. Hopp, T. Smausz, N. Barna, C. Vass, Z. Antal, L. Kredics, D.B. Chrisey, J. Phys. D Appl. Phys. 38, 833 (2005)
T. Smausz, B. Hopp, G. Kecskeméti, Z. Bor, Appl. Surf. Sci. 252, 4738 (2006)
J.A. Barron, D.B. Krizman, B.R. Ringeisen, Ann. Biomed. Eng. 33, 121 (2005)
J.A. Barron, R. Rosen, J. Jones-Meehan, B.J. Spargo, S. Belkin, B.R. Ringeisen, Biosens Bioelectron 20, 246 (2004)
J.A. Barron, B.J. Spargo, B.R. Ringeisen, Appl. Phys. A 79, 1027 (2004)
J.A. Barron, P. Wu, H.D. Ladouceur, B.R. Ringeisen, Biomed. Microdevices 6, 139 (2004)
J.A. Barron, H.D. Young, D.D. Dlott, M.M. Darfler, D.B. Krizman, B.R. Ringeisen, Proteomics 5, 4138 (2005)
N.T. Kattamis, P.E. Purnick, R. Weiss, C.B. Arnold, Appl. Phys. Lett. 91, 171120 (2007)
T. Lippert, Adv. Polym. Sci. 168, 51 (2004)
D.P. Banks, K. Kaur, R. Gazia, R. Fardel, M. Nagel, T. Lippert, R.W. Eason, Europhys. Lett. 83, 38003 (2008)
A. Doraiswamy, R.J. Narayan, T. Lippert, L. Urech, A. Wokaun, M. Nagel, B. Hopp, M. Dinescu, R. Modi, R.C.Y. Auyeung, D.B. Chrisey, Appl. Surf. Sci. 252, 4743 (2006)
R. Fardel, M. Nagel, F. Nusch, T. Lippert, A. Wokaun, Appl. Surf. Sci. 254, 1322 (2007)
R. Fardel, M. Nagel, F. Nuesch, T. Lippert, A. Wokaun, Appl. Phys. Lett. 91, 061103 (2007)
M. Nagel, R. Fardel, P. Feurer, M. Häberli, F. Nüesch, T. Lippert, A. Wokaun, Appl. Phys. A 92, 781 (2008)
Acknowledgements
Financial support of the Paul Scherrer Institut and the Swiss National Science Foundation to support parts of this work is gratefully acknowledged. Contributions from R. Fardel, M. Nagel, F. Nüesch, and L.Urech are also gratefully acknowledged.
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Lippert, T. (2010). UV Laser Ablation of Polymers: From Structuring to Thin Film Deposition. In: Miotello, A., Ossi, P. (eds) Laser-Surface Interactions for New Materials Production. Springer Series in Materials Science, vol 130. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-03307-0_7
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